Method for producing a cross-linked siloxane network

Patent metadata

Field	Value
Publication number	US-10370497-B2
Application number	US-201715664846-A
Country	US
Kind code	B2
Filing date	Jul 31, 2017
Priority date	Aug 23, 2016
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

A method for producing a cross-linked siloxane network comprises the steps of: (a) providing a first part comprising (i) a first siloxane compound comprising at least one cyclic siloxane moiety, (ii) an inorganic particulate material, and (iii) an aminosilane compound, (b) providing a second part, the second part comprising a hydroxide salt, (c) combining the first part and the second part to produce a reaction mixture, (d) heating the reaction mixture to a temperature sufficient for the hydroxide salt to open the ring of the cyclic siloxane moiety, and (e) maintaining the reaction mixture at an elevated temperature so that at least a portion of the opened cyclic siloxane moieties react to produce a cross-linked siloxane network.

First claim

What is claimed is:

1. A method for producing a cross-linked siloxane network, the method comprising the steps of:
(a) providing a first part comprising (i) a first siloxane compound comprising at least two cyclic siloxane moieties, (ii) an inorganic particulate material, and (iii) an aminosilane compound, wherein, optionally, at least a portion of the aminosilane compound is disposed on the surface of the inorganic particulate material;
(b) providing a second part, the second part comprising a hydroxide salt;
(c) combining the first part and the second part to produce a reaction mixture;
(d) heating the reaction mixture to a temperature sufficient for the hydroxide salt to open the ring of the cyclic siloxane moiety; and
(e) maintaining the reaction mixture at an elevated temperature so that at least a portion of the opened cyclic siloxane moieties react to produce a cross-linked siloxane network.

2. The method of claim 1 , wherein the first part further comprises a second siloxane compound, and the second siloxane compound comprises at least one cyclic siloxane moiety.

3. The method of claim 1 , wherein the inorganic particulate material is a metal oxide.

4. The method of claim 3 , wherein the inorganic particulate material is silica.

5. The method of claim 1 , wherein the inorganic particulate material is present in the first part in an amount of about 0.5 wt. % to about 10 wt. % based on the total weight of the first part.

6. The method of claim 1 , wherein at least a portion of the aminosilane compound is disposed on the surface of the inorganic particulate material.

7. The method of claim 1 , wherein the aminosilane compound is an amino-functional alkoxysilane compound.

8. The method of claim 7 , wherein the aminosilane compound conforms to the structure of Formula (C)

wherein R 101 , R 102 , and R 103 are independently selected from the group consisting of alkyl groups and alkoxy groups, provided at least one of R 101 , R 102 , and R 103 is an alkoxy group, R 104 is an alkanediyl group, and R 105 is selected from the group consisting of hydrogen, —R 106 —NH 2 , and —R 107 —N(H)—R 108 —NH 2 , where R 106 , R 107 , and R 108 are independently selected from the group consisting of alkanediyl groups.

9. The method of claim 8 , wherein the aminosilane compound is selected from the group consisting of (3-aminopropyl)trimethoxysilane, (3-aminopropyl)-methyl-dimethoxysilane, (3-aminopropyl)-dimethyl-methoxysilane, (3-aminopropyl)triethoxysilane, (3-aminopropyl)-ethyl-diethoxysilane, (3-aminopropyl)-diethyl-ethoxysilane, and mixtures thereof.

10. The method of claim 1 , wherein aminosilane compound is present in the first part in an amount of about 100 ppm or more, based on the total weight of the first part.

11. The method of claim 1 , wherein the hydroxide salt comprises a cation selected from the group consisting of a lithium cation, a sodium cation, a potassium cation, ammonium cations, and phosphonium cations.

12. The method of claim 11 , wherein the cation is selected from the group consisting of ammonium cations and phosphonium cations.

13. The method of claim 12 , wherein the hydroxide salt is selected from the group consisting of tetramethylammonium hydroxide, tetrabutylammonium hydroxide, tetrabutylphosphonium hydroxide, and mixtures thereof.

14. The method of claim 13 , wherein the hydroxide salt is tetrabutylphosphonium hydroxide.

15. The method of claim 1 , wherein the reaction mixture is heated to a temperature of about 120° C. or more.

Assignees

• Milliken & Co

Inventors

• Stapleton Russell A

Classifications

• C08K3/20

  Oxides; Hydroxides {(graphene oxides C08K3/042)} · CPC title

• C08L83/04

  Polysiloxanes · CPC title

• C08K5/544

  containing nitrogen · CPC title

• C08K3/36

  Silica · CPC title

• C08G77/08 Primary

  characterised by the catalysts used · CPC title