Catalyst system and process for the production of glycols

Patent metadata

Field	Value
Publication number	US-10369550-B2
Application number	US-201615776863-A
Country	US
Kind code	B2
Filing date	Nov 17, 2016
Priority date	Nov 19, 2015
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

The invention provides a catalyst system comprising: a) one or more silver tungstate-containing species; and b) one or more catalytic species suitable for hydrogenation, wherein the weight ratio of said one or more silver tungstate-containing species to the one or more catalytic species suitable for hydrogenation is greater than 2.5:1, on the basis of the total weight of the catalyst system; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor at a reactor temperature in the range of from 145 to 190° C. in the presence of a solvent and said catalyst system.

First claim

That which is claimed is:

1. A process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor at a reactor temperature in the range of from 145 to 190° C. in the presence of a solvent and the catalyst system comprising:
(a) one or more silver tungstate-containing species; and
(b) one or more catalytic species suitable for hydrogenation, wherein the weight ratio of said one or more silver tungstate-containing species to the one or more catalytic species suitable for hydrogenation is greater than 2.5:1, on the basis of the total weight of the catalyst system.

2. The process according to claim 1 , wherein the saccharides are selected from the group consisting of monosaccharides, disaccharides, oligosaccharides and polysaccharides.

3. The process according to claim 1 , wherein the catalytic species suitable for hydrogenolysis in the catalyst system are present in an amount in the range of from 0.005 to 10 wt. %, based on the total weight of the reaction mixture.

4. The process according to claim 1 , wherein the reactor temperature is in the range of from 150 to 185° C.

5. The process according to claim 1 , wherein the reactor pressure is in the range of from at least 1 to at most 25 MPa.

6. The process according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals from Groups 8, 9 or 10 of the Periodic Table, or compounds thereof.

7. The process according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are selected from one or more transition metals selected from the group of cobalt, iron, platinum, palladium, ruthenium, rhodium, nickel, iridium, and compounds thereof.

8. The process according to claim 1 , wherein the one or more catalytic species suitable for hydrogenation are solid, unsupported species.

9. The process according to claim 8 , wherein the one or more catalytic species suitable for hydrogenation are on solid catalyst supports.

10. The process according to claim 1 , wherein the solid catalyst support is selected aluminas, silicas, zirconium oxide, magnesium oxide, zinc oxide, titanium oxide, carbon, activated carbon, zeolites, clays, silica alumina and mixtures thereof.

11. The process according to claim 1 , wherein the weight ratio of the one or more silver tungstate-containing species to the one or more catalytic species suitable for hydrogenation is greater than 3:1, on the basis of the total weight of the catalyst system.

12. The process according to claim 1 , wherein the weight ratio of the one or more silver tungstate-containing species to the one or more catalytic species suitable for hydrogenation is greater than 4:1, on the basis of the total weight of the catalyst system.

Assignees

• Shell Oil Co

Inventors

• Edulji Smita
• Van Der Heide Evert

Classifications

• B01J25/02

  Raney nickel · CPC title

• B01J23/74

  Iron group metals · CPC title

• C07C29/60

  by elimination of -OH groups, e.g. by dehydration (C07C29/34 takes precedence) · CPC title

• B01J23/56

  Platinum group metals · CPC title

• C07C29/132

  by reduction of an oxygen containing functional group · CPC title