Composition based on oxides of cerium, of zirconium and of another rare earth metal with high reducibility, preparation process and use in the field of catalysis

Patent metadata

Field	Value
Publication number	US-10369547-B2
Application number	US-201214125639-A
Country	US
Kind code	B2
Filing date	Jun 13, 2012
Priority date	Jun 17, 2011
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

The composition of the invention is based on oxides of cerium, of zirconium and of at least one rare earth metal other than cerium, with a cerium oxide content of greater than 50% by weight and it has, after calcination at 1000° C. for 4 hours, a specific surface area of at least 20 m2/g and an amount of mobile oxygen between 200° C. and 400° C. of at least 0.8 ml O2/g. It is prepared by a process in which, in a reactor, a mixture of compounds of cerium, of zirconium and of the other rare earth metal is reacted continuously with a basic compound with a residence time of the reaction medium in the mixing zone of the reactor of at most 100 milliseconds; the precipitate is heated then brought into contact with a surfactant before being calcined.

First claim

The invention claimed is:

1. A composition based on oxides of cerium, zirconium and at least one rare-earth metal other than cerium, with a cerium oxide content of greater than 50% by mass, wherein the composition has, after calcination at 1000° C. for 4 hours:
a specific surface area of at least 20 m 2 /g;
an amount of mobile oxygen between 200° C. and 400° C. of at least 0.8 ml O 2 /g; and
a maximum reducibility temperature of not more than 520° C.

2. The composition as claimed in claim 1 , wherein the composition has an amount of mobile oxygen between 200° C. and 400° C. of at least 1 ml O 2 /g.

3. The composition as claimed in claim 1 , wherein the composition has an amount of mobile oxygen between 200° C. and 450° C. of at least 1 ml O 2 /g.

4. The composition as claimed in claim 1 , wherein the composition has, after calcination at 1000° C. for 4 hours, a specific surface area of at least 25 m 2 /g.

5. The composition as claimed in claim 1 , wherein the composition has a cerium oxide content between 50% and 90%.

6. The composition as claimed in claim 1 , wherein the composition has a content of oxide of the rare-earth metal other than cerium of not more than 30%.

7. The composition as claimed in claim 6 , wherein the composition has a content of oxide of the rare-earth metal other than cerium of between 5% and 20%.

8. The composition as claimed in claim 1 , wherein the rare-earth metal other than cerium is selected from yttrium, lanthanum, praseodymium, gadolinium and neodymium.

9. The composition as claimed in claim 1 , further comprising one or more additional elements selected from iron, cobalt, strontium, copper and manganese.

10. The composition as claimed in claim 1 , wherein the composition has a maximum reducibility temperature of not more than 520° C. after calcination at 1000° C. for 4 hours.

11. The composition as claimed in claim 1 , wherein the composition is deaggregatable by an ultrasonication treatment and wherein, after the ultrasonication treatment, the composition is in the form of particles with a mean diameter (d50) of not more than 10 μm.

12. A catalytic system, comprising a composition as claimed in claim 1 .

Assignees

• Ifrah Simon
• Rohart Emmanuel
• Hernandez Julien
• Horbez Dominique
• Itani Lama
• Rhodia Operations

Inventors

• Ifrah Simon
• Rohart Emmanuel
• Hernandez Julien
• Horbez Dominique
• Itani Lama

Classifications

• C01F17/206

  oxide or hydroxide being the only anion · CPC title

• C01G25/006

  Compounds containing zirconium, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• B01J23/83

  with rare earths or actinides · CPC title

• C01P2006/13

  thermal stability thereof at high temperatures · CPC title

• B01D53/945

  characterised by a specific catalyst · CPC title