Carbon nanotube membranes

Patent metadata

Field	Value
Publication number	US-10369526-B2
Application number	US-201715651306-A
Country	US
Kind code	B2
Filing date	Jul 17, 2017
Priority date	Oct 21, 2015
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

A process for making an iron oxide impregnated carbon nanotube membrane. In this template-free and binder-free process, iron oxide nanoparticles are homogeneously dispersed onto the surface of carbon nanotubes by wet impregnation. The amount of iron oxide nanoparticles loaded on the carbon nanotubes range from 0.25-80% by weight per total weight of the doped carbon nanotubes. The iron oxide doped carbon nanotubes are then pressed to form a carbon nanotube disc which is then sintered at high temperatures to form a mixed matrix membrane of iron oxide nanoparticles homogeneously dispersed across a carbon nanotube matrix. Methods of characterizing porosity, hydrophilicity and fouling potential of the carbon nanotube membrane are also described.

First claim

The invention claimed is:

1. An iron oxide impregnated carbon nanotube disc membrane, comprising:
a matrix comprising a plurality of carbon nanotubes;
wherein:
the plurality of carbon nanotubes is randomly oriented along a two-dimensional singular axis and is impregnated with iron oxide nanoparticles on the surface;
wherein iron oxide impregnated carbon nanotube disc is obtained by die-pressing the matrix to form a die-pressed disc and sintering the die-pressed disc at temperature of from 1,000 to 1,500° C., and
the iron oxide impregnated carbon nanotube disc is binder-free.

2. The iron oxide impregnated carbon nanotube disc membrane of claim 1 , having an iron oxide nanoparticle content of 0.25-80% by weight per total weight of the carbon nanotube membrane.

3. The iron oxide impregnated carbon nanotube disc membrane of claim 1 , wherein no iron oxide nanoparticles are embedded in the inner wall of the plurality of carbon nanotubes.

4. The iron oxide impregnated carbon nanotube disc membrane of claim 1 , having a carbon nanotube density of at least 10 10 cm −2 .

5. The iron oxide impregnated carbon nanotube disc membrane of claim 1 , having a porosity of 50-80%.

6. The iron oxide impregnated carbon nanotube disc membrane of claim 1 , having a total pore volume of 0.05-0.5 cm 3 /g.

7. The iron oxide impregnated carbon nanotube disc membrane of claim 1 , having an average pore diameter of 0.05-10 μm.

8. The iron oxide impregnated carbon nanotube disc membrane of claim 2 , wherein the iron oxide nanoparticle content is at least 20% and the iron oxide nanoparticles partially aggregate to form pores having an average diameter of 0.05-20 μm on the iron oxide impregnated carbon nanotube disc membrane.

9. The iron oxide impregnated carbon nanotube disc membrane of claim 1 , having a water contact angle of 5-75°.

10. The iron oxide impregnated carbon nanotube disc membrane of claim 1 , having a water flux of 20-2000 Lm −2 h −1 .

11. A method for desalinating and/or treating an aqueous sample, comprising:
contacting the aqueous sample with the iron oxide impregnated carbon nanotube disc membrane of claim 1 .

12. A water desalination or treatment system comprising one or more of the iron oxide impregnated carbon nanotube disc membranes of claim 1 .

Assignees

• Univ King Fahd Pet & Minerals

Inventors

• Atieh Muataz Ali
• Ihsanullah
• Laoui Tahar

Classifications

• C02F1/288

  using composite sorbents, e.g. coated, impregnated, multi-layered · CPC title

• B01D67/0083 Primary

  Thermal after-treatment · CPC title

• B01D71/021

  Carbon · CPC title

• B01D2323/46

  Impregnation · CPC title

• B01D2325/02

  Details relating to pores or porosity of the membranes · CPC title