Magnesium-containing electrolytic solution

Patent metadata

Field	Value
Publication number	US-10367231-B2
Application number	US-201515529902-A
Country	US
Kind code	B2
Filing date	Nov 27, 2015
Priority date	Nov 28, 2014
Publication date	Jul 30, 2019
Grant date	Jul 30, 2019

Abstract

It is an object of the present invention to provide an electrolytic solution having high oxidation decomposition potential, where dissolution and deposition of magnesium proceed repeatedly and stably, using a non-nucleophilic alkoxide-type magnesium salt.
The present invention relates to
(1) an electrolytic solution for a magnesium battery comprising a mixture of a compound represented by the following general formula (I), a Lewis acid and a solvent:

(2) an electrochemical device comprising the electrolytic solution, a positive electrode and a negative electrode, and
(3) a compound represented by the following general formula (I′):

First claim

The invention claimed is:

1. An electrolytic solution for a magnesium battery comprising a mixture of a compound represented by the following general formula (I), a Lewis acid and a solvent:

wherein Y represents a carbon atom or a silicon atom, X represents a chlorine atom or a bromine atom, R 1 represents an aryl group having 6 to 10 carbon atoms, which may have a halogeno group, an alkyl group, a halogenoalkyl group or an alkoxy group, as a substituent, R 2 and R 3 each independently represent a magnesium chloride oxy group (—OMgCl); a magnesium bromide oxy group (—OMgBr); an alkenyl group having 1 to 6 carbon atoms; an alkyl group having 1 to 6 carbon atoms, which may have a halogeno group or an alkoxy group, as a substituent; or an aryl group having 6 to 10 carbon atoms, which may have a halogeno group, an alkyl group, a halogenoalkyl group or an alkoxy group, as a substituent.

2. The electrolytic solution for a magnesium battery according to claim 1 , wherein the Lewis acid contains beryllium, boron, aluminum, silicon, tin, titanium, chromium, iron, or cobalt, as an element.

3. The electrolytic solution for a magnesium battery according to claim 1 , wherein the Lewis acid contains aluminum, as an element.

4. The electrolytic solution for a magnesium battery according to claim 1 , wherein the Lewis acid is aluminum chloride.

5. The electrolytic solution for a magnesium battery according to claim 1 , wherein R 1 in the compound is an aryl group having 6 to 10 carbon atoms, which may have a halogeno group, an alkyl group or an alkoxy group, as a substituent, R 2 and R 3 each independently represent a magnesium chloride oxy group (—OMgCl); an alkenyl group having 1 to 6 carbon atoms; an alkyl group having 1 to 6 carbon atoms; or an aryl group having 6 to 10 carbon atoms, which may have a halogeno group, an alkyl group or an alkoxy group, as a substituent.

6. The electrolytic solution for a magnesium battery according to claim 1 , wherein R 1 in the compound is a phenyl group which may have a halogeno group, an alkyl group or an alkoxy group, as a substituent, R 2 and R 3 each independently represent —OMgCl; an alkenyl group having 1 to 6 carbon atoms; an alkyl group having 1 to 6 carbon atoms; or a phenyl group having an alkyl group as a substituent.

7. The electrolytic solution for a magnesium battery according to claim 1 , wherein X in the compound is a chlorine atom.

8. The electrolytic solution for a magnesium battery according to claim 1 , wherein the solvent is an ether-type solvent, a halogenated hydrocarbon-type solvent, a carbonate-type solvent or a nitrile-type solvent.

9. An electrochemical device comprising the electrolytic solution according to claim 1 , a positive electrode and a negative electrode.

10. A compound represented by the following general formula (I′):

wherein X represents a chlorine atom, R′ 1 represents an aryl group having 6 to 10 carbon atoms, which may have a halogeno group, an alkyl group, a halogenoalkyl group or an alkoxy group, as a substituent, R′ 2 and R′ 3 each independently represent a magnesium chloride oxy group (—OMgCl); a magnesium bromide oxy group (—OMgBr); an alkenyl group having 1 to 6 carbon atoms; an alkyl group having 1 to 6 carbon atoms, which may have a halogeno group or an alkoxy group; or an aryl group having 6 to 10 carbon atoms, which may have a halogeno group, an alkyl group, a halogenoalkyl group or an alkoxy group, as a substituent.

11. The compound according to claim 10 , wherein R′ 2 represents a magnesium chloride oxy group (—OMgCl); a magnesium bromide oxy group (—OMgBr); an alkenyl group having 1 to 6 carbon atoms; or an aryl group having 6 to 10 carbon atoms, which may have a halogeno group, an alkyl group, a halogenoalkyl group or an alkoxy group, as a substituent.

Assignees

• Fujifilm Wako Pure Chemical Corp

Inventors

• Sato Kazuhiko
• Kiyosu Takahiro
• Mizuta Hironori
• Mori Goro
• Okamoto Kuniaki

Classifications

• H01M10/0567 Primary

  characterised by the additives · CPC title

• C07F7/0836

  Compounds with one or more Si-OH or Si-O-metal linkage · CPC title

• C07F19/005

  without metal-C linkages · CPC title

• H01M10/0568 Primary

  characterised by the solutes · CPC title

• H01M10/054

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title