Heating component to reduce solidification in a cryogenic distillation system

Patent metadata

Field	Value
Publication number	US-10365037-B2
Application number	US-201615197810-A
Country	US
Kind code	B2
Filing date	Jun 30, 2016
Priority date	Sep 18, 2015
Publication date	Jul 30, 2019
Grant date	Jul 30, 2019

Abstract

A method and a system for feeding a feed gas including methane (CH 4 ) and carbon dioxide (CO 2 ) to a cryogenic distillation column are provided herein. The method includes flowing a freeze zone CO 2 vapor stream into a freezing section of the column to produce an overhead stream that exits the column. The method includes heating the overhead stream via a heating component to reduce or prevent solidification of the CO 2 in the overhead stream.

First claim

What is claimed is:

1. A method comprising:
feeding a feed gas comprising methane (CH4) and carbon dioxide (CO2) to a cryogenic distillation column during start-up of the cryogenic distillation column;
producing an acid gas rich bottom stream and a freeze zone vapor stream;
flowing the freeze zone vapor stream into a freezing section of the cryogenic distillation column, wherein the freeze zone vapor stream exits the cryogenic distillation column as an overhead stream, and wherein the overhead stream has a temperature and a CO2 concentration;
heating the overhead stream via a heating component to form a heated overhead stream to reduce or prevent solidification of the CO2 in the overhead stream;
regulating an amount of heat emitted by the heating component via a control system, wherein the control system maintains a temperature margin of the heated overhead stream using a measured temperature as an input into a control scheme, wherein the temperature margin is a temperature difference between the temperature of the overhead stream and a temperature at which CO2 solidification would occur in the overhead stream given the CO2 concentration of the overhead stream; and
flowing the heated overhead stream into a heat exchanger, wherein the heated overhead stream substantially prevents solidification of CO2 in the heat exchanger.

2. The method of claim 1 , wherein the heating of the overhead stream comprises raising a temperature of the overhead stream by 0.5° F. to 10° F.

3. The method of claim 1 , comprising measuring a temperature of the heated overhead stream at an inlet of the heat exchanger.

4. The method of claim 1 , comprising recycling the overhead stream back to the cryogenic distillation column, wherein the overhead stream enters a cooling cycle comprising compression, heat exchange, and reduction in pressure and temperature in the recycle.

5. The method of claim 1 , comprising recycling the overhead stream back to the cryogenic distillation column until a concentration of the CO2 is lowered to a non-solidifying range.

6. The method of claim 1 , comprising diverting the overhead stream to a reflux accumulator after a non-solidifying range for the CO2 is reached.

7. The method of claim 1 , wherein heating the overhead stream via the heating component comprises disposing an inline heater in a flow line of the overhead stream, wherein the inline heater is disposed upstream of the heat exchanger.

8. The method of claim 1 , wherein heating the overhead stream via the heating component comprises disposing heat tracing on a flow line of the overhead stream, wherein the heating tracing is disposed upstream of the heat exchanger.

9. The method of claim 1 , wherein heating the overhead stream via the heating component comprises diverting a portion of the overhead stream to an external heat exchanger to form a heated diverted portion and blending the heated diverted portion into the overhead stream.

10. A method comprising:
feeding a feed gas comprising carbon dioxide (CO2) and methane (CH4) into a cryogenic distillation column during start-up;
producing an acid gas rich bottom stream and a freeze zone vapor stream in the cryogenic distillation column;
flowing the freeze zone vapor stream into a freezing section of the cryogenic distillation column, wherein the freeze zone vapor stream exits the cryogenic distillation column as an overhead stream, and wherein the overhead stream has a temperature and a CO2 concentration;
heating the overhead stream via a heating component to form a heated overhead stream;
regulating an amount of heat emitted by the heating component via a control system, wherein the control system uses a measured temperature as an input into a control scheme to maintain a temperature margin of the heated overhead stream, wherein the temperature margin is a temperature difference between the temperature of the overhead stream and a temperature at which CO2 solidification would occur in the overhead stream given the CO2 concentration of the overhead stream;
flowing the heated overhead stream into a heat exchanger, wherein solidification of the CO2 in the heat exchanger is substantially reduced or prevented;

compressing the heated overhead stream via an overhead compressor to produce a high-pressure vapor, wherein the heated overhead stream is compressed to a pressure beyond solidification conditions for CO2;
reducing pressure and temperature of the high-pressure vapor via a Joule-Thomson (J-T) valve to produce a liquid-vapor stream;
flowing the liquid-vapor stream into the cryogenic distillation column, wherein the liquid-vapor stream is introduced into the cryogenic distillation column to lower a concentration of the CO2 in the overhead stream;
cycling the liquid-vapor stream back to the cryogenic distillation column, wherein the cycling comprises a cooling cycle comprising compression, heat exchange, and reduction in pressure and temperature; and
continuously recycling the liquid-vapor stream back to the cryogenic distillation column until a concentration of the CO2 in the liquid-vapor stream is lowered to a non-solidifying range.

Assignees

• Valencia Jaime A
• Smith Ransdall K
• Kimble E Lawrence
• Kelman Scott D
• Exxonmobil Upstream Res Co

Inventors

• Valencia Jaime A
• Smith Ransdall K
• Kimble E Lawrence
• Kelman Scott D

Classifications

• F25J2280/40

  Control of freezing of components · CPC title

• F25J2200/74

  Refluxing the column with at least a part of the partially condensed overhead gas · CPC title

• F25J2200/76

  Refluxing the column with condensed overhead gas being cycled in a quasi-closed loop refrigeration cycle · CPC title

• F25J2205/20

  using solidification of components · CPC title

• F25J3/0233

  separation of CnHm with 1 carbon atom or more · CPC title