Method of removing hydrous silica from bentonite

Patent metadata

Field	Value
Publication number	US-10364155-B2
Application number	US-201514983255-A
Country	US
Kind code	B2
Filing date	Dec 29, 2015
Priority date	Dec 30, 2014
Publication date	Jul 30, 2019
Grant date	Jul 30, 2019

Abstract

A method of removing hydrous silica from bentonite includes irradiating an ultrasonic wave after preparing slurry by putting the bentonite and a sodium compound into distilled water or deionized water, adding the distilled water or the deionized water to the slurry, into which the ultrasonic wave is irradiated, to dilute and centrifugate the slurry, and drying a supernatant obtained through the centrifugation.

First claim

What is claimed is:

1. A method of removing hydrous silica from bentonite, the method comprising:
preparing a slurry by putting the bentonite and a sodium compound into distilled water or deionized water;
ultrasonicating the slurry;
diluting the ultrasonicated slurry by adding distilled water or deionized water;
centrifuging the diluted slurry; and
drying a supernatant obtained through the centrifugation,
wherein the sodium compound is added with a weight ratio in a range of 0.04 to 0.09 with respect to the bentonite,
the sodium compound is contained in the slurry at an amount greater than 90% of a cation exchange capacity (CEC) value (meq/100 g) of the bentonite,
the bentonite comprises Ca-bentonite, and the Ca-bentonite is converted to Na-bentonite using the sodium compound,
the centrifugation is performed at 10,000 rpm to 12,000 rpm for 30 min.

2. The method of claim 1 , wherein the bentonite is contained in the slurry such that the bentonite has a concentration of 3.0 weight % to 9.0 weight %.

3. The method of claim 1 , wherein the sodium compound includes one selected from the group consisting of Na 2 CO 3 , NaHCO 3 and (NaPO 3 ) 6 .

4. The method of claim 1 , wherein the sodium compound is added with a weight ratio in a range of 0.04 to 0.05 with respect to the bentonite when the sodium compound is Na 2 CO 3 .

5. The method of claim 1 , wherein the sodium compound is added with a weight ratio in a range of 0.06 to 0.07 with respect to the bentonite when the sodium compound is NaHCO 3 .

6. The method of claim 1 , wherein the sodium compound is added with a weight ratio in a range of 0.07 to 0.09 with respect to the bentonite when the sodium compound is (NaPO 3 ) 6 .

7. The method of claim 1 , wherein the ultrasonicating comprises irradiating an ultrasonic wave with frequency of 20 kHz and energy of 500 W to 700 W for 10 min to 20 min.

8. The method of claim 7 , wherein the distilled water or the deionized water is added after the ultrasonic wave is irradiated, such that the slurry has concentration of 0.75 weight % to 1.5 weight %.

9. A method of removing hydrous silica from bentonite, the method comprising:
performing pretreatment with respect to the bentonite;
preparing a slurry by putting the bentonite and a sodium compound into distilled water or deionized water;
ultrasonicating the slurry;
diluting the ultrasonicated slurry by adding distilled water or deionized water;
centrifuging the diluted slurry; and
drying a supernatant obtained through the centrifugation,
wherein the sodium compound is added with a weight ratio in a range of 0.04 to 0.09 with respect to the bentonite,
the sodium compound is contained in the slurry at an amount greater than 90% of a cation exchange capacity (CEC) value (meq/100 g) of the bentonite,
the bentonite comprises Ca-bentonite, and the Ca-bentonite is converted to Na-bentonite using the sodium compound,
the centrifugation is performed at 10,000 rpm to 12,000 rpm for 30 min.

10. The method of claim 9 , the pretreatment comprises a process of drying, scrubbing, levigating, and drying the bentonite.

11. The method of claim 9 , wherein the bentonite is contained in the slurry such that the bentonite has a concentration in a range of 3.0 weight % to 9.0 weight %.

12. The method of claim 9 , wherein the sodium compound includes one selected from the group consisting of Na 2 CO 3 , NaHCO 3 and (NaPO 3 ) 6 .

13. The method of claim 9 , wherein the ultrasonicatinq comprises irradiating an ultrasonic wave with frequency of 20 kHz and energy of 500 W to 700 W for 10 min to 20 min.

14. The method of claim 13 , wherein the distilled water or the deionized water is added after the ultrasonic wave is irradiated, such that the bentonite in the slurry, which is subject to the pretreatment, has concentration of 0.75 weight % to 1.5 weight %.

Assignees

• Korea Inst Geoscience & Mineral Resources

Inventors

• Kim Wan-Tae
• Kim Sang-Bae
• Kang Il-Mo

Classifications

• C01B33/26 Primary

  Aluminium-containing silicates {, i.e. silico-aluminates} · CPC title

• C01B33/40 Primary

  Clays · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title