Mesoporous material-coated cobalt-based catalyst for fischer-tropsch synthesis and method for preparing the same

Patent metadata

Field	Value
Publication number	US-10363550-B2
Application number	US-201615331925-A
Country	US
Kind code	B2
Filing date	Oct 24, 2016
Priority date	Apr 22, 2014
Publication date	Jul 30, 2019
Grant date	Jul 30, 2019

Abstract

A catalyst including cobalt, a carrier including silica, and a selective promoter including zirconium. The cobalt and the selective promoter are disposed on the surface of the carrier, and the outer surfaces of the active component cobalt and the selective promoter zirconium are coated with a shell layer including a mesoporous material. A method for preparing the catalyst, including: 1) soaking the carrier including silica into an aqueous solution including a zirconium salt, aging, drying, and calcining a resulting mixture to yield a zirconium-loaded carrier including silica; 2) soaking the zirconium-loaded carrier including silica into an aqueous solution including a cobalt salt, aging, drying, calcining a resulting mixture to yield a primary cobalt-based catalyst; 3) preparing a precursor solution of a mesoporous material; and 4) soaking the primary cobalt-based catalyst into the precursor solution of the mesoporous material; and crystalizing, washing, drying, and calcining a resulting mixture.

First claim

The invention claimed is:

1. A catalyst, comprising:
elemental cobalt;
a carrier, the carrier comprising silica; and
a selective promoter, the selective promoter comprising zirconium; wherein:
the elemental cobalt and the selective promoter are disposed on a surface of the carrier;
outer surfaces of the elemental cobalt and the selective promoter are coated with a shell layer comprising a mesoporous material; and
a hydrophobic organic compound is disposed on an exterior surface of the shell layer.

2. The catalyst of claim 1 , wherein the carrier is an inorganic silica gel.

3. The catalyst of claim 2 , wherein the inorganic silica gel has a specific area of between 150 and 350 m 2 /g, an average pore size of between 3 and 50 nm, a pore volume of between 0.7 and 1.7 mL/g, and a particle size of between 20 and 200 μm.

4. The catalyst of claim 3 , wherein the specific area of the inorganic silica gel is between 200 and 300 m 2 /g, the average pore size of the inorganic silica gel is between 8 and 13 nm, the pore volume of the inorganic silica gel is between 0.75 and 1.3 mL/g, and the particle size of the inorganic silica gel is between 40 and 150 μm.

5. The catalyst of claim 1 , wherein a content of the elemental cobalt accounts for between 10 and 25 wt. % of a total weight of the catalyst; and a content of the selective promoter accounts for between 5 and 10 wt. % of the total weight of the catalyst.

6. The catalyst of claim 5 , wherein the content of the elemental cobalt accounts for between 15 and 20 wt. % of the total weight of the catalyst; and the content of the selective promoter accounts for between 5 and 8 wt. % of the total weight of the catalyst.

7. The catalyst of claim 5 , wherein the content of the elemental cobalt accounts for between 20 and 25 wt. % of the total weight of the catalyst; and the content of the selective promoter accounts for between 8 and 10 wt. % of the total weight of the catalyst.

8. The catalyst of claim 1 , wherein a thickness of the shell layer comprising the mesoporous material is between 1.8 and 13 μm.

9. The catalyst of claim 8 , wherein the thickness of the shell layer comprising the mesoporous material is between 2.0 and 6.0 μm.

10. The catalyst of claim 1 , wherein the catalyst has a specific area of between 150 and 400 m 2 /g, an average pore size of between 2 and 40 nm, and a pore volume of between 0.5 and 1.4 mL/g.

11. The catalyst of claim 10 , wherein the catalyst has the specific area of between 250 and 350 m 2 /g, the average pore size of between 3 and 9 nm, and the pore volume of between 0.6 and 1.0 mL/g.

12. The catalyst of claim 1 , wherein the hydrophobic organic compound is selected from polymethyltriethoxysilane, γ-aminopropyltriethoxysilane, and trimethylchlorosilane.

13. The catalyst of claim 1 , wherein the hydrophobic organic compound protects the elemental cobalt from being oxidized by water.

14. The catalyst of claim 1 , wherein when the catalyst is used in a Fischer-Tropsch synthesis process,
the Fischer-Tropsch synthesis process yields a carbon-containing mixture comprising C 5+ hydrocarbons and CH 4 ;
the hydrophobic organic compound shields the elemental cobalt from water that is produced during the Fischer-Tropsch synthesis process;
a content of the C 5+ hydrocarbons accounts for between 82.9 and 87.5 wt. % of the total weight of the carbon-containing mixture; and
a content of the CH 4 accounts for between 5.2 and 9.2 wt. % of the total weight of the carbon-containing mixture.

Assignees

• Wuhan Kaidi Eng Tech Res Inst

Inventors

• Rao Shasha
• Song Dechen
• Liu Qianqian
• Zheng Shenke

Classifications

• C10G2/00

  Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon · CPC title

• B01J23/75 Primary

  Cobalt · CPC title

• B01J31/0274 Primary

  containing silicon (ligands in coordination complexes B01J31/1608) · CPC title

• B01J33/00

  Protection of catalysts, e.g. by coating · CPC title

• B01J37/088

  Decomposition of a metal salt · CPC title