Aluminum based metallic glass powder for efficient degradation of AZO dye and other toxic organic chemicals

Patent metadata

Field	Value
Publication number	US-10363548-B2
Application number	US-201715409972-A
Country	US
Kind code	B2
Filing date	Jan 19, 2017
Priority date	Jan 22, 2016
Publication date	Jul 30, 2019
Grant date	Jul 30, 2019

Abstract

The present invention provides amorphous bi-functional catalytic aluminum metallic glass particles having an aluminum metallic glass core and 2 or more transition metals disposed on the surface of the aluminum metallic glass core to form amorphous bi-functional aluminum metallic glass particles with catalytic activity.

First claim

What is claimed is:

1. Amorphous bi-functional catalytic aluminum metallic glass particles comprising:
an aluminum metallic glass core; and
2 or more transition metals disposed on the surface of the aluminum metallic glass core to form amorphous bi-functional aluminum metallic glass particles with catalytic activity, wherein the aluminum comprises 77% or more of the composition.

2. The particles of claim 1 , wherein an amorphous bi-functional aluminum metallic glass particle surface has a concentration of the 2 or more transition metals is between 13 to 23% of the particle.

3. The particles of claim 1 , wherein the amorphous bi-functional aluminum metallic glass particles reacts to degrade one or more azo compounds.

4. The particles of claim 3 , wherein the azo compounds are selected from the group consisting of Orange II (C 16 H 11 N 2 NaO 4 S), Chrysoidine (C 12 H 13 ClN 4 ), Tropaeolin O (C 12 H 9 N 2 NaO 5 S), Acid Orange, and Acid Red.

5. The particles of claim 1 , wherein the 2 or more transition metals are Ni and Fe.

6. The particles of claim 1 , wherein the 2 or more transition metals are Y, Ni and Fe.

7. The particles of claim 1 , wherein the 2 or more transition metals are selected from the group consisting of Scandium, Titanium, Vanadium, Chromium, Manganese, Iron, Cobalt, Nickel, Copper, Zinc, Yttrium, Zirconium, Niobium, Molybdenum, Technetium, Ruthenium, Rhodium, Palladium, Silver, Cadmium, Hafnium, Tantalum, Tungsten, Rhenium, Osmium, Iridium, Platinum, Gold, Mercury, Rutherfordium, Dubnium, Seaborgium, Bohrium, Hassium, Meitnerium, Ununnilium, Unununium, and Ununbium.

8. The particles of claim 1 , wherein the aluminum comprises at least 80% of the composition.

9. The particles of claim 1 , wherein the aluminum comprises at least 80%, Y comprises at least 5%, Ni comprises at least 4% and Fe comprises at least 1% of the particle.

10. The particles of claim 1 , wherein the aluminum comprises 77-87%, Y comprises 5-11%, Ni comprises 4-10% and Fe comprises 1-5% of the particle.

11. The particles of claim 1 , wherein the aluminum comprises about 82%, Y comprises about 8%, Ni comprises about 7% and Fe comprises about 3% of the particle.

12. The particles of claim 1 , wherein the amorphous bi-functional aluminum metallic glass particles comprises Al 82 Y 8 Ni 7 Fe 3 .

13. The particles of claim 1 , wherein the amorphous bi-functional aluminum metallic glass particles have a diameter of greater than 500 nm.

14. The particles of claim 1 , wherein the amorphous bi-functional aluminum metallic glass particles have a diameter of 0.5-40 μm.

15. Amorphous bi-functional aluminum metallic glass catalyst comprising:
an aluminum metallic glass core; and
2 or more transition metals disposed on the surface of the aluminum metallic glass core to form amorphous bi-functional aluminum metallic glass particles with catalytic activity, wherein the aluminum comprises 77% or more of the composition.

16. The catalyst of claim 15 , wherein the amorphous bi-functional aluminum metallic glass particles comprises Al 82 Y 8 Ni 7 Fe 3 .

17. The catalyst of claim 15 , wherein the aluminum comprises at least 80%, Y comprises at least 5%, Ni comprises at least 4% and Fe comprises at least 1% of the catalyst.

Assignees

• Univ North Texas

Inventors

• Das Santanu
• Mukherjee Sundeep

Classifications

• C22C1/11

  Making amorphous alloys · CPC title

• B22F1/17

  Metallic particles coated with metal · CPC title

• B22F1/08

  Metallic powder characterised by particles having an amorphous microstructure · CPC title

• B22F1/00

  Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties · CPC title

• B01J21/02

  Boron or aluminium; Oxides or hydroxides thereof · CPC title