Liquefaction method and system

Patent metadata

Field	Value
Publication number	US-10359228-B2
Application number	US-201615160209-A
Country	US
Kind code	B2
Filing date	May 20, 2016
Priority date	May 20, 2016
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

A system and method for liquefaction of a natural gas stream utilizing a plurality of asymmetric parallel pre-cooling circuits. The use of asymmetric parallel cooling circuits allows for greater control over each refrigerant stream during the cooling process and simplifies process control by dedicating heat exchangers to performing similar duties.

First claim

What is claimed is:

1. A method for liquefying a hydrocarbon feed stream, the method comprising:
(a) providing a hydrocarbon fluid feed stream at a first feed temperature;
(b) splitting the hydrocarbon fluid feed stream into a first portion and a second portion;
(c) cooling the first portion of the hydrocarbon fluid feed stream in a first pre-cooling heat exchanger against a first mixed refrigerant to form a first pre-cooled hydrocarbon fluid stream that exits the first pre-cooling heat exchanger at a first pre-cooled temperature;
(d) cooling the second portion of the hydrocarbon fluid feed stream in a second pre-cooling heat exchanger against the first mixed refrigerant to form a second pre-cooled hydrocarbon fluid stream that exits the second pre-cooling heat exchanger at a second pre-cooled temperature, the second pre-cooling heat exchanger having a different geometry from the first pre-cooling heat exchanger;
(e) withdrawing an evaporated second mixed refrigerant stream from a shell side of a main heat exchanger;
(f) compressing and cooling the evaporated second mixed refrigerant stream to form a resultant second mixed refrigerant stream at a resultant second mixed refrigerant temperature, the resultant second mixed refrigerant temperature being substantially equal to the first feed temperature;
(g) cooling the resultant second mixed refrigerant stream in the second pre-cooling heat exchanger against the first mixed refrigerant to form a pre-cooled second mixed refrigerant stream that exits the second pre-cooling heat exchanger at a third pre-cooled temperature;
(h) combining the first pre-cooled hydrocarbon fluid stream and the second pre-cooled hydrocarbon fluid stream and introducing the combined pre-cooled hydrocarbon fluid stream into the tube side of the main heat exchanger;
(i) introducing at least a portion of the pre-cooled second mixed refrigerant stream into the tube side of the main heat exchanger;
(j) cooling the combined pre-cooled hydrocarbon fluid stream in the main heat exchanger against the second mixed refrigerant on the shell side of the main heat exchanger to form a liquefied hydrocarbon fluid stream;
(k) cooling the at least a portion of the pre-cooled second mixed refrigerant stream in the main heat exchanger against a flow the second mixed refrigerant on the shell side of the main heat exchanger to form at least one cooled second mixed refrigerant stream; and
(l) withdrawing each of the at least one cooled second mixed refrigerant stream from the tube side of the main heat exchanger, expanding each of the each of the at least one cooled second mixed refrigerant stream to form an expanded second refrigerant stream, and providing each of the at least one expanded second mixed refrigerant stream to the shell side of the main heat exchanger.

2. The method of claim 1 , further comprising:
(m) separating a liquid portion of the pre-cooled second mixed refrigerant stream from a vapor portion of the pre-cooled second refrigerant mixed stream;
wherein step (i) comprises introducing the liquid portion of pre-cooled second mixed refrigerant stream and the vapor portion of the pre-cooled second mixed refrigerant stream into the tube side of the main heat exchanger.

3. The method of claim 1 , wherein the second pre-cooled temperature and third pre-cooled temperature are substantially equal to the first pre-cooled temperature.

4. The method of claim 1 , wherein step (f) comprises compressing and cooling the second mixed refrigerant stream to form a resultant second mixed refrigerant stream at a resultant second mixed refrigerant temperature, the resultant second mixed refrigerant temperature being substantially equal to the first feed temperature and substantially all of the resultant second mixed refrigerant stream is vapor phase.

5. The method of claim 1 , wherein step (c) comprises cooling the first portion of the hydrocarbon fluid feed stream in a tube side of a first pre-cooling heat exchanger against a first mixed refrigerant flowing through a shell side of the first pre-cooling heat exchanger to form a first pre-cooled hydrocarbon fluid stream that exits the first pre-cooling heat exchanger at a first pre-cooled temperature.

6. The method of claim 5 , wherein step (d) comprises cooling the second portion of the hydrocarbon fluid feed stream in a tube side of a second pre-cooling heat exchanger against the first mixed refrigerant flowing through a shell side of the second pre-cooling heat exchanger to form a second pre-cooled hydrocarbon fluid stream that exits the second pre-cooling heat exchanger at a second pre-cooled temperature.

7. The method of claim 1 , further comprising:
(n) circulating the first mixed refrigerant in a closed refrigeration loop that flows through a shell side of each of the first and second pre-cooling heat exchangers.

8. The method of claim 1 , further comprising:
(o) withdrawing an evaporated first mixed refrigerant stream from a shell side of each of the first and second pre-cooling heat exchangers;
(p) compressing and cooling the evaporated first mixed refrigerant stream to form a resultant first mixed refrigerant stream;
(q) introducing the resultant first mixed refrigerant stream into a tube side of the first pre-cooling heat exchanger;
(r) cooling the resultant first mixed refrigerant stream in the first pre-cooling heat exchanger against a flow of the first mixed refrigerant on the shell side of the first pre-cooling heat exchanger to form a cooled first mixed refrigerant stream;
(s) withdrawing the cooled first mixed refrigerant stream from the first pre-cooling heat exchanger and splitting the cooled first mixed refrigerant stream into first and second cooled first mixed refrigerant streams;
(t) expanding each of the first and second cooled first mixed refrigerant streams to form first and second expanded first mixed refrigerant streams; and
(u) introducing the first expanded first mixed refrigerant stream into the shell side of the first pre-cooling heat exchanger; and
(v) introducing the second expanded first mixed refrigerant stream into a shell side of the second pre-cooling heat exchanger.

9. The method of claim 1 , wherein step (d) comprises:
(d) cooling the second portion of the hydrocarbon fluid feed stream in a second pre-cooling heat exchanger against the first mixed refrigerant to form a second pre-cooled hydrocarbon fluid stream that exits the second pre-cooling heat exchanger at a second pre-cooled temperature, the second pre-cooling heat exchanger having the same refrigeration duty as the first pre-cooling heat exchanger.

Assignees

• Air Prod & Chem

Inventors

• Brostow Adam Adrian
• Chen Fei
• Roberts Mark Julian
• Ott Christopher Michael

Classifications

• F25J2210/06

  Splitting of the feed stream, e.g. for treating or cooling in different ways · CPC title

• F25J1/0292

  Refrigerant compression by cold or cryogenic suction of the refrigerant gas · CPC title

• F25J2220/64

  Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general · CPC title

• F25J2270/12

  External refrigeration with liquid vaporising loop · CPC title

• F25J1/0022 Primary

  Hydrocarbons, e.g. natural gas · CPC title