Resin particle dispersion, sheet product, and friction plate

Patent metadata

Field	Value
Publication number	US-10358773-B2
Application number	US-201615555688-A
Country	US
Kind code	B2
Filing date	Mar 1, 2016
Priority date	Mar 12, 2015
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

The present invention relates to a resin fine particle dispersion optimal for manufacturing a sheet product such as paper. Specifically, an object of the present invention is to provide a resin fine particle dispersion with which a sheet product having excellent heat resistance and high mechanical strength is obtained, and which has a small environmental load due to a small amount of resin particles remaining in wastewater after papermaking. Provided are a resin fine particle dispersion including resin fine particles (A), a fiber material (B), an ionic polyacrylamide (C), and water as essential components, and a sheet product and a friction plate using this.

First claim

The invention claimed is:

1. A friction plate comprising a resin fine particle dispersion, wherein the resin fine particle dispersion comprises
resin fine particles (A), a fiber material (B), an ionic polyacrylamide (C), and water as essential components,
wherein the resin fine particles (A) comprises a resin composition including a phenol resin as an essential component;
the phenol resin is a novolak type phenol resin (N) or a resol type phenol resin (R) or a combination thereof;
the number average molecular weight (Mn) of the phenol resin is in the range of 300 to 2,000;
a blending rate of the resin fine particles (A) is 0.1% to 50% by mass in the resin fine particle dispersion.

2. The friction plate according to claim 1 ,
wherein a degree of ionization of the ionic polyacrylamide (C) is from −5 to 5 meq/g.

3. The friction plate according to claim 1 ,
wherein a blending amount of the ionic polyacrylamide (C) is from 0.001 to 2.0 parts by mass with respect to 100 parts by mass of the fiber material (B).

4. The friction plate according to claim 1 ,
wherein an ionic parameter acquired by the following equation is from −0.45 to 0.35 meq/g:
Ionic parameter (meq/g)=Σ [degree of ionization of ionic polyacrylamide (C) (meq/g)×a blending rate of ionic polyacrylamide (C) with respect to fiber material (B) (% by mass)].

5. The friction plate according to claim 1 ,
wherein the resin fine particle dispersion further comprises a curing agent (D).

6. The friction plate according to claim 5 ,
wherein the blending rate of the resin fine particles (A) is 0.1% to 50% by mass, the blending rate of the fiber material (B) is 0.5% to 80% by mass, the blending rate of the ionic polyacrylamide (C) is 0.001% to 1% by mass, the blending rate of the curing agent (D) is 0.1% to 75% by mass, and the blending rate of water is 50% to 99% by mass.

7. The friction plate according to claim 1 ,
wherein the blending rate of the fiber material (B) is from 0.5% to 80% by mass.

8. The friction plate according to claim 1 , wherein
a viscosity in terms of 10% by mass of an aqueous solution of the ionic polyacrylamide (C) is 300 to 100,000 cps.

9. The friction plate according to claim 1 , wherein
the ionic polyacrylamide (C) is a polymer consisting of a cationic and/or amphoteric acrylamide polymer.

10. The friction plate according to claim 9 , wherein
the ionic polyacrylamide (C) is a polymer of the combination of dimetylaminoprolyl(meth)acrylamide and itaconic acid.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Kimoto Seiji
• Kida Shigenobu

Classifications

• C08L2205/16

  Fibres; Fibrils · CPC title

• C08L61/06 Primary

  of aldehydes with phenols · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• D21H17/37

  Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates · CPC title

• C08L33/26

  Homopolymers or copolymers of acrylamide or methacrylamide · CPC title