Hot stamp molded body, and method for producing hot stamp molded body

Patent metadata

Field	Value
Publication number	US-10358687-B2
Application number	US-201414897479-A
Country	US
Kind code	B2
Filing date	Jun 6, 2014
Priority date	Jun 11, 2013
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

A hot stamp molded body that can be produced highly efficiently without causing sticking of plating to a mold, when an electrogalvanized steel sheet with a light plating weight is hot-stamped using a rapidly heating method such as Joule heating and induction heating, and can secure favorable paint adhesiveness without a posttreatment such as shotblasting after hot stamping, as well as a method for producing the same. A hot stamp molded body is produced by hot-stamping an electrogalvanized steel sheet which is composed of predetermined components, and is electrogalvanized on each face with a plating weight not less than 5 g/m2 and less than 40 g/m2; and therein a galvanized layer of the hot stamp molded body is configured with 0 g/m2 to 15 g/m2 of a Zn—Fe intermetallic compound and a Fe—Zn solid solution phase as a balance, and in the galvanized layer of the hot stamp molded body 1×10 pcs to 1×104 pcs of particulate matter with an average diameter of from 10 nm to 1 μm are present per 1 mm length of the galvanized layer.

First claim

The invention claimed is:

1. A hot stamp molded body produced by hot-stamping an electrogalvanized steel sheet, the steel sheet comprising, by mass %:
C: from 0.10 to 0.35%,
Si: from 0.01 to 3.00%,
Al: from 0.01 to 3.00%,
Mn: from 1.0 to 3.5%,
P: from 0.001 to 0.100%,
S: from 0.001 to 0.010%,
N: from 0.0005 to 0.0100%,
Ti: from 0.000 to 0.200%,
Nb: from 0.000 to 0.200%,
Mo: from 0.00 to 1.00%,
Cr: from 0.00 to 1.00%,
V: from 0.000 to 1.000%,
Ni: from 0.00 to 3.00%,
B: from 0.0000 to 0.0050%,
Ca: from 0.0000 to 0.0050%, and
Mg: from 0.0000 to 0.0050%,
a balance being Fe and impurities,
wherein the steel sheet is electrogalvanized on each face with a plating weight not less than 5 g/m 2 and less than 40 g/m 2 ;
wherein a galvanized layer of the hot stamp molded body is configured with 0 g/m 2 to 15g/m 2 of a Zn-Fe intermetallic compound and a Fe-Zn solid solution phase as a balance,
wherein, in the galvanized layer of the hot stamp molded body, 1×10 pcs to 1×10 4 pcs of particulate matter with an average diameter of from 10 nm to 1 μm are present per 1 mm length of the galvanized layer,
wherein the particulate matter contains one, or two or more kinds of single oxides or complex oxides or a complex structure of single oxides and complex oxides, of Si, Mn, Cr, and Al,
wherein the single oxides comprise one or more of MnO, MnO 2 , Mn 2 O 3 , Mn 3 O 4 , SiO 2 , Al 2 O 3 , Cr 2 O 3 , and non-stoichiometric compositions thereof, and
wherein the complex oxides comprise one or more of FeSiO 3 , Fe 2 SiO 4 , MnSiO 3 , Mn 2 SiO 4 , AlMnO 3 , FeCr 2 O 4 , Fe 2 CrO 4 , MnCr 2 O 4 , Mn 2 CrO 4 , and non-stoichiometric compositions thereof.

2. The hot stamp molded body according to claim 1 , wherein the steel sheet comprises, by mass %, one or more of:
Ti: from 0.001 to 0.200%,
Nb: from 0.001 to 0.200%,
Mo: from 0.01 to 1.00%,
Cr: from 0.01 to 1.00%,
V: from 0.001 to 1.000%,
Ni: from 0.01 to 3.00%,
B: from 0.0002 to 0.0050%,
Ca: from 0.0002 to 0.0050%, or
Mg: from 0.0002 to 0.0050%.

3. The hot stamp molded body according to claim 1 , wherein the electrogalvanized steel sheet is an electrolytic zinc alloy-coated steel sheet.

4. The hot stamp molded body according to claim 1 , wherein inside the galvanized layer of the hot stamp molded body, 1×10 pcs to 1×10 4 pcs of particulate matter with an average diameter of from 10 nm to 1 μm are present per 1 mm length of the galvanized layer.

5. A method for producing a hot stamp molded body according to claim 1 , the method comprising subjecting a steel comprising, by mass %:
C: from 0.10 to 0.35%,
Si: from 0.01 to 3.00%,
Al: from 0.01 to 3.00%,
Mn: from 1.0 to 3.5%,
P: from 0.001 to 0.100%,
S: from 0.001 to 0.010%,
N: from 0.0005 to 0.0100%,
Ti: from 0.000 to 0.200%,
Nb: from 0.000 to 0.200%,
Mo: from 0.00 to 1.00%,
Cr: from 0.00 to 1.00%,
V: from 0.000 to 1.000%,
Ni: from 0.00 to 3.00%,
B: from 0.0000 to 0.0050%,
Ca: from 0.0000 to 0.0050%, and
Mg: from 0.0000 to 0.0050%,
a balance being Fe and impurities, to hot rolling, pickling, cold rolling, continuous annealing, temper rolling, and electrogalvanizing to yield an electrogalvanized steel sheet, and subjecting the electrogalvanized steel sheet to hot stamp molding to produce a hot stamp molded body;
wherein the continuous annealing includes subjecting the steel sheet to repeated bending at a bending angle of from 90° to 220° four or more times during heating of the steel sheet in an atmosphere gas containing hydrogen at from 0.1 volume % to 30 volume %, H 2 O corresponding to a dew point of from −70° C. to −20° C., and nitrogen and impurities as a balance, at a sheet temperature within a range of from 350° C. to 700° C.,
wherein the electrogalvanizing includes electrogalvanizing each face of the steel sheet with a plating weight of not less than 5 g/m 2 and less than 40 g/m 2 , and
wherein the hot stamp molding includes heating the electrogalvanized steel sheet with an average temperature elevation rate of 50° C./sec or more to a temperature range of from 700° C. to 1100° C., hot stamping within 1 min from the initiation of the temperature elevation, and thereafter cooling to normal temperature,
therefore producing the hot stamp molded body of claim 1 .

6. The method for producing a hot stamp molded body according to claim 5 , wherein the steel comprises, by mass %, one or more of:
Ti: from 0.001 to 0.200%,
Nb: from 0.001 to 0.200%,
Mo: from 0.01 to 1.00%,
Cr: from 0.01 to 1.00%,
V: from 0.001 to 1.000%,
Ni: from 0.01 to 3.00%,
B: from 0.0002 to 0.0050%,
Ca: from 0.0002 to 0.0050%, or
Mg: from 0.0002 to 0.0050%.

Assignees

• Nippon Steel & Sumitomo Metal Corp
• Nippon Steel Corp

Inventors

• Akiba Kojiro
• Kondo Yusuke
• Kikuchi Yoshitaka
• Kato Satoshi

Classifications

• C25D7/0614

  Strips or foils · CPC title

• C25D5/36

  of iron or steel · CPC title

• C22C38/58

  with more than 1.5% by weight of manganese · CPC title

• C22C38/06 Primary

  containing aluminium · CPC title

• C22C38/04

  containing manganese · CPC title