Sugar extraction and ionic liquid recycling using alkaline solutions

Patent metadata

Field	Value
Publication number	US-10358685-B2
Application number	US-201314398432-A
Country	US
Kind code	B2
Filing date	May 2, 2013
Priority date	May 2, 2012
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

The present invention provides a method for obtaining a monosaccharide from a lignocellulosic material in a form suitable for use as a carbon source in a reaction. In some embodiments, the monosaccharide is in a form suitable for use in a fermentation reaction, e.g., to produce an alcohol such as ethanol.

First claim

What is claimed is:

1. A method for obtaining sugar monomers from a lignocellulosic material, comprising:
(i) contacting a lignocellulosic material with an ionic liquid to form a solution of the lignocellulosic material in the ionic liquid, wherein the ionic liquid is an imidazolium salt, and
adding an aqueous acidic solution to the solution lignocellulosic material in the ionic liquid to form by acidolysis an aqueous solution comprising sugar monomers and the ionic liquid;
(ii) preparing a biphasic system, wherein the step of preparing the biphasic system consists of contacting the aqueous solution of sugar monomers and the ionic liquid of (i) with an aqueous hydroxide solution to form a biphasic system which comprises a first phase and a second phase,
wherein the final concentration of hydroxide is at least about 15 wt % based on the total weight of biphasic system,
wherein the first phase is an aqueous ionic liquid phase which is essentially free of sugar monomers, and
wherein the second phase is an aqueous liquid phase comprising sugar monomers;
(iii) separating the first phase and the second phase of the biphasic system of (ii), thereby separating the sugar monomers from the ionic liquid; and
(iv) recovering the sugar monomers from the second phase obtained in step (iii).

2. The method of claim 1 , wherein the lignocellulosic material is untreated.

3. The method of claim 2 , wherein the lignocellulosic material is selected from the group consisting of switchgrass, corn stover and bagasse.

4. The method of claim 1 , wherein the imidazolium salt is a chloride salt.

5. The method of claim 1 , wherein step (iii) is conducted by decantation.

6. The method of claim 1 , wherein the ionic liquid is selected from the group consisting of 1-ethyl-3-methylimidazolium chloride and 1-butyl-3-methylimidazolium chloride.

7. The method of claim 1 , wherein the contacting the lignocellulosic material with the ionic liquid to form a solution of the lignocellulosic material in the ionic liquid is performed at a temperature of from about 100° C. to about 160° C.

8. The method of claim 1 , wherein the contacting the lignocellulosic material with the ionic liquid to form a solution of the lignocellulosic material in the ionic liquid is performed for a period of about 1 hour to about 16 hours.

9. The method of claim 1 , wherein the aqueous acidic solution is a hydrochloric acid solution.

10. The method of claim 1 , wherein the concentration of the aqueous acidic solution prior to step (i) is about 2 M to about 12 M.

11. The method of claim 10 , wherein the final concentration of the hydroxide is from about 15% w/w to 50% w/w based on the total weight of biphasic system.

12. The method of claim 1 , wherein adding the aqueous acidic solution is performed at a temperature of from about 60° C. to about 110° C.

13. The method of claim 1 , wherein the adding is performed for a period of from about 2 hours to about 6 hours.

14. The method of claim 1 , wherein the hydroxide is selected from the group consisting of calcium hydroxide, ammonium hydroxide, potassium hydroxide, sodium hydroxide and lithium hydroxide.

15. The method of claim 14 , wherein the hydroxide is sodium hydroxide.

16. The method of claim 1 , wherein the contacting with the aqueous hydroxide solution is performed at a temperature of from about 20° C. to about 50° C.

17. The method of claim 1 , wherein the contacting with the aqueous hydroxide solution is performed for a period of about 15 minutes to about 1 hour.

18. The method of claim 1 , wherein the density of the second phase is from about 1.2 gram/cm 3 to about 1.4 gram/cm 3 .

19. The method of claim 1 , wherein the concentration of the sugar monomers in the second phase is from about 2 g/L to about 40 g/L.

20. The method of claim 1 , wherein the sugar monomers are selected from the group consisting of glucose, xylose and mixtures thereof.

21. The method of claim 1 , further comprising recovering and reusing the ionic liquid.

22. The method of claim 1 , wherein the water content of the first phase is from about 20 wt % to about 50 wt %.

23. The method of claim 1 , wherein the concentration of the aqueous acidic solution prior to step (i) is about 2 M to about 12 M.

24. The method of claim 1 , wherein the ionic liquid is an imidazolium salt, the aqueous hydroxide solution is sodium hydroxide, and the final concentration of sodium hydroxide added in (ii) is about 15 wt % based on the total weight of biphasic system.

25. A method for obtaining fermentable sugar monomers from a lignocellulosic material, comprising:
(i) contacting a lignocellulosic material with an ionic liquid to form a solution of the lignocellulosic material in the ionic liquid, wherein the ionic liquid is an imidazolium salt; and
adding an aqueous acidic solution to the solution of the lignocellulosic material in the ionic liquid to form by acidolysis an aqueous solution comprising sugar monomers and the ionic liquid,
wherein the aqueous acidic solution is a hydrochloric acid solution, a sulfuric acid solution, or a mixture thereof;
(ii) preparing a biphasic system, wherein the method of preparing the biphasic liquid consists of contacting the aqueous solution of sugar monomers and the ionic liquid of (i) with an aqueous hydroxide solution to form a biphasic system which comprises a first phase and a second phase,
wherein the final concentration of hydroxide is at least about 15 wt % based on the total weight of biphasic system,
wherein the first phase is an aqueous ionic liquid phase which is essentially free of sugar monomers, and
wherein the second phase is an aqueous phase comprising sugar monomers;
(iii) separating first phase and the second phase of the biphasic system of (ii), thereby separating the sugar monomers from the ionic liquid; and
(iv) subjecting the second phase obtained in step (iii) to neutralization and desalination.

Assignees

• Univ California
• Sandia Corp
• Nat Tech & Eng Solutions Sandia Llc

Inventors

• Sun Ning
• Holmes Bradley M
• Tran Kim
• George Anthe
• Simmons Blake

Classifications

• C13K1/02 Primary

  obtained by saccharification of cellulosic materials (manufacture of fodder A23K10/32) · CPC title

• C13K13/002

  Xylose · CPC title

• C13K1/04

  Purifying · CPC title