Two-component coating compounds

Patent metadata

Field	Value
Publication number	US-10358576-B2
Application number	US-201615567827-A
Country	US
Kind code	B2
Filing date	Apr 12, 2016
Priority date	Apr 20, 2015
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

The present invention relates to the use of two-component coating compositions comprising isocyanurates of pentamethylene diisocyanate and NCO group reactive compounds with rapid curing and good chemical resistance at temperatures to 80° C.

First claim

The invention claimed is:

1. A method of coating a substrate, comprising
applying to the substrate a coating composition comprising:
a) at least one polyisocyanate obtained from pentamethylene diisocyanate as a precursor;
b) at least one hydroxy-functional poly(meth)acrylate polyol;
c) at least one Lewis base as urethanization catalyst; and
d) at least one organic solvent; and
curing the coating composition at a temperature of 80° C. or less.

2. The method according to claim 1 , wherein the polyisocyanate a) is selected from the group consisting of isocyanurates, urethanes, and allophanates.

3. The method according to claim 1 , wherein the polyisocyanate a) is a polyisocyanate comprising isocyanurate groups.

4. The method according to claim 1 , wherein the polyisocyanate a) has a viscosity of 300-1200 mPa*s (23° C.).

5. The method according to claim 1 , wherein the poly(meth)acrylate polyol b) has a molecular weight M n (number average) of 500 to 50 000.

6. The method according to claim 1 , wherein the coating composition further comprises at least one polyester polyol which has a number-average molecular weight Mn of 500 to 4000 and/or a polydispersity of less than or equal to 5.

7. The method according to claim 6 , wherein the poly(meth)acrylate polyol b) component to the polyester polyol component is in a weight ratio of from 2.7:1 to 20:1, based on the total solids content in the composition.

8. The method according to claim 1 , wherein the Lewis base c) has a pKa of more than 8.

9. The method according to claim 1 , wherein the Lewis base c) is selected from the group consisting of tertiary aliphatic, cycloaliphatic, aromatic amines, amidines, guanidines and ionic liquids comprising amine groups.

10. The method according to claim 1 , wherein the Lewis base c) is a cycloaliphatic amine.

11. The method according to claim 1 , wherein the curing is performed at a temperature in a temperature range from ambient temperature up to 80° C.

12. The method according to claim 1 , wherein the substrate is a building, a vehicle, a wind turbine, a bridge, a power mast, a tank, a container, a pipeline, a power station, a chemical plant, a pool, a roof, furniture, a window, a door, wood flooring, or cardboard.

13. The method according to claim 1 , wherein the substrate is wood, wood veneer, paper, paperboard, cardboard, textile, film, leather, nonwoven fabric, glass, ceramic, mineral building materials, plastics, or metals, each of which may optionally have been already coated and/or pretreated.

14. The method according to claim 1 , wherein the coating composition further comprises at least one of a coating additive, a filler, a dye, and/or a pigment.

15. The method according to claim 1 , wherein the polyisocyanate a) is selected from the group consisting of isocyanurates, urethanes, and allophanates, the polyisocyanate a) having a viscosity of 300-1200 mPa*s (23° C.),
wherein the poly(meth)acrylate polyol b) has a molecular weight M n (number average) of 500 to 50 000, and
wherein the Lewis base c) is a cycloaliphatic amine.

Assignees

• Basf Se

Inventors

• Schaefer Harald
• Binder Horst
• Lucas Frederic
• Emmerling Sebastian

Classifications

• C08G18/73

  acyclic · CPC title

• C08G18/10

  Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step · CPC title

• C08G18/6254

  Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups · CPC title

• B05D3/0254

  After-treatment · CPC title

• C08G18/6229 Primary

  Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols · CPC title