Low EFO polypropylene composition

Patent metadata

Field	Value
Publication number	US-10358546-B2
Application number	US-201615743051-A
Country	US
Kind code	B2
Filing date	Jul 27, 2016
Priority date	Jul 31, 2015
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

Polymer composition comprising at least one polypropylene homopolymer and/or random copolymer, up to 15 wt % of at least one polyethylene, optionally at least one elastomer in an amount of 8 to 40 wt % and optionally fillers and/or additives in an amount of up to 45 wt % based on the total weight of the final polymer composition with the at least one polyethylene having a density of higher than 940 kg/m3, a content of hexane hot extractables of below 0.80 wt % preferably below 0.60 wt %, most preferably below 0.40 wt % and a copolymer/homopolymer (COHO) ratio measured by Temperature Rising Elution Fraction (TREF) up to 6%.

First claim

The invention claimed is:

1. A polymer composition comprising:
a) one or more of at least one polypropylene homopolymer or random copolymer,
b) from 0.1 up to 15 wt % of at least one polyethylene,
c) optionally at least one elastomer in an amount of 8 to 40 wt % and
d) optionally one or more of fillers or additives in an amount of up to 45 wt % based on the total weight of the final polymer composition
with the at least one polyethylene having a density of higher than 940 kg/m 3 , a content of hexane hot extractables of below 0.80 wt %, and a copolymer/homopolymer (COHO) ratio measured by Temperature Rising Elution Fraction (TREF) of up to 6%.

2. The polymer composition according to claim 1 comprising:
a) one or more of at least one polypropylene homopolymer or random copolymer,
b) 5 to 15 wt % of at least one polyethylene having a density of higher than 940 kg/m 3 , a content of hexane hot extractables of below 0.80 wt % and a copolymer/homopolymer ratio (COHO ratio) measured by Temperature Rising Elution Fraction (TREF) up to 6%,
c) an elastomer in an amount of 10 to 30 wt %,
d) up to 30 wt % fillers and
e) up to 4 wt % additives, based on the total weight of the final polymer composition.

3. The polymer composition according to claim 1 , comprising:
a) one or more of at least one polypropylene homopolymer or random copolymer,
b) 5 to 15 wt % of at least one polyethylene having a density of higher than 940 kg/m 3 , a content of hexane hot extractables of below 0.80 wt % and a copolymer/homopolymer ratio (COHO ratio) measured by Temperature Rising Elution Fraction (TREF) up to 6%,
c) an elastomer in an amount of 10 to 30 wt %,
d) 5 to 30 wt % talc as a filler and
e) up to 4 wt % additives comprising 2 to 3 wt % of a colour masterbatch and 1 wt % of other additives, based on the total weight of the final polymer composition.

4. The polymer composition according to claim 1 , wherein the one or more of at least one polypropylene homopolymer or random copolymer has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 1 to 1000 g/10 min.

5. The polymer composition according to claim 1 , wherein the content of the xylene cold soluble (XCS) fraction of the one or more of at least one polypropylene homopolymer or random copolymer is in the range of 0.1 to 6 wt %.

6. The polymer composition according to claim 1 , wherein the at least one polypropylene has a glass transition temperature (Tg) in the range of −10 to +10° C.

7. The polymer composition according to claim 1 , wherein the at least one polyethylene has a molar-mass dispersity DM of 2.5-4.

8. The polymer composition according to claim 1 , wherein the at least one polyethylene has a comonomer content of 0 to 0.5 wt % based on the weight of the at least one polyethylene component.

9. The polymer composition according to claim 1 , wherein the at least one polyethylene has a MFR 2 (190° C.) measured according to ISO 1133 of 0.2 to 15 g/10 min.

10. The polymer composition according to claim 1 , wherein the at least one elastomer has been produced in the polymerization reaction step with ethylene or higher α-olefins like C 4 to C 8 being used as comonomers to the one or more of polypropylene homopolymer or random copolymer and wherein a heterophasic copolymer is obtained.

11. The polymer composition according to claim 1 , wherein the MFR 2 (230° C.) measured according to ISO 1133 of the polymer composition is in the range of 5-100 g/10 min.

12. The polymer composition according to claim 1 , wherein the polymer composition contains up to 1 wt % of a slip agent based on the total weight of the final polymer composition.

13. A method comprising producing polymer compositions with at least one polyethylene, the at least one polyethylene having a density of higher than 940 kg/m 3 , a content of hexane hot extractables of below 0.80 wt % and a copolymer/homopolymer (COHO) ratio measured by Temperature Rising Elution Fraction (TREF) of up to 6%, the polymer compositions having a scratch resistance of below 3, an odour value of below 3.5 and a simultaneous increase of the FOG value of not more than 40%, the VOC value of not more than 35% and the Fogging of not more than 300% compared to the polymer matrix material.

14. A method comprising producing articles with reduced EFO with a polymer composition according to claim 1 .

15. An article comprising a polymer composition, the polymer composition comprising:
a) one or more of at least one polypropylene homopolymer or random copolymer,
b) from 0.1 up to 15 wt % of at least one polyethylene,
c) optionally at least one elastomer in an amount of 8 to 40 wt % and
d) optionally one or more of fillers or additives in an amount of up to 45 wt % based on the total weight of the final polymer composition
with the at least one polyethylene having a density of higher than 940 kg/m 3 , a content of hexane hot extractables of below 0.80 wt %, and a copolymer/homopolymer (COHO) ratio measured by Temperature Rising Elution Fraction (TREF) of up to 6%.

16. The polymer composition according to claim 1 , wherein the content of hexane hot extractables is below 0.60 wt %.

17. The polymer composition according to claim 1 , wherein the content of hexane hot extractables is below 0.40 wt %.

18. The method according to claim 13 , wherein the at least one polyethylene has a content of hexane hot extractables of below 0.60 wt %.

19. The method according to claim 13 , wherein the at least one polyethylene has a content of hexane hot extractables of below 0.40 wt %.

20. The article according to claim 15 , wherein the article is an automotive interior or a houseware article.

Assignees

• Borealis Ag

Inventors

• Wang Jingbo
• Kniesel Claudia
• Doshev Petar
• Prades Floran

Classifications

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L23/12 Primary

  Polypropene · CPC title

• C08L23/06

  Polyethylene · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• C08L2203/00

  Applications · CPC title