Process and system for reducing volatile compound emissions from a product

Patent metadata

Field	Value
Publication number	US-10358540-B2
Application number	US-201715618550-A
Country	US
Kind code	B2
Filing date	Jun 9, 2017
Priority date	Jun 9, 2017
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

Volatile compound emissions from a product that comprises a polymeric material may be reduced or eliminated from the product by heating the product in a subatmospheric pressure environment. The product may be heated in the subatmospheric pressure environment at a temperature sufficient to vaporize a volatile compound contained within the polymeric material such that vapors of the volatile compound are extracted or released from the product.

First claim

What is claimed is:

1. A process for reducing volatile compound emissions from a product, the process comprising:
positioning a product comprising a polymeric material in a chamber;
establishing a subatmospheric pressure environment within the chamber;
heating the product within the chamber to a temperature sufficient to vaporize a volatile compound contained within the polymeric material; and
withdrawing a gaseous stream comprising vapors of the volatile compound from the chamber, and
wherein the product comprises at least one of a vehicle body panel or a vehicle shell.

2. The process set forth in claim 1 wherein the polymeric material comprises at least one polymer or copolymer selected from the group consisting of: acetals; acrylics; acrylonitrile-butadiene-styrene; alkyds; diallyl phthalate; epoxy; fluorocarbons; melamine-formaldehyde; nitrile resins; phenolics; polyamides; polyamide-imide; poly(aryl ether); polycarbonate; polyesters; polyimides; polymethylpentene; polyolefins; polyphenylene oxide; polyphenylene sulfide; polyurethanes; silicones; styrenics; sulfones; urea-formaldehyde; vinyls; and combinations thereof.

3. The process set forth in claim 1 wherein the volatile compound comprises a compound having a normal boiling point less than 100° C. at standard atmospheric pressure.

4. The process set forth in claim 1 wherein the volatile compound comprises a compound having a normal boiling point greater than or equal to 100° C. at standard atmospheric pressure and a vapor pressure less than or equal to 5 mmHg at 20° C.

5. The process set forth in claim 4 wherein the product is heated in step (c) at a temperature below the normal boiling point of the volatile compound.

6. The process set forth in claim 1 wherein the volatile compound comprises an organic compound.

7. The process set forth in claim 1 wherein the product comprises a fiber reinforced polymer.

8. The process set forth in claim 7 wherein the volatile compound comprises a styrenic compound, a subatmospheric pressure of less than or equal to 2 mmHg is established within the chamber, and the product is heated in step (c) at a temperature greater than or equal to 150° C.

9. The process set forth in claim 1 wherein the polymeric material comprises a polymeric adhesive or sealer.

10. The process set forth in claim 9 wherein the volatile compound comprises an organic solvent or a plasticizer, a subatmospheric pressure of less than or equal to 2 mmHg is established within the chamber, and the product is heated in step (c) at a temperature greater than or equal to 125° C.

11. The process set forth in claim 1 wherein the volatile compound comprises a compound having a heat of vaporization in the range of 5 kJ/mol to 150 kJ/mol.

12. The process set forth in claim 1 comprising:
condensing at least a portion of the vapors withdrawn from the chamber to a liquid phase to produce a liquid condensate comprising the volatile compound.

13. The process set forth in claim 1 comprising: delivering the liquid condensate comprising the volatile compound to a storage tank.

14. A system for reducing volatile compound emissions from products, the system comprising:
a distillation chamber configured to enclose a product comprising a polymeric material, wherein the product comprises at least one of a vehicle body panel, a vehicle shell, a polymeric adhesive or sealer applied to a vehicle body panel, or a combination thereof;
a vacuum pump configured to establish a subatmospheric pressure environment in the distillation chamber;
a heater configured to heat the product within the distillation chamber to a temperature sufficient to vaporize a volatile compound embodied in the polymeric material; and
a condenser configured to receive a gaseous stream comprising vapors of the volatile compound from the distillation chamber and to convert at least a portion of the vapors to a liquid phase.

15. The process set forth in claim 1 wherein the product is heated in step (c) at a temperature greater than or equal to 50° C. and less than or equal to 175° C.

16. The process set forth in claim 1 wherein the product is heated in step (c) at a temperature of 152° C.

17. The process set forth in claim 1 wherein the volatile compound comprises a saturated hydrocarbon, an unsaturated hydrocarbon, an aromatic hydrocarbon, a halogenated hydrocarbon, formic acid, methanol, or a combination thereof.

18. A process for reducing volatile compound emissions from a product, the process comprising:
positioning a product comprising a polymeric material in a chamber;
establishing a subatmospheric pressure environment within the chamber;
heating the product within the chamber to a temperature sufficient to vaporize a volatile compound contained within the polymeric material; and
withdrawing a gaseous stream comprising vapors of the volatile compound from the chamber, and
wherein the product comprises a polymeric adhesive or sealer applied to a vehicle body panel.

19. The process set forth in claim 18 wherein the volatile compound comprises an organic solvent, and wherein the organic solvent comprises an alcohol, acetate, saturated, unsaturated, or aromatic hydrocarbon, ether, ester, or a combination thereof.

20. The process set forth in claim 18 wherein the volatile compound comprises a plasticizer, and wherein the plasticizer comprises an adipate, azelate, benzoate, epoxy, ester, mellitate, trimellitate, phosphate, phthalate, polybutene, sebacate, sulfonamide, terephthalate, orthophthalate, or a combination thereof.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Chapaton Thomas J
• Reeder Wayne E

Classifications

• B01D3/14

  Fractional distillation {or use of a fractionation or rectification column} · CPC title

• B01D3/06

  Flash distillation · CPC title

• C08J11/02 Primary

  of solvents, plasticisers or unreacted monomers · CPC title

• B01D1/0017

  Use of electrical or wave energy (B01D1/0029 takes precedence) · CPC title

• B29C71/00 Primary

  After-treatment of articles without altering their shape; Apparatus therefor (B29C44/56, B29C73/00 take precedence; surface shaping B29C59/00 {; for joined or sealed parts B29C66/03; after-treatment specially adapted for vulcanising tyres B29D30/0633}) · CPC title