Process and apparatus for producing fluorinated alkenes

Patent metadata

Field	Value
Publication number	US-10358402-B2
Application number	US-201515516124-A
Country	US
Kind code	B2
Filing date	Sep 30, 2015
Priority date	Oct 1, 2014
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

Provided is a process for producing fluorinated alkenes by providing a microwave plasma in a reactor chamber, introducing a protective gas feed into the reactor chamber, and contacting a conversion feed comprising at least one fluorinated linear or branched alkane with the plasma. Also provided are an apparatus and the use of the process and the apparatus.

First claim

The invention claimed is:

1. A process for producing fluorinated alkenes, the process comprising:
a) providing a microwave plasma, forming a reaction zone in a reactor comprising a reactor chamber at least partially confined by a reactor wall, wherein the reactor chamber has
a substantially circular cross-section with a diameter and a length, which length is perpendicular to the cross-section and is equal to or greater than the diameter, and
a longitudinal axis running parallel to the length in a central part of the reactor chamber;

b) providing a protective gas feed in the reactor chamber, and
c) contacting a conversion feed comprising at least one fluorinated linear or branched alkane having from 1 to 10 carbon atoms with the plasma to produce a product stream containing a fluorinated alkene;
 wherein the protective gas feed in the reactor chamber flows such that the protective gas feed creates or supports to create a reaction zone that extends in an axial direction along the longitudinal axis of the reactor chamber and wherein the reaction zone is confined in a radial direction, which is perpendicular to the axial direction, to the central part of the reactor chamber such that the reaction zone does not contact the reactor wall.

2. The process according to claim 1 , wherein the plasma is generated by a microwave source arranged outside the reactor chamber and the reactor wall comprises a zone which is transparent to microwaves.

3. The process according to claim 1 , wherein the protective gas comprises at least one compound selected from the group consisting of helium, neon, argon, nitrogen, fluorinated alkanes, hydrogen, steam, and a combination of two or more thereof.

4. The process according to claim 1 , wherein the protective gas feed is introduced into the reactor chamber at an angle with respect to the longitudinal axis, of from 45° to 110°, and further wherein the conversion feed is directed along the longitudinal axis.

5. The process according to claim 1 , wherein the plasma is generated by a frequency of 915 MHz or 2.45 GHz or 5.8 GHz.

6. The process according to claim 1 , wherein the conversion feed comprises the at least one fluorinated linear or branched alkane in a gaseous state.

7. The process according to claim 1 , wherein the conversion feed has a residence time in the plasma in the range of from 1 to 10 ms.

8. The process according to claim 1 , wherein the concentration of the at least one fluorinated linear or branched alkane in the conversion feed is in the range of from 50 to 80 vol %.

9. The process according to claim 1 , wherein the protective gas feed and the conversion feed are introduced into the reactor chamber at a flow rate ratio of flow rate of the protective gas feed to the flow rate of the conversion feed of from 50 to 700.

10. The process according to claim 1 , wherein the pressure in the reactor chamber under continuous operating conditions is kept in the range of from 0.8 to 1.2 bar.

11. The process according to claim 1 , additionally comprising:
d) quenching the product stream comprising the fluorinated alkene.

12. The process according to claim 11 , wherein in step d) the product stream is quenched with water or an aqueous solution, wherein the aqueous solution comprises hydrofluoric acid, potassium hydroxide, sodium hydroxide or calcium hydroxide.

13. The process according to claim 11 , wherein the product stream is cooled with a cooling rate in the range of from 100 K/s to 1,000 K/s.

Assignees

• 3M Innovative Properties Co

Inventors

• Zipplies Tilman C
• Hintzer Klaus
• Willert-Porada Monika A
• Gerdes Thorsten
• Herdegen Jens
• Schmidt-Rodenkirchen Achim
• Aschauer Stephan

Classifications

• C07C17/361 Primary

  by reactions involving a decrease in the number of carbon atoms · CPC title

• C07C17/23 Primary

  by dehalogenation · CPC title

• B01J2219/0875

  Gas · CPC title

• B01J19/088

  giving rise to electric discharges (for heating purposes H05B7/00; for the production of ozone C01B13/11, H01T19/00) · CPC title

• B01J2219/1293

  Single source · CPC title