Process for recovering para-xylene using a metal organic framework adsorbent in a simulated moving-bed process

Patent metadata

Field	Value
Publication number	US-10358401-B2
Application number	US-201615747951-A
Country	US
Kind code	B2
Filing date	Jul 29, 2016
Priority date	Sep 17, 2015
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

Para-xylene is separated from a mixture of C8 aromatics using a simulated moving bed (SMB) adsorption process, wherein a MOF is used as an adsorbent and an alkane or alkene having 7 or less carbon atoms, such as hexane or heptane is used as desorbent. Because of the difference in boiling points of a hexane or heptane desorbent as compared to conventional desorbents such as toluene or para-diethylbenzene, less energy is required to separate hexane or heptane from C8 aromatics by distillation than the energy required to separate toluene or diethylbenzene from C8 aromatics by distillation.

First claim

The invention claimed is:

1. A process for separating para-xylene from a mixture of para-xylene and at least one other C8 aromatic by simulated moving-bed adsorptive separation, said process comprising the steps of:
(a) introducing a feed stream, which comprises para-xylene and at least one other C8 aromatic, into a simulated moving-bed adsorptive apparatus, wherein said simulated moving-bed adsorptive apparatus comprises multiple beds containing adsorbent material;
(b) introducing a desorbent stream, which comprises desorbent, into the simulated moving-bed adsorptive apparatus;
(c) withdrawing an extract stream, which comprises desorbent and para-xylene, from the simulated moving-bed adsorptive apparatus;
(d) withdrawing at least one raffinate stream, which comprises desorbent and at least one C8 aromatic, which is different from the para-xylene in the extract stream of step (c), from the simulated moving-bed adsorptive apparatus;
(e) maintaining a flow of circulating fluid throughout the simulated moving-bed adsorptive apparatus; and
(f) switching the flow of streams into and out of the simulated moving-bed adsorptive apparatus to a bed downstream in terms of the direction of the circulating fluid at a set time interval,
wherein the desorbent stream of step (b) comprises at least 50 wt % of one or a mixture of linear or branched alkanes or alkenes having 7 or less carbon atoms, and
wherein the adsorbent material of step (a) comprises a para-xylene selective Metal Organic Framework (MOF) selected from the group consisting of MIL-140b, ZIF-8 and MOF-48.

2. The process of claim 1 , wherein the desorbent stream of step (b) comprises at least 90 wt % of one or a mixture of linear or branched alkanes or alkenes having 7 or less carbon atoms.

3. The process of claim 1 , wherein the desorbent stream of step (b) comprises at least 50 wt % of a naphtha cut, that is free of sulfur and nitrogen contaminants, and having an initial boiling point of 50° C. or more and final boiling point of 110° C. or less.

4. The process of claim 1 , wherein the desorbent stream of step (b) comprises at least 90 wt % of at least one linear alkane selceted from the group consisting of n-hexane and n-heptane.

5. The process of claim 1 , wherein the desorbent stream of step (b) comprises at least 99 wt % of n-hexane.

6. The process of claim 1 , wherein the desorbent stream of step (b) comprises at least 99 wt % of n-heptane.

7. The process of claim 1 , wherein the mixture of at least two aromatics comprises para-xylene, meta-xylene, ortho-xylene and ethylbenzene, and wherein the raffinate stream of step (d) comprises meta-xylene, ortho-xylene and ethylbenzene.

8. The process of claim 7 further comprising the steps of:
(g) passing the raffinate stream from step (d) to a distillation zone;
(h) maintaining the distillation zone of step (g) under conditions sufficient to obtain an overhead stream comprising desorbent and a bottoms stream comprising meta-xylene, ortho-xylene and ethylbenzene;
(i) using at least a portion of the overhead stream of step (h) as desorbent in step (b);
(j) passing at least a portion of the bottoms stream from step (h) to an isomerization zone;
(k) maintaining the isomerization zone of step (j) under conditions sufficient to produce a product stream comprising para-xylene; and
(l) using at least a portion of the para-xylene in the product stream from step (k) as a portion of the feed stream in step (a).

9. The process of claim 7 , wherein the bottoms stream from step (h) comprises at least a portion of the C7− alkane or alkene introduced into the distillation zone of step (h);
wherein the isomerization zone of step (k) is maintained under vapor phase conditions; and
wherein C7− alkane or alkene is cracked in the isomerization zone of step (k).

10. A process for separating para-xylene from a mixture of para-xylene, meta-xylene, ortho-xylene and ethylbenzene by simulated moving-bed adsorptive separation in a simulated moving-bed adsorption apparatus comprising multiple beds containing adsorbent material, including a step of introducing the mixture into the apparatus, introducing a desorbent stream into the apparatus, withdrawing an extract stream from the apparatus and withdrawing at least one raffinate stream from the apparatus, the improvement comprising using a para-xylene selective Metal Organic Framework (MOF) selected from the group consisting of MIL-140b, ZIF-8and MOF-48 as the adsorbent material and at least 50 wt % of one or a mixture of linear or branched alkanes or alkenes having 7 or less carbon atoms for the desorbent stream.

11. The process of claim 10 , wherein the desorbent stream of step (b) comprises at least 90 wt % of at least one linear alkane selceted from the group consisting of n-hexane and n-heptane.

12. The process of claim 10 , wherein the desorbent stream of step (b) comprises at least 99 wt % of n-hexane.

13. The process of claim 10 , wherein the desorbent stream of step (b) comprises at least 99 wt % of n-heptane.

Assignees

• Exxonmobil Chemical Patents Inc
• Georgia Tech Res Inst

Inventors

• Rungta Meha
• Abichandani Jeevan S
• Pilliod Dana L
• Tinger Robert G
• Go Anthony
• Zhang Ke
• Nair Sankar
• Gee Jason
• Sholl David

Classifications

• Y02P20/57

  Cross-Sectional Technologies · mapped topic

• B01D15/1828

  characterised by process features · CPC title

• C07C7/04

  by distillation · CPC title

• B01D15/185

  characterised by the components to be separated · CPC title

• C07C5/2732

  Catalytic processes · CPC title