MTO process for enhanced production of propylene and high value products

Patent metadata

Field	Value
Publication number	US-10358394-B2
Application number	US-201715617934-A
Country	US
Kind code	B2
Filing date	Jun 8, 2017
Priority date	Dec 11, 2014
Publication date	Jul 23, 2019
Grant date	Jul 23, 2019

Abstract

A process is presented for the production of light olefins. The process utilizes a SAPO-18 catalyst and is operated at an elevated pressure. The process generates higher concentrations of heavier olefins which can then be processed to generate light olefins. The processing of the heavier olefins can include metathesis reactions and olefin cracking processes.

First claim

The invention claimed is:

1. A process for the production of light olefins from an oxygenate feed comprising at least one of an alcohol, an aldehyde and/or an ether, the process comprising passing the oxygenate feed to a single OTO reactor, wherein the reactor comprises a catalyst comprising SAPO-18 having a Si content of less than 4-wt. % wherein the catalyst occupies greater than 15 volume % of the reactor and wherein the reactor is operated at reaction conditions including a partial pressure of the oxygenate of from greater than 310 kPa to 1.3 MPa, a temperature of from about 375° C. to about 475° C., and a WHSV of from about 3 to about 7 hr −1 to generate an effluent stream comprising ethylene, propylene, and butenes, with a butenes to ethylene weight ratio of about 2:1 or greater;
passing the effluent stream to a quench tower to generate a water stream and a dewatered effluent stream;
passing the dewatered effluent stream to a compressor to generate a compressed stream;
passing the compressed stream to a DME recovery unit to generate a DME stream and a DME olefins stream;
passing the DME olefins stream to a light olefins recovery unit to generate an ethylene stream, a propylene stream, a C4 olefin stream, a C5 olefin stream and a C6+ heavies stream; and
passing a portion or all of the C5 olefin stream and a portion or all of the ethylene stream to a metathesis reactor, thereby generating a metathesis stream comprising mostly propylene and butenes.

2. The process of claim 1 wherein the MTO reactor is a fluidized bed.

3. The process of claim 1 wherein the oxygenate feed comprises methanol and dimethyl ether.

4. The process of claim 1 wherein the oxygenate feed comprises methanol.

5. The process of claim 1 wherein a process pressure and temperature are set to provide a desired distribution of ethylene, propylene, and butenes.

6. The process of claim 1 further comprising passing the C4 olefin stream to a C4 separation unit to generate an isobutene stream and normal butene stream.

7. The process of claim 6 further comprising passing the normal butene stream to an oxidative dehydrogenation reactor, thereby generating an on purpose butadiene stream consisting of butadiene.

8. The process of claim 1 further comprising passing the C6+ heavies stream to an olefin cracking unit to generate an olefins cracking effluent stream comprising light olefins.

9. The process of claim 8 further comprising passing the olefins cracking effluent stream to the light olefins recovery unit.

Assignees

• Uop Llc

Inventors

• Chellppannair Thulasidas
• Schoenfeldt Nicholas J
• Bozzano Andrea G
• Spieker Wolfgang A
• Digiulio Christopher D
• Funk Gregory A
• Moscoso Jaime G

Classifications

• Y02P20/584

  Recycling of catalysts · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C07C2529/85

  Silicoaluminophosphates (SAPO compounds) · CPC title

• C07C6/04

  at a carbon-to-carbon double bond · CPC title

• C07C4/06

  Catalytic processes {(C07C4/025 takes precedence)} · CPC title