Electrochemical energy storage device

Patent metadata

Field	Value
Publication number	US-10354808-B2
Application number	US-201615010330-A
Country	US
Kind code	B2
Filing date	Jan 29, 2016
Priority date	Jan 29, 2015
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

An electrochemical energy storage device includes an anode having a first mixture which includes a first plurality of electrically conductive carbon-comprising particles having a first average porosity, and lithium metal materials. The weight ratio of the first plurality of carbon-comprising and lithium metal materials is from 30:1 to 3:1. A cathode includes a second mixture having a second plurality of electrically conductive carbon-comprising particles having a second average porosity greater than the first average porosity, and lithium-intercalating metal oxide particles. The weight ratio of the second plurality of carbon-comprising and lithium-intercalating metal oxide particles is from 1:20 to 5:1. The weight ratio between the lithium metal materials loaded in the anode and the second plurality of carbon-comprising particles in the cathode is from 0.1-10%. An electrolyte physically and ionically contacts the anode and the cathode, and fills the pore volume in the anode, cathode and a porous separator.

First claim

We claim:

1. A method of producing an electrochemical energy storage device, comprising:
an anode produced from disposing a first mixture on a first current collector, the first mixture comprising a plurality of lithium metal materials and a first plurality of lithium-intercalating electrically conductive carbon-comprising particles, the weight ratio of carbon-comprising and lithium metal materials being from 30:1 to 3:1;
a cathode produced from disposing a second mixture on a second current collector, the second mixture comprising a second plurality of electrically conductive carbon-comprising particles and lithium-intercalating metal oxide particles, the weight ratio of carbon-comprising and lithium-intercalating metal oxide particles being from 1:20 to 5:1;
wherein the weight ratio between the lithium metal materials in the anode and the second plurality of electrically conductive carbon comprising particles in the cathode is from 0.1-10%; and,
providing a housing and positioning within the housing the first current collector, second current collector, with an electrically insulating porous separating layer there between; and,
introducing an electrolyte into said housing;
wherein the first mixture in an initial state further comprises two layers, comprising a layer of lithium metal materials and a layer of the first plurality of carbon-comprising particles.

2. The method of claim 1 , wherein the weight ratio between the lithium metal materials in the anode and the second plurality of carbon-comprising particles in the cathode is from 0.3-5%.

3. The method of claim 1 , wherein the weight ratio between the lithium metal materials in the anode and the second plurality of carbon-comprising particles in the cathode is from 0.6-1.7%.

4. The method of claim 1 , wherein the second plurality of carbon-comprising particles in the cathode has an electrical conductivity greater than 1 S/cm.

5. The method of claim 1 , wherein the second plurality of carbon-comprising particles in the cathode has a specific surface area greater than 500 m 2 /g.

6. The method of claim 1 , wherein the second plurality of carbon-comprising particles in the cathode has a specific capacitance greater than 50 F/g.

7. The method of claim 1 , wherein the second plurality of carbon-comprising particles in the cathode has a porosity greater than 50%.

8. The method of claim 1 , wherein the weight ratio of the first plurality of carbon-comprising particles and lithium metal materials in the anode is from 20:1 to 8:1.

9. The method of claim 1 , wherein the weight ratio of the first plurality of carbon-comprising particles and lithium metal materials in the anode is from 17:1 to 11:1.

10. The method of claim 1 , wherein the weight ratio of the second plurality of carbon-comprising particles and lithium-intercalating metal oxide particles in the cathode is from 1:5 to 3:1.

11. The method of claim 1 , wherein the weight ratio of the second plurality of carbon-comprising particles and lithium-intercalating metal oxide particles in the cathode is from 1:2 to 2:1.

12. The method of claim 1 , wherein the first plurality of carbon-comprising particles in the anode comprises at least one selected from the group consisting of hard carbon, soft carbon, graphitic carbon, carbon black, carbon microbeads, carbon nanotubes, and carbon nanofibers.

13. The method of claim 1 , wherein the second plurality of carbon-comprising particles in the cathode comprises at least one selected from the group consisting of activated carbon, carbon microbeads, carbon black, carbon nanotubes, activated carbon nanotubes, and activated carbon nanofibers.

14. The method of claim 1 , wherein the lithium metal oxide particles comprise at least one selected from the group consisting of LiCoO 2 (lithium cobalt oxide), LiNi 0.8 Co 0.15 Al 0.05 O 2 (NCA), LiMn 2 O 4 (spinel), LiV 3 O 8 , LiNi1 /3 Mn 1/3 Co 1/3 O 2 (NMC 333), LiMn x Co y Ni z O 2 (NMC non-stoichiometric), where x+y+z=1, LiFePO 4 (lithium iron phosphate), xLi 2 MnO 3 .(1−x)LiMO 2 , LiNi 1/3 Mn 1/3 Co 1/3 O 2 , LiNi 1/3 Mn 1/3 Co 1/3 O 2 , Li[Li 0.2 Mn 0.54 Ni 0.13 Co 0.13 ]O 2 , and Li[Li 0.2 Mn 0.54 Ni 0.13 C o0.13 ]O 2 .

15. The method of claim 1 , wherein the first mixture in an initial state further comprises a plurality of lithium metal materials mixed with said first plurality of carbon-comprising particles, and wherein the first plurality of carbon-comprising particles in the initial state are substantially free of lithium ions.

16. The method of claim 1 , wherein the layer of lithium metal materials at the initial state is positioned between the layer of the first plurality of carbon-comprising particles and the separating layer.

17. The method of claim 1 , wherein the layer of lithium metal materials at the initial state is positioned between the first plurality of electrically conductive carbon and the current collector.

18. The method of claim 1 , wherein the second mixture in an initial state further comprises lithium-intercalating metal oxide particles mixed with the second plurality of carbon-comprising particles.

19. A method of producing an electrochemical energy storage device, comprising:
an anode produced from disposing a first mixture on a first current collector, the first mixture comprising a plurality of lithium metal materials and a first plurality of lithium-intercalating electrically conductive carbon-comprising particles, the weight ratio of carbon-comprising and lithium metal materials being from 30:1 to 3:1;
a cathode produced from disposing a second mixture on a second current collector, the second mixture comprising a second plurality of electrically conductive carbon-comprising particles and lithium-intercalating metal oxide particles, the weight ratio of carbon-comprising and lithium-intercalating metal oxide particles being from 1:20 to 5:1;
wherein the weight ratio between the lithium metal materials in the anode and the second plurality of electrically conductive carbon comprising particles in the cathode is from 0.1-10%;
providing a housing and positioning within the housing the first current collector, second current collector, with an electrically insulating porous separating layer there between; and,
introducing an electrolyte into said housing;
wherein the second mixture in an initial state further comprises two layers comprising a layer of the lithium-intercalating metal oxide particles and a layer of the second plurality of carbon-comprising particles.

20. A method of producing an electrochemical energy storage device, comprising:
an anode produced from disposing a first mixture on a first current collector, the first mixture comprising a plurality of lithium metal materials and a first plurality of lithium-intercalating electrically conductive carbon-comprising particles, the weight ratio of carbon-comprising and lithium metal materials being from 30:1 to 3:1;
a cathode produced from disposing a second mixture on a second current collector, the second mixture comprising a second plurality of electrically conductive carbon-comprising particles and lithium-intercalating metal oxide particles, the weight ratio of carbon-comprising and lithium-intercalating metal oxide particles being from 1:20 to 5:1;
wherein the weight ratio between the lithium metal materials in the anode and the second plurality of electrically conductive carbon comprising particles in the cathode is from 0.1-10%;
providing a housing and positioning within the housing the first current collector, second current co

Assignees

• Univ Florida State Res Found

Inventors

• Zheng Jian-Ping
• Zheng Junsheng

Classifications

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title

• Y02T10/7022

  Cross-Sectional Technologies · mapped topic

• H01M2004/028

  Positive electrodes · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M2004/027

  Negative electrodes · CPC title