Electrostatic image developing toner

Patent metadata

Field	Value
Publication number	US-10353309-B2
Application number	US-201816133027-A
Country	US
Kind code	B2
Filing date	Sep 17, 2018
Priority date	Jun 17, 2015
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

Provided is an electrostatic image developing toner comprising a toner base particle containing a binder resin and a releasing agent, wherein the binder resin comprises an amorphous vinyl resin and a crystalline polyester resin; a weight-average molecular weight of the electrostatic image developing toner is in the range of 50000 to 90000, when calculated from a chromatogram which represents a molecular weight distribution and is measured by gel permeation chromatography; a ratio of content of a resin component having a molecular weight of 100000 or more is in the range of 10 to 20% by area, in the chromatogram which represents the molecular weight distribution; the crystalline polyester resin has a melting point in the range of 65 to 85° C.; and, a ratio of content of the crystalline polyester resin in the binder resin is in the range of 5 to 20% by mass.

First claim

What is claimed is:

1. An electrostatic image developing toner comprising a toner base particle containing a binder resin and a releasing agent, wherein
the binder resin comprises an amorphous vinyl resin and a crystalline polyester resin;
a weight-average molecular weight of the electrostatic image developing toner is in the range of 50000 to 90000, when calculated from a chromatogram which represents a molecular weight distribution and is measured by gel permeation chromatography;
a ratio of content of a resin component having a molecular weight of 100000 or more is in the range of 10 to 20% by area, and a ratio of content of a resin component having a molecular weight of 300000 or more is in the range of 1.2 to 9% by area, in the chromatogram which represents the molecular weight distribution of the toner;
the crystalline polyester resin has a melting point in the range of 65 to 85° C.; and,
a ratio of content of the crystalline polyester resin in the binder resin is in the range of 5 to 20% by mass.

2. The electrostatic image developing toner of claim 1 , wherein a ratio of content of the amorphous vinyl resin in the binder is 50% by mass or more.

3. The electrostatic image developing toner of claim 1 , wherein the crystalline polyester resin is a single polymer synthesized by a polycondensation reaction between a polyhydric alcohol component and a polycarboxylic acid component.

4. The electrostatic image developing toner of claim 1 , wherein the crystalline polyester resin is a hybrid crystalline polyester resin having copolymerized therein a crystalline polyester resin unit synthesized by a polycondensation reaction between a polyhydric alcohol component and a polycarboxylic acid component, and an amorphous resin unit other than polyester resin.

5. The electrostatic image developing toner of claim 4 , wherein the amorphous resin unit is a vinyl resin unit.

6. The electrostatic image developing toner of claim 4 , wherein the ratio of content of the amorphous resin unit in the hybrid crystalline polyester resin is in the range of 5 to 20% by mass.

7. The electrostatic image developing toner of claim 3 , wherein the number of carbon atoms of the polyhydric alcohol component (C(alcohol)) and the number of carbon atoms of the polycarboxylic acid component C(acid)) satisfy relations represented by Expressions (1) to (3) below:
C(acid)−C(alcohol)≥4  Expression (1)

C(acid)≥10  Expression (2)

C(alcohol)≤6  Expression (3).

8. The electrostatic image developing toner of claim 7 , wherein the number of carbon atoms of the polyhydric alcohol component (C(alcohol)) and the number of carbon atoms of the polycarboxylic acid component (C(acid)) satisfy a relation represented by Expression (4) below:
C(acid)−C(alcohol)≥6  Expression (4).

9. The electrostatic image developing toner of claim 1 , wherein
a weight-average molecular weight of the crystalline polyester resin is in the range of 15000 to 40000, when calculated from a chromatogram which represents a molecular weight distribution and is measured by gel permeation chromatography.

10. The electrostatic image developing toner of claim 3 , wherein the polycarboxylic acid component is dodecane diacid and the polyhydric alcohol component is 1,6-hexanediol.

11. The electrostatic image developing toner of claim 1 , wherein the amorphous vinyl resin is formed from a monomer composition including an acrylic ester-based monomer.

Assignees

• Konica Minolta Inc

Inventors

• Sugama Kouji
• Nagasawa Hiroshi
• Hori Anju
• Ueda Noboru

Classifications

• G03G9/08795

  characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants · CPC title

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/08755 Primary

  Polyesters · CPC title

• G03G9/08711

  with esters of acrylic or methacrylic acid · CPC title

• G03G9/08728 Primary

  Polymers of esters · CPC title