Capillary ionic transistor

Patent metadata

Field	Value
Publication number	US-10352898-B2
Application number	US-201515121440-A
Country	US
Kind code	B2
Filing date	Feb 26, 2015
Priority date	Feb 26, 2014
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

A capillary ionic transistor and method of using is disclosed. The method including providing a capillary pipette (100) having an inner surface defining a channel, and a conductive layer disposed (102) about electrode the channel; filling at least a portion of the channel with an ionic solution (110) such that an electrical double layer forms on the inner surface of the pipette; inducing an electric potential within the ionic solution sufficient to generate a longitudinal flow of ions within the channel; and inducing an electric potential in the conductive layer sufficient to alter the zeta potential of the electrical double layer and adjust the flow of ions within the ionic solution.

First claim

What is claimed is:

1. A method for controlling the transport of ions through a channel, comprising the steps of:
providing a capillary pipette having a narrow portion with an inner surface defining a channel, wherein the narrow portion terminates at a tip having an end, one or more voltage sources connected to a first electrode and a second electrode, the first electrode within the channel, and a conductive layer disposed along the narrow portion and extending to the end of the tip;
positioning at least a part of the narrow portion in a bath of an ionic solution;
wherein the second electrode extends at least partially into the bath of the ionic solution, directly exposed to the ionic solution;
filling at least a portion of the channel with the ionic solution such that an electrical double layer forms on the inner surface of the pipette;
wherein the flow of all moving ions in the ionic solution is only toward the tip of the narrow portion;
inducing an electric potential within the ionic solution, between the first and second electrodes, sufficient to generate a longitudinal flow of ions within the channel;
wherein the moving ions exit the capillary pipette at the tip of the narrow portion; and
inducing an electric potential in the conductive layer sufficient to alter the electrical double layer and adjust the flow of ions within the ionic solution.

2. The method of claim 1 , wherein the capillary pipette is dimensioned such that the electric double layer overlaps at at least one point.

3. The method of claim 1 , wherein the capillary pipette is dimensioned such that the electric double layer will overlap at least one point upon the application of a predetermined potential to the conductive layer.

4. The method of claim 1 , wherein the pipette is dimensioned to narrow at at least one point.

5. The method of claim 4 , wherein the narrow point of the pipette is minimally 10 nm in diameter and maximally 100 nm in diameter.

6. The method of claim 4 , wherein the narrow point is at a tip of the pipette.

7. The method of claim 1 , wherein the potential applied to the conductive layer causes the electrical double layer to widen, reducing the flow of ions within the channel.

8. The method of claim 1 , wherein the potential applied to the conductive layer causes the electrical double layer to narrow, enhancing the flow of current within the channel.

9. The method of claim 1 wherein said conductive layer is comprised of one of chromium, aluminum, copper, or any other material capable of retaining a charge.

10. A device for controlling the transport of ions through a channel, comprising:
a capillary pipette having a narrow portion with an inner surface defining a channel;
wherein the narrow portion terminates at a tip having an end;
one or more voltage sources connected to a first electrode and a second electrode, the first electrode within the channel;
wherein the pipette is adapted to form an electric double layer on the inner surface when filled with an ionic solution;
wherein the device is configured to control the flow of all moving ions in the ionic solution to only toward the tip of the narrow portion;
a bath of the ionic solution, wherein at least part of the narrow portion is submerged within the ionic solution and the second electrode extends at least partially into the bath of the ionic solution, directly exposed to the ionic solution; and
a conductive layer positioned along the narrow portion, extending to the end of the tip, to exhibit an electric field within the channel when subjected to an electric charge, such that any electric double layer on the inner surface will be altered by the electric field;
wherein the device is configured so that all moving ions exit the capillary pipette at the tip of the narrow portion.

11. The device of claim 10 , further comprising a voltage source positioned to induce a longitudinal flow of ions in any ionic fluid at least partially filling the channel.

12. The device of claim 10 , further comprising a voltage source connected to apply a potential to the conductive layer.

13. The device of claim 10 wherein the capillary pipette is dimensioned to cause the electric double layer to overlap when the channel is filled with an ionic solution.

14. The device of claim 10 wherein the capillary pipette 100 is dimensioned to cause the electric double layer to overlap when the channel is filled with an ionic solution and a predetermined potential is applied to the conductive layer.

15. The device of claim 10 , wherein the capillary pipette is dimensioned to narrow at at least one point.

16. The device of claim 15 , wherein the narrow point is at the tip of the pipette.

17. The device of claim 10 , wherein the capillary pipette 100 is minimally 10 nm in diameter and maximally 100 nm in diameter.

18. The device of claim 10 , wherein said conductive layer is comprised of one of chromium, aluminum, copper, or any other material capable of retaining a charge.

Assignees

• Univ Central Florida Res Found Inc
• Univ Of Central Florida Research Foundaing Inc

Inventors

• Rudzevich Yauheni
• Lin Yuqing
• Chow Lee

Classifications

• B01L2400/0415

  electrical forces, e.g. electrokinetic · CPC title

• G01N27/4146

  involving nanosized elements, e.g. nanotubes, nanowires · CPC title

• B01L2300/16

  Surface properties and coatings · CPC title

• G01N27/44752 Primary

  Controlling the zeta potential, e.g. by wall coatings · CPC title

• B01L2300/0838

  Capillaries · CPC title