Sensitive film for neutron detection and method for forming the same

Patent metadata

Field	Value
Publication number	US-10351967-B2
Application number	US-201715843666-A
Country	US
Kind code	B2
Filing date	Dec 15, 2017
Priority date	Dec 26, 2016
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

The present invention provides a method for forming a sensitive film for neutron detection, wherein the sensitive film is formed by electrophoresis coating, the liquid used for electrophoresis coating includes neutron sensitive material, electrophoresis paint and deionized water, and the neutron sensitive material is 10 B single substance, 10 B compound or mixture containing 10 B. The sensitive film for neutron detection has the high detection efficiency because of the high content of 10 B. The sensitive film for neutron detection has the uniform and stable film thickness, and excellent consistency. The production efficiency and the cost of the sensitive film are improved.

First claim

What is claimed is:

1. A method for forming a sensitive film for neutron detection, wherein the sensitive film is formed by electrophoresis coating, a liquid used for electrophoresis coating includes neutron sensitive material, electrophoresis paint and deionized water, and the neutron sensitive material is 10 B single substance, 10 B compound or mixture containing 10 B, and wherein the neutron sensitive material is ground in a grinding step prior to the electrophoresis coating, wherein the grinding step comprises pressing a coarse powder containing boron into grinding balls by sintering at high temperature, and grinding the neutron sensitive material into particles of 0.1 to 5 microns by use of the grinding balls.

2. The method according to claim 1 , wherein the boron compound is 10 B 4 C or 10 B 2 O 3 .

3. The method according to claim 1 , wherein the electrophoresis paint is an anodic electrophoresis paint or a cathodic electrophoresis paint.

4. The method according to claim 3 , wherein the anodic electrophoresis paint is at least one selected from the group consisting of polybutadiene anodic electrophoresis paint and acrylic anodic electrophoresis paint; and the cathodic electrophoresis paint is at least one of epoxy cathodic electrophoresis paint, acrylate cathodic electrophoresis paint and polyurethane cathodic electrophoresis paint.

5. The method according to claim 1 , further comprising removing organic components in the neutron sensitive film by heating after the neutron sensitive film is formed by electrophoresis.

6. The method according to claim 5 , wherein the heating is carried out in an inert or reducing gas atmosphere.

7. A sensitive film for neutron detection, being formed by the method according to claim 1 .

8. The sensitive film for neutron detection according to claim 7 , wherein the thickness of the sensitive film is 1 to 5 microns.

9. A method for forming a sensitive film for neutron detection, wherein the sensitive film is formed by electrophoresis coating, a liquid used for electrophoresis coating includes neutron sensitive material, electrophoresis paint and deionized water, and the neutron sensitive material is 10 B single substance, 10 B compound or mixture containing 10 B, and wherein the neutron sensitive material is ground in a grinding step prior to the electrophoresis coating, wherein the grinding step comprises grinding the neutron sensitive material into particles of 0.1 to 5 microns by use of standard steel balls as grinding balls, and removing an iron composition from the ground neutron sensitive material.

10. The method according to claim 9 , wherein the removing of the iron composition is carried out by acid-washing, ferromagnetic iron, or both of them.

11. The method according to claim 9 , wherein the boron compound is 10 B 4 C or 10 B 2 O 3 .

12. The method according to claim 9 , wherein the electrophoresis paint is an anodic electrophoresis paint or a cathodic electrophoresis paint.

13. The method according to claim 12 , wherein the anodic electrophoresis paint is at least one selected from the group consisting of polybutadiene anodic electrophoresis paint and acrylic anodic electrophoresis paint; and the cathodic electrophoresis paint is at least one of epoxy cathodic electrophoresis paint, acrylate cathodic electrophoresis paint and polyurethane cathodic electrophoresis paint.

14. The method according to claim 9 , further comprising removing organic components in the sensitive film by heating after the sensitive film is formed by electrophoresis.

15. The method according to claim 14 , wherein the heating is carried out in an inert or reducing gas atmosphere.

Assignees

• Nuctech Co Ltd

Inventors

• Wang Yongqiang
• Zhang Qingjun
• Li Yuanjing
• Zhao Ziran
• Chang Jianping
• Wang Yanchun
• Sun Lifeng
• Bai Nan
• Zhai Xingliang

Classifications

• C09D7/61

  inorganic · CPC title

• C25D13/02 Primary

  with inorganic material · CPC title

• C09D5/4488

  Cathodic paints (C09D5/4403 - C09D5/4476 take precedence) · CPC title

• C08K2003/387

  Borates · CPC title

• C25D13/20

  Pretreatment · CPC title