Water decomposition apparatus and water decomposition method

Patent metadata

Field	Value
Publication number	US-10351961-B2
Application number	US-201615392440-A
Country	US
Kind code	B2
Filing date	Dec 28, 2016
Priority date	Aug 1, 2014
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

Provided are a water decomposition apparatus and a water decomposition method that can maintain high gas generation efficiency even in an early stage of light irradiation and even in a case where time has elapsed and that can recover the gas generation amount of hydrogen gas or the like, can generate hydrogen gas or the like stably for a long time on an average, and can increase the integrated amount of generation of hydrogen for a long time, even in a case where time has elapsed and the gas generation amount of hydrogen gas or the like has decreased.

First claim

What is claimed is:

1. A water decomposition apparatus that decomposes an electrolyte aqueous solution into hydrogen gas and oxygen gas by means of light, the water decomposition apparatus comprising:
a hydrogen gas generating part that includes an inorganic semiconductor film having a pn junction and one surface as a light-receiving surface, and a hydrogen generation catalyst and that generates hydrogen gas;
an oxygen gas generating part that is formed on the other surface of the inorganic semiconductor film and generates oxygen gas;
an electrolytic chamber that contains (a) the electrolyte aqueous solution, coming into contact with the hydrogen gas generating part and the oxygen gas generating part, (b) the hydrogen gas generated in the hydrogen gas generating part, and (c) the oxygen gas generated in the oxygen gas generating part; and
a shielding mechanism that is configured to shield at least a portion of light with which the hydrogen gas generating part is irradiated,
wherein the shielding mechanism is configured to shield the hydrogen gas generating part at regular time intervals.

2. The water decomposition apparatus according to claim 1 ,
wherein the shielding mechanism shields 70% or more of the light with which the hydrogen gas generating part is irradiated.

3. The water decomposition apparatus according to claim 1 ,
wherein the shielding mechanism includes a shielding structure, and
wherein the shielding structure moves a light irradiation position where the hydrogen gas generating part is irradiated with light and a shielding position where the hydrogen gas generating part is shielded, at the regular time intervals.

4. The water decomposition apparatus according to claim 1 ,
wherein the shielding mechanism is a rotational movement mechanism that rotationally moves an apparatus body including the hydrogen gas generating part, the oxygen gas generating part, and the electrolytic chamber,
wherein the apparatus body is moved to a light irradiation position where the hydrogen gas generating part is irradiated with light, and a shielding position where the hydrogen gas generating part is shielded, at the regular time intervals by the rotational movement mechanism.

5. The water decomposition apparatus according to claim 1 ,
wherein a photoelectromotive force E (V) between the hydrogen gas generating part and the oxygen gas generating part satisfy the following Formula (1) if a water decomposition starting voltage of the electrolyte aqueous solution is defined as Es (V),
Es ( V )< E ( V )< Es+ 0.6( V )  (1).

6. The water decomposition apparatus according to claim 1 ,
wherein the hydrogen generation catalyst is platinum.

7. The water decomposition apparatus according to claim 1 ,
wherein the electrolyte aqueous solution includes Na 2 SO 4 .

8. The water decomposition apparatus according to claim 1 , further comprising:
a barrier that partitions the electrolytic chamber into a region including the hydrogen gas generating part and a region including the oxygen gas generating part and has ion permeability and gas non-permeability.

9. The water decomposition apparatus according to claim 1 ,
wherein the inorganic semiconductor film includes a copper indium gallium selenide compound semiconductor.

10. The water decomposition apparatus according to claim 1 ,
wherein the inorganic semiconductor film includes a copper zinc tin sulfide compound semiconductor.

11. The water decomposition apparatus according to claim 1 , further comprising:
a controller that controls the shielding mechanism such that a ratio of a shielding time when the hydrogen gas generating part is shielded by the shielding mechanism to a light irradiation time when the hydrogen gas generating part is irradiated with light by the shielding mechanism is 1:2 to 1:100 and the hydrogen gas generating part is shielded at the regular time intervals by the shielding mechanism.

12. A water decomposition method of decomposing an electrolyte aqueous solution into hydrogen gas and oxygen gas by means of light, using a water decomposition apparatus according to claim 1 , the water decomposition method comprising:
shielding at least a portion of light with which the hydrogen gas generating part is irradiated, at the regular time intervals.

13. The water decomposition method according to claim 12 ,
wherein 70% or more of the light with which the hydrogen gas generating part is irradiated is shielded.

14. The water decomposition method according to claim 12 ,
wherein the shielding is performed by moving a shielding structure between a light irradiation position where the hydrogen gas generating part is irradiated with light and a shielding position where the hydrogen gas generating part is shielded, at the regular time intervals.

15. The water decomposition method according to claim 12 ,
wherein the shielding is performed by rotationally moving the water decomposition apparatus between a light irradiation position where the hydrogen gas generating part is irradiated with light and a shielding position where the hydrogen gas generating part is shielded, at the regular time intervals.

16. The water decomposition method according to claim 12 ,
wherein a photoelectromotive force E (V) between the hydrogen gas generating part and the oxygen gas generating part satisfy the following Formula (1) if a water decomposition starting voltage of the electrolyte aqueous solution is defined as Es (V),
Es ( V )< E ( V )< Es+ 0.6( V )  (1).

17. The water decomposition method according to claim 12 ,
wherein the hydrogen generation catalyst is platinum.

18. The water decomposition method according to claim 12 ,
wherein the electrolyte aqueous solution includes Na 2 SO 4 .

19. The water decomposition method according to claim 12 ,
wherein the inorganic semiconductor film includes a copper indium gallium selenide compound semiconductor.

20. The water decomposition method according to claim 12 ,
wherein the inorganic semiconductor film includes a copper zinc tin sulfide compound semiconductor.

21. The water decomposition method according to claim 12 ,
wherein a ratio of a shielding time when the hydrogen gas generating part is shielded by the shielding mechanism to a light irradiation time when the hydrogen gas generating part is irradiated with light by the shielding mechanism is 1:2 to 1:100.

Assignees

• Fujifilm Corp
• Japan Tech Research Association Of Artifical Photosynthetic Chemical Process
• Japan Tech Research Association Of Artificial Photosynthetic Chemical Process

Inventors

• Higashi Kohei
• Sato Naotoshi

Classifications

• C25B15/02

  Process control or regulation · CPC title

• C25B9/00

  Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features · CPC title

• C01B3/042 Primary

  Decomposition of water (by electrolysis of water C25B1/04) · CPC title

• C25B11/04

  characterised by the material · CPC title

• Y02E10/541

  CuInSe2 material PV cells · CPC title