Composition suitable for production of rigid polyurethane or polyisocyanurate foams

Patent metadata

Field	Value
Publication number	US-10351687-B2
Application number	US-201415107732-A
Country	US
Kind code	B2
Filing date	Dec 17, 2014
Priority date	Dec 30, 2013
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

The present invention relates to a composition suitable for production of rigid polyurethane or polyisocyanurate foams, said composition comprising at least one isocyanate component, at least one polyol component, at least one foam stabilizer, at least one urethane and/or isocyanurate catalyst, optionally water and/or blowing agent, and optionally at least one flame retardant and/or further additives, which comprises at least two different varieties 1 and 2 of polyether siloxanes as foam stabilizers, and to the use of this composition for production of foamed polyurethane or polyisocyanurate materials, preferably rigid foams.

First claim

The invention claimed is:

1. A composition suitable for production of rigid polyurethane or polyisocyanurate foams, comprising at least one isocyanate component, at least one isocyanate-reactive component, at least one foam stabilizer, at least one urethane and/or isocyanurate catalyst, optionally water and/or blowing agent, and optionally at least one flame retardant and/or further additives, wherein the composition comprises at least two different varieties of polyether siloxanes as foam stabilizers, wherein one polyether siloxane variety, hereinafter polyether siloxane variety 1, conforms to formula (I)

R 1 =independently alike or different hydrocarbon moieties of 1 to 16 carbon atoms,
R 2 =independently R 1 , R 3 or R 4 ,
wherein R 3 is a polyether moieties of general formula (II),
—R 5 O[CH 2 CH 2 O] g [CH 2 CH(CH 3 )O] h [CHR 6 CHR 7 O] i R 8   (II)

wherein
R 5 is a divalent hydrocarbon moieties of 1 to 16 carbon atoms, which may be interrupted by oxygen atoms, preferably a moiety of general formula (IV)
CH 2 j   (IV)

where j=1 to 8,
R 6 and R 7 are hydrocarbon moieties of 1 to 16 carbon atoms, which may be interrupted by oxygen atoms, or H,
R 8 are hydrocarbon moieties of 1 to 16 carbon atoms, which may be interrupted by urethane functions, —C(O)NH—, carbonyl functions or —C(O)O—, or H,

R 4 independently alike or different moieties of the general formula (IIIa) or (IIIb)

R 9 =a divalent organic moiety, which may optionally be interrupted by one or more oxygen functions or functions of the formula —[SiR 1 2 —O] k —SiR 1 2 — where k=1 to 10, and optionally possess OH functions,
a is from 2 to 32,
b is from 2 to 247,
c is from 0.5 to 35,
d is from 0 to 6,
e is from 0 to 15,
f is from 0 to 15,
wherein N=a+b+c+d+e+f is from 5 to 250,
g is from 4 to 25,
h is from 0 to 10,
i is 0,
wherein the polyether siloxanes of polyether siloxane variety 1 are subject to the condition that g+h+i is >3 and that there is at least one R 3 moiety whose molar weight comprises at least 90% by mass of —[CH 2 CH 2 O]— units,
and one polyether siloxane variety, hereinafter polyether siloxane variety 2, conforms to formula (I) as defined for polyether siloxane variety 1, wherein in the case of polyether siloxane variety 2
a=2 to 32,
b=2 to 297,
c=0.3 to 30,
d=0 to 6,
e=0 to 15,
f=0 to 15,
wherein N=a+b+c+d+e+f is from 5 to 300,
g is from 5 to 30,
h is from 3 to 20, and
i is 0, and polyether siloxanes of polyether siloxane variety 2 are subject to the condition that g+h+i is >3 and there is at least one R 3 moiety whose molar weight comprises at most 50% by mass, by mass by mass of —[CH 2 CH 2 O]— units
where as polyether siloxanes of the polyether siloxane variety 1 are present, in which R 3 contains more than 70 mol % of the radicals R 8 H in the residues present, and where

as polyether siloxanes of polyether siloxane variety 2 such are present at which in the residues R 3 present are less than 30 mol % of the residues R 8 H, and wherein the mass ratio of polyether siloxanes of the polyether siloxane variety 1 to polyether siloxanes of polyether siloxane variety 2 in the composition of 0.1 to 1 to 1 to 0.1.

2. The composition according to claim 1 , wherein the polyether siloxanes present as polyether siloxanes of polyether siloxane variety 1 are those where above 100 mol % of the R 8 moieties in the R 3 moieties present are H.

3. The composition according to claim 1 , wherein the polyether siloxanes present as polyether siloxanes of polyether siloxane variety 2 are those where less than 10 mol %, of the R 8 moieties in the R 3 moieties present are H.

4. The composition according to claim 1 , wherein the mass fraction of polyether siloxanes of polyether siloxane varieties 1 and 2 in the composition, based on 100 parts by mass of polyol component (pphp), is in the range from 0.05 to 10 pphp.

5. The composition according to claim 1 , wherein the mass ratio of polyether siloxanes of polyether siloxane variety 1 to polyether siloxanes of polyether siloxane variety 2 in the composition is in the range from 0.2:1 to 1:0.2.

6. The composition according to claim 1 , wherein the composition contains exclusively polyether siloxanes that are encompassed by the definitions of polyether siloxane variety 1 or polyether siloxane variety 2.

7. The composition according to claim 1 , obtainable by combining two or more separate components, where one of the components is the isocyanate-reactive component and one other component is the isocyanate component, in which case the isocyanate-reactive component is used as a mixture comprising all polyether siloxanes of polyether siloxane variety 1.

8. The composition according to claim 7 , wherein the isocyanate-reactive component is used as a mixture comprising all polyether siloxanes of polyether siloxane variety 1 or polyether siloxane variety 2.

9. The composition according to claim 7 , wherein the isocyanate component is used as a mixture comprising all polyether siloxanes of polyether siloxane variety 2.

10. The composition according to claim 1 , wherein R 1 is selected from the group consisting methyl, ethyl, propyl and phenyl.

11. The composition according to claim 1 , wherein R 1 is methyl.

12. The composition according to claim 1 , wherein the mass fraction of polyether siloxanes of polyether siloxane varieties 1 and 2 in the composition, based on 100 parts by mass of polyol component (pphp), is in the range from 0.1 to 3 pphp.

13. The composition according to claim 12 , wherein j=3,
R 6 and R 7 is selected from the group consisting of methyl, ethyl, phenyl or H, and R 8 is selected from the group consisting of methyl, —C(O)Me or H.

14. The composition according to claim 1 , wherein
a=2 to 15,
b=3 to 150,
c=1 to 22,
d=0 to 4,
e=0 to 10,
f=0 to 10,
wherein N=a+b+c+d+e+f=5 to 160.

15. The composition according to claim 1 , wherein
a=2,
b=4 to 80,
c=1.5 to 12,
d=0,
e=0,
f=0,
wherein N=a+b+c+d+e+f=8 to 80.

16. The composition according to claim 1 , wherein
polyether siloxane variety 2, conforms to formula (I) as defined for polyether siloxane variety 1, with the proviso that in the case of polyether siloxane variety 2
a=2 to 15,
b=3 to 190,
c=0.9 to 20,
d=0 to 4,
e=0 to 10,
f=0 to 10,
wherein N=a+b+c+d+e+f=8 to 200
and there is at least one R 3 moiety whose molar weight comprises at most 60% by mass by mass of —[CH 2 CH 2 O]— units.

Assignees

• Evonik Degussa Gmbh

Inventors

• Diendorf Jorg
• Geiling Iii Raymond M
• Eilbracht Christian
• Ferenz Michael

Classifications

• C08J2203/142

  Halogenated saturated hydrocarbons, e.g. H3C-CF3 · CPC title

• C08G18/4018

  Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48 · CPC title

• C08G77/46

  containing polyether sequences · CPC title

• C08J2201/03

  Extrusion of the foamable blend · CPC title

• C08J9/02

  using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules · CPC title