Formation of Ziegler-Natta catalyst using non-blended components

Patent metadata

Field	Value
Publication number	US-10351640-B2
Application number	US-76545410-A
Country	US
Kind code	B2
Filing date	Apr 22, 2010
Priority date	Apr 22, 2010
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

Methods of forming a catalyst, catalysts, polymerization processes and polymers formed therefrom are described herein. The method of forming a catalyst generally includes contacting an alkyl magnesium compound with an alcohol to form a magnesium alkoxide compound; contacting the magnesium alkoxide compound with a first titanium alkoxide and a first agent to form a reaction product “A”, wherein the titanium alkoxide and the first agent are nonblended individual components prior to contacting the magnesium alkoxide; and sequentially contacting the reaction product “A” with a second agent, followed by a third agent, and subsequently a first reducing agent to form a catalyst component.

First claim

What is claimed is:

1. A method of forming a catalyst component comprising:
contacting an alkyl magnesium compound with an alcohol and a viscosity modifier, wherein the viscosity modifier is an alkyl aluminum represented by the formula AlR 3 3 , wherein R 3 is selected from C 1 to C 10 alkyl groups, to form a magnesium alkoxide compound;
contacting the magnesium alkoxide compound with a first titanium alkoxide and a first agent to form a reaction product solution “A”, wherein the first titanium alkoxide and the first agent are nonblended individual components prior to contacting the magnesium alkoxide compound, and wherein first agent comprises a metal halide; and sequentially contacting the reaction product solution “A” with a second titanium alkoxide of the formula Ti(OR 6 ) 4 wherein R 6 is selected from C 2 to C 20 alkyl groups, followed by a third agent, and subsequently a reducing agent, wherein the reducing agent is an organolithium compound, an organomagnesium compound, an organoaluminum compound, or combinations thereof, to form a catalyst component;
shearing reaction product solution “A” with an impeller at an agitation rate while sequentially contacting the reaction product solution “A” with the second titanium alkoxide and third agent in order to provide the catalyst component with a particle size distribution span of less than 2;
and
utilizing a solvent for precipitation of the catalyst component in an amount reduced by 5% to 50% compared to an identical catalyst component synthesis without the viscosity modifier, and wherein the catalyst component has a particle size D 50 (as measured by Malvern Hydro2000μP) of at least 10 microns.

2. The method of claim 1 , wherein the alkyl magnesium compound is represented by the formula MgR 1 R 2 , wherein R 1 and R 2 are independently selected from C 1 to C 10 alkyls.

3. The method of claim 1 , wherein the alkyl magnesium compound is selected from butyl ethyl magnesium, diethyl magnesium, dipropyl magnesium, dibutyl magnesium, and combinations thereof.

4. The method of claim 1 , wherein the alcohol contacts the alkyl magnesium compound in a molar equivalent of from about 0.5 to about 6.

5. The method of claim 1 , wherein the alcohol is represented by the formula R 4 OH, wherein R 4 is selected from C 2 to C 20 alkyls.

6. The method of claim 1 , wherein the alcohol is selected from butanol, isobutanol, 2-ethylhexanol, or combinations thereof.

7. The method of claim 1 , wherein the first titanium alkoxide is represented by the formula Ti(OR 5 ) 4 , wherein R 5 is selected from C 2 to C 20 alkyl groups.

8. The method of claim 1 , wherein the first titanium alkoxide is selected from titanium 2-ethylhexyl alkoxide, titanium isopropoxide, titanium n-butoxide, or combinations thereof.

9. The method of claim 1 , wherein the first agent comprises titanium halide.

10. The method of claim 1 , wherein the third agent comprises a metal halide.

11. The method of claim 1 , wherein the viscosity modifier is selected from trimethyl aluminum, triisobutyl aluminum, triethyl aluminum, n-octyl aluminum, n-hexyl aluminum, or combinations thereof.

12. The method of claim 1 , wherein the viscosity modifier comprises triethyl aluminum.

13. The method of claim 1 , wherein the viscosity modifier contacts the alkyl magnesium compound in a molar equivalent of from about 0.01 to about 0.6.

14. The method of claim 1 , wherein the reducing agent is an organoaluminum compound represented by the formula AlR 7 3 , wherein R 7 is selected from C 1 to C 10 alkyl groups.

15. The method of claim 14 , wherein the organoaluminum compound is triethyl aluminum.

16. The method of claim 1 , wherein the second titanium alkoxide is titanium 2-ethylhexyl alkoxide, titanium isopropoxide, and titanium n-butoxide.

17. The method of claim 1 , wherein the alkyl magnesium compound is contacted with the viscosity modifier prior to contacting the alcohol.

18. The method of claim 1 , wherein the magnesium alkoxide compound is a non-reducing magnesium alkoxide compound.

19. The method of claim 1 , wherein the viscosity modifier contacts the alkyl magnesium compound in a molar equivalent of from about 0.1 to about 0.3.

20. The method of claim 1 , wherein the impeller is a four blade impeller, and wherein the catalyst component has a particle size D 50 of at least 15 microns.

21. The method of claim 1 , wherein the catalyst component has a particle size D 50 of at least 15 microns.

22. The method of claim 1 , wherein the catalyst component has unimodal particle distribution.

23. The method of claim 1 , wherein the catalyst component has bimodal particle distribution.

24. The method of claim 1 , wherein the impeller speed is controlled to minimize particle distribution span.

25. The method of claim 1 , wherein solvent reduction is reduced by about 25% compared to an identical catalyst component synthesis without the viscosity modifier.

Assignees

• Zhang Lei
• Gauthier William
• Fina Technology

Inventors

• Zhang Lei
• Gauthier William

Classifications

• C08F10/00 Primary

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F110/02

  Ethene · CPC title

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J37/00

  Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts · CPC title

• C08F4/6546

  organo-magnesium compounds · CPC title