Use of a Lewis donor solvent to purify a feedstock that contains ethanol, acetaldehyde, and impurities

Patent metadata

Field	Value
Publication number	US-10351497-B2
Application number	US-201716300122-A
Country	US
Kind code	B2
Filing date	May 9, 2017
Priority date	May 12, 2016
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

The invention pertains to the use of a solvent that comprises a Lewis donor compound that is selected from the group made up of unsaturated fatty acids that have between 12 and 18 carbon atoms, phosphate esters that have between 12 and 30 carbon atoms, and mixtures thereof to separate the impurities from a feedstock that contains ethanol, acetaldehyde, and impurities.

First claim

The invention claimed is:

1. A method for purifying a feedstock that contains ethanol, acetaldehyde, and impurities using a solvent, referred to as a Lewis donor solvent, that comprises a Lewis donor compound that is selected from the group made up of unsaturated fatty acids that have between 12 and 18 carbon atoms, phosphate esters that have between 12 and 30 carbon atoms, and mixtures thereof, where said method comprises:
a counter-current liquid-liquid extraction step A) that is fed at the top with said feedstock in a mixture with the raffinate obtained from re-extraction step B), wherein said mixture constitutes the feed for said step A), and at the bottom is fed with the Lewis donor solvent-rich effluent obtained from regeneration step C), a Lewis donor solvent make-up that may optionally be mixed with said Lewis donor solvent-rich effluent, where said step produces at the top an extract and at the bottom a purified feedstock and operates at a temperature of between 10 and 70° C. and at a pressure of between 0.1 and 0.5 MPa with a continuous-phase mass flow rate/dispersed-phase mass flow rate ratio of less than 70;
a counter-current liquid-liquid re-extraction step B) that is fed at the top with an auxiliary solvent and at the bottom with the extract obtained from step A) and that produces at the top an extract and at the bottom a raffinate, where said raffinate feeds said step A), with this step operating at a temperature of between 10 and 70° C. and at a pressure of between 0.1 and 0.5 MPa with a continuous-phase mass flow rate/dispersed-phase mass flow rate ratio of less than 70;
a regeneration step C) in which the extract obtained from step B) is separated by a first distillation into a distillate that is rich in light impurities and a residue that undergoes a second distillation, where the latter produces at the top an effluent that is rich in Lewis donor solvent and a residue that is rich in heavy impurities;
where said Lewis donor solvent comprises a Lewis donor selected from the group made up of unsaturated fatty acids that have between 12 and 18 carbon atoms, phosphate esters that have between 12 and 30 carbon atoms, and mixtures thereof.

2. The method in accordance with claim 1 in which said Lewis donor compound is selected from the group made up of oleic acid, linoleic acid, tributyl phosphate, and mixtures thereof.

3. The method in accordance with claim 1 , in which said Lewis donor solvent also comprises at least one hydrocarbon that contains at least 12 carbon atoms, with the proportion (Lewis donor compound)/hydrocarbon+Lewis donor compound) falling into a range of from 1 to less than 100% by weight.

4. The method in accordance with claim 1 in which said ratio falls into a range of from 15 to less than 100% by weight.

5. The method in accordance with claim 1 in which said auxiliary solvent solution is water.

6. A process for separating impurities from a feedstock containing ethanol, acetaldehyde, and impurities, comprising subjecting the feedstock to a solvent that comprises a Lewis donor compound that is selected from the group made up of unsaturated fatty acids that have between 12 and 18 carbon atoms, phosphate esters that have between 12 and 30 carbon atoms, and mixtures thereof.

7. The process according to claim 6 in which said Lewis donor compound is selected from the group made up of oleic acid, linoleic acid, tributyl phosphate, and mixtures thereof.

8. The process according to claim 7 in which said Lewis donor compound is oleic acid.

9. The process according to claim 6 in which said solvent that comprises a Lewis donor compound also comprises at least one hydrocarbon containing at least 12 carbon atoms, with the proportion (Lewis donor compound)/hydrocarbon+Lewis donor compound) falling into a range of from 1% to less than 100% by weight.

Assignees

• Ifp Energies Now
• Michelin & Cie

Inventors

• Hognon Celine
• Drozdz Sophie
• Jacquin Marc

Classifications

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• B01D11/0488

  Flow sheets · CPC title

• C07C29/86 Primary

  by liquid-liquid treatment · CPC title

• C07C45/80

  by liquid-liquid treatment · CPC title

• B01D11/0492

  Applications, solvents used · CPC title