Method for preparing spherical silica aerogel granules and spherical silica aerogel granules prepared thereby

Patent metadata

Field	Value
Publication number	US-10351434-B2
Application number	US-201715578641-A
Country	US
Kind code	B2
Filing date	Mar 16, 2017
Priority date	Mar 28, 2016
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

The present invention relates to a method for preparing spherical silica aerogel granules and spherical silica aerogel granules prepared thereby. The method for preparing spherical silica aerogel granules, which is suitable for mass production because droplets of a water glass solution are uniformly dispersed with a uniform size in a non-aqueous solvent using a surfactant in a certain step to reduce a process time and enhance productivity, may be provided. The spherical silica aerogel granules having a uniform size prepared by the method may be provided, wherein the spherical silica aerogel granules have a high working property and excellent flowability.

First claim

The invention claimed is:

1. A method for preparing spherical silica aerogel granules, comprising:
a) mixing a water glass solution and a non-aqueous solvent to prepare a mixed solution;
b) adding a surfactant to the mixed solution to form dispersed droplets of the water glass solution in the solvent prior to preparation of a silica sol;
c) adding a neutralizing agent to the mixed solution to form a silica sol;
d) adding a gelling agent to the silica sol to form a silica gel;
e) subjecting the silica gel to solvent substitution and adding a surface modifying agent to the silica gel to hydrophobicize the silica gel; and
f) drying the hydrophobicized silica gel,
wherein the surfactant in step b) is included at a volume ratio of 3.0 to 9.0% with respect to the mixed solution.

2. The method of claim 1 , wherein the surfactant in step b) comprises one or more surfactants selected from the group consisting of sorbitan monooleate, sorbitan monostearate, sorbitan monopalmitate, and sorbitan monolaurate.

3. The method of claim 1 , wherein the neutralizing agent in step c) is included at a volume ratio of 5 to 10% with respect to the mixed solution.

4. The method of claim 1 , wherein the gelling agent in step d) comprises one or more selected from the group consisting of ammonia, acetone, ethanol, and isopropanol.

5. The method of claim 1 , wherein the surface modifying agent in step e) is included at a volume ratio of 5 to 20% with respect to the mixed solution.

6. The method of claim 1 , wherein a total process time of the method is in a range of 1 to 5 hours.

7. Spherical silica aerogel granules prepared by the method of claim 1 .

8. The spherical silica aerogel granule of claim 7 , wherein the spherical silica aerogel granules have an average particle diameter (D 50 ) of 1 to 1,000 μm.

9. The spherical silica aerogel granule of claim 7 , wherein the spherical silica aerogel granules have a density of 0.05 to 0.3 g/cm 3 .

10. The spherical silica aerogel granule of claim 7 , wherein the spherical silica aerogel granules have a specific surface area of 500 to 900 m 2 /g.

11. The spherical silica aerogel granule of claim 7 , wherein the spherical silica aerogel granules are used in one or more selected from the group consisting of a thermal insulation material, a moisture absorbent, a sound absorbent, a carrier, a low-dielectric coating film, and an anti-reflection film.

12. The method of claim 1 , wherein the non-aqueous solvent is a hydrophobic non-polar organic solvent.

13. The method of claim 1 , wherein the non-aqueous solvent is a hexane or cyclopentane.

Assignees

• Lg Chemical Ltd
• Univ Inha Res & Business Found

Inventors

• Kim Ye Hon
• Lee Je Kyun
• Hwang Hae Jin
• Lee Kyoung Jin

Classifications

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01B33/158

  Purification; Drying; Dehydrating · CPC title

• C01B33/159

  Coating or hydrophobisation · CPC title

• C01P2006/10

  Solid density · CPC title

• C01B33/1585 Primary

  Dehydration into aerogels · CPC title