Method for performing endothermic processes

Patent metadata

Field	Value
Publication number	US-10351422-B2
Application number	US-201314651862-A
Country	US
Kind code	B2
Filing date	Dec 12, 2013
Priority date	Dec 13, 2012
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

The invention relates to a method of carrying out heat-consuming processes, wherein the total energy required averaged over a year for the heat-consuming process originates from at least two different energy sources, where one of the energy sources is an electric energy source whose power varies in the range from 0 to 100% of the total power required, and three different energy modes can individually provide the total power required for the heat-consuming process: (i) exclusively electric energy, (ii) a mixture of electric energy and at least one further nonelectric energy source or (iii) exclusively nonelectric energy, where the changeover time in which the change from one energy mode to another energy mode is completed is not more than 30 minutes.

First claim

The invention claimed is:

1. A method of carrying out a heat-consuming chemical conversion process, wherein a total energy required averaged over a year for the heat-consuming process originates from at least two different energy sources, where one of the energy sources is an electric energy source from a power grid whose power provided from the power grid varies in the range from 0 to 100% of the total power required at any given time such that, averaged over the year, at least 10% of the total energy required for the heat-consuming process is provided by the electric energy source, and where an excess power, which is defined as a power which is offered on a power market at well below generation costs or at prices which, based on energy content, are lower than for a fossil fuel having a same joule value or for nothing or even at negative prices, is used without intermediate storage or prior smoothing/compensation in a power station in the heat-consuming process,
and wherein the following three different energy modes can individually provide the total power required at any given time for the heat-consumer process: (i) exclusively electric energy, (ii) a mixture of electric energy and a further nonelectric energy source or (iii) exclusively nonelectric energy, where a change of energy sources/energy modes is effected while carrying out the heat-consuming process and changeover time in which the change from one energy mode to another energy mode is completed is not more than 30 minutes, where the nonelectric energy source is supplied by oxidative processes, and thermal energy which is taken from the electric energy source with power which fluctuates over time, and which is for the heat-consuming process, is supplied by inductive or resistive methods, plasma processes, heating by electrically conductive heating elements/contact areas or by microwaves, the two or more energy sources being connected in series or in parallel.

2. The method as claimed in claim 1 , wherein the efficiency of the electric energy source whose power varies in the range from 0 to 100% of the total power required is greater than 90%.

3. The method as claimed in claim 1 , wherein at least 75% of the electric energy used is provided by excess power and/or nighttime power.

4. The method as claimed in claim 1 , wherein, averaged over a year, at least 10% of the total energy required for the heat-consuming process is drawn from the electric energy sources having a fluctuating power output.

5. The method as claimed in claim 1 , wherein a process stream whose heat is subsequently utilized for the heat-consuming process are heated by the electric power.

6. The method as claimed in claim 1 , wherein the heat flow supplied to the heat-consuming process fluctuates by not more than 10% during the changeover time.

7. The method as claimed in claim 1 , wherein the changeover time is not more than 7.5 minutes.

8. The method as claimed in claim 1 , wherein the energy consumption of the heat-consuming process is greater than 0.5 MW/m3 in the reaction zone.

9. The method as claimed in claim 1 , wherein the by-product selectivity of the heat-consuming processes is increased by a maximum of 1% during the change of the energy sources.

10. The method as claimed in claim 1 , wherein thermal energy is generated oxidatively in a nonelectric energy source.

11. The method as claimed in claim 10 , wherein electrically heated radiation tubes and oxidatively heated radiation tubes are arranged alternately in the reaction zone of the heat-consuming process.

12. The method as claimed in claim 1 , wherein the changeover time is not more than 60 seconds.

13. The method as claimed in claim 1 , wherein the heat-consuming process is steam reforming and dry reforming, the thermolysis of water, the dehydrogenation of ethylbenzene to styrene, of propane to propene, of butane to butene and/or of cyclohexane to benzene, the pyrolysis and cracking of hydrocarbons, pyrolytic acetylene production, the preparation of benzene from methane, the reduction of carbon dioxide to carbon monoxide, the preparation of hydrocyanic acid from methane and ammonia and/or the preparation of nitrogen monoxide from nitrogen and oxygen.

14. The method as claimed in claim 1 , wherein in energy mode (ii), thermal energy from the electric energy source is supplied to a process stream in a first heating step and if the instantaneous power of the electric energy source is not sufficient, the temperature of the process stream is increased to the desired value further downstream in a second heating step by introduction of thermal energy from a nonelectric energy source.

15. The method as claimed in claim 1 , wherein in energy mode (ii), the process stream is firstly preheated by thermal energy from a nonelectric energy source and subsequently brought to the desired temperature by electrically generated heat.

16. The method as claimed in claim 1 , wherein one of the energy sources is an electric energy source whose power varies in the range from 0 to 100% of the total power required at any given time such that, averaged over the year, at least 15% of the total energy required for the heat-consuming process is provided by the electric energy source.

17. The method as claimed in claim 1 , wherein one of the energy sources is an electric energy source whose power varies in the range from 0 to 100% of the total power required at any given time such that, averaged over the year, at least 20% of the total energy required for the heat-consuming process is provided by the electric energy source.

18. The method as claimed in claim 1 , wherein one of the energy sources is an electric energy source whose power varies in the range from 0 to 100% of the total power required at any given time such that, averaged over the year, at least 25% of the total energy required for the heat-consuming process is provided by the electric energy source.

19. The method as claimed in claim 1 , wherein at least 50% of the electric energy used is provided by excess power and/or nighttime power.

Assignees

• Basf Se
• Linde Ag

Inventors

• Machhammer Otto
• Hormuth Wolfgang Alois
• Schneider Christian
• Bode Andreas
• Goeke Volker
• Maass Hans-Juergen
• Kern Matthias
• Klingler Dirk
• Koenig Rene
• Brueggemann Philipp
• Bernnat Jens
• Kolios Grigorios

Classifications

• B01J19/00 Primary

  Chemical, physical or physico-chemical processes in general; Their relevant apparatus · CPC title

• C01B2203/0272

  containing a non-catalytic decomposition step · CPC title

• B01J8/00

  Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes · CPC title

• B01J2219/00135

  Electric resistance heaters · CPC title

• C01B2203/0866

  by combination of different heating methods · CPC title