Non-aqueous electrolyte secondary battery, electrode body used therefor, and method of manufacturing the electrode body

Patent metadata

Field	Value
Publication number	US-10347946-B2
Application number	US-201515522497-A
Country	US
Kind code	B2
Filing date	Oct 26, 2015
Priority date	Oct 29, 2014
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

An electrode body includes: a positive electrode that includes a positive electrode active material layer; a negative electrode that includes a negative electrode active material layer; and a separator that electrically separates the positive electrode and the negative electrode from each other, in which the positive electrode active material layer and the separator contain N-methylpyrrolidone (NMP). A N-methylpyrrolidone (NMP) content in the positive electrode active material layer is 54 ppm to 602 ppm with respect to a total solid content of the positive electrode active material layer, and a N-methylpyrrolidone content (NMP) in the separator is 10 ppm to 26 ppm with respect to the total solid content of the positive electrode active material layer.

First claim

What is claimed is:

1. An electrode body used for a nonaqueous electrolyte secondary battery, the electrode body comprising:
a positive electrode that includes a positive electrode active material layer containing a positive electrode active material;
a negative electrode that includes a negative electrode active material layer containing a negative electrode active material; and
a separator that electrically separates the positive electrode and the negative electrode from each other, wherein
the positive electrode active material layer and the separator contain N-methylpyrrolidone,
a N-methylpyrrolidone content in the positive electrode active material layer is 54 ppm to 602 ppm with respect to a total solid content of the positive electrode active material layer, and
a N-methylpyrrolidone content in the separator is 10 ppm to 26 ppm with respect to the total solid content of the positive electrode active material layer.

2. The electrode body according to claim 1 , wherein
the positive electrode active material is a lithium composite oxide.

3. The electrode body according to claim 1 , wherein
the electrode body is a wound electrode body in which the elongated positive electrode, the elongated negative electrode, and the elongated separator are laminated and wound in a longitudinal direction.

4. A nonaqueous electrolyte secondary battery comprising:
an electrode body in which a positive electrode including a positive electrode active material layer, a negative electrode including a negative electrode active material layer, and a separator electrically separating the positive electrode and the negative electrode from each other are laminated; and
a nonaqueous electrolytic solution, wherein
the electrode body is the electrode body according to claim 1 .

5. A method of manufacturing an electrode body,
the electrode body including a positive electrode, a negative electrode, and a separator,
the positive electrode including a positive electrode active material layer containing a positive electrode active material,
the negative electrode including a negative electrode active material layer containing a negative electrode active material,
the separator electrically separating the positive electrode and the negative electrode from each other, and
the method comprising:
preparing a positive electrode in which the positive electrode active material layer is formed on a positive electrode current collector by applying a positive electrode active material layer-forming composition, which contains the positive electrode active material and N-methylpyrrolidone, to the positive electrode current collector, the positive electrode active material layer containing N-methylpyrrolidone;
laminating the positive electrode, and the negative electrode with the separator interposed therebetween to obtain a laminate; and
standing of the laminate, to stand for a predetermined amount of time such that a part of N-methylpyrrolidone in the positive electrode active material layer is moved into the separator; and
drying the laminate after the standing, wherein
the standing and the drying are performed such that a N-methylpyrrolidone content in the positive electrode active material layer of the dry laminate is 54 ppm to 602 ppm with respect to a total solid content of the positive electrode active material layer, and a N-methylpyrrolidone content in the separator of the dry laminate is 10 ppm to 26 ppm with respect to the total solid content of the positive electrode active material layer.

6. The method of manufacturing the electrode body according to claim 5 , wherein
during the standing of the laminate, the laminate is left to stand in a normal-temperature and normal-humidity environment for 1 hour to 2 hours.

7. The method of manufacturing the electrode body according to claim 5 , wherein
the positive electrode active material is a lithium composite oxide.

8. The method of manufacturing the electrode body according to claim 5 , wherein
the electrode body is a wound electrode body in which the elongated positive electrode, the elongated negative electrode, and the elongated separator are laminated and wound in a longitudinal direction.

9. The method of manufacturing the electrode body according to any one of claim 6 , wherein
the normal-temperature is a temperature in a range of 5° C. to 35° C., and
the normal-humidity is a relative humidity in a range of 45% rh to 85% rh.

10. The method of manufacturing the electrode body according to claim 5 , wherein
a N-methylpyrrolidone content in a positive electrode active material layer of a positive electrode before an electrode body is configured is 89 ppm to 1004 ppm with respect to the total solid content of the positive electrode active material layer.

Assignees

• Toyota Motor Co Ltd

Inventors

• Tamaki Takuml
• Takehara Satoru

Classifications

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/1391

  of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0587 Primary

  of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators · CPC title

• H01M4/62 Primary

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title