Temperature influenced chemical vaporization and detection of compounds having low volatility

Patent metadata

Field	Value
Publication number	US-10345282-B2
Application number	US-201715599612-A
Country	US
Kind code	B2
Filing date	May 19, 2017
Priority date	Mar 8, 2016
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

The present disclosure is directed to methods and systems for detecting a chemical substance. The methods and systems include chemically modifying a sample of a substance of interest through combination with a reagent to increase the volatility of the substance of interest. The systems and methods further include performing an analysis of the substance of interest.

First claim

What is claimed is:

1. A method for detecting a substance of interest, the method comprising:
collecting a sample of a substantially non-volatile substance of interest on a sampling trap;
introducing the trap including the substance of interest into an opening of a thermal desorber, wherein the opening of the thermal desorber is defined, at least in part, by two plates;
depositing a reagent on the trap, wherein the reagent increases the volatility of the substance of interest, wherein depositing the reagent includes spraying the reagent on the trap;
increasing the temperature within the desorber by resistively heating at least one of the two plates, wherein the temperature increases at a rate and wherein said rate is not constant;
vaporizing the substance of interest;
transferring the vaporized substance of interest from the desorber into a detector;
performing an analysis of the substance of interest; and,
detecting the substance of interest.

2. The method of claim 1 , wherein the reagent includes at least one of an organic acid, an inorganic acid and a reducing agent.

3. The method of claim 2 , wherein the reagent includes at least one of sulfuric acid, sulfonic acid, phosphonic acid, phosphoric acid or combinations thereof.

4. The method of claim 1 , wherein the substance of interest include at least one of an explosive, an energetic material, a taggant, a narcotic, a toxin, a chemical warfare agent, a biological warfare agent, a pollutant, a pesticide, a toxic industrial chemical, a toxic industrial material, a homemade explosive, a pharmaceutical trace contaminant or combinations thereof.

5. The method of claim 1 , wherein the substance of interest includes at least one of nitrates, chlorates, perchlorates, permanganates or combinations thereof.

6. The method of claim 5 , wherein the substance of interest includes at least one of sodium nitrate, potassium nitrate, strontium nitrate, barium nitrate, sodium chlorate, potassium chlorate, sodium perchlorate, potassium perchlorate, sodium permanganate, potassium permanganate, or combinations thereof.

7. The method of claim 1 , wherein the temperature increases within the desorber from about 50° C. to about 400° C.

8. The method of claim 1 , wherein the temperature within the desorber is increased over a period of time from about 0 seconds to about 20 seconds.

9. A substance detection system comprising:
a sampling trap including a substantially non-volatile substance of interest;
a thermal desorber configured to receive the sampling trap into an opening, wherein the thermal desorber includes a deposition device, the deposition device including a reagent and configured to deposit the reagent onto the sampling trap, wherein the reagent increases the volatility of the substance of interest, wherein the opening of the thermal desorber is defined, at least in part, by two plates, wherein the desorber is configured to vaporize the substance of interest, and wherein the desorber comprises a heater configured to change a heating rate during operation by passing a current through at least of the two plates;
an analysis device coupled in flow communication with the desorber, the analysis device configured to receive the vaporized substance of interest and perform an analysis of the substance of interest.

10. The system of claim 9 , wherein the reagent includes at least one of an organic acid, an inorganic acid or a reducing agent.

11. The system of claim 10 , wherein the reagent includes at least one of sulfuric acid, sulfonic acid, phosphonic acid, phosphoric acid or combinations thereof.

12. The system of claim 9 , wherein the substance of interest include at least one of an explosive, an energetic material, a taggant, a narcotic, a toxin, a chemical warfare agent, a biological warfare agent, a pollutant, a pesticide, a toxic industrial chemical, a toxic industrial material, a homemade explosive, a pharmaceutical trace contaminant or combinations thereof.

13. The system of claim 9 , wherein the substance of interest includes at least one of nitrates, chlorates, perchlorates, permanganates or combinations thereof.

14. The system of claim 13 , wherein the substance of interest includes at least one of sodium nitrate, potassium nitrate, strontium nitrate, barium nitrate, sodium chlorate, potassium chlorate, sodium perchlorate, potassium perchlorate, sodium permanganate, potassium permanganate, or combinations thereof.

15. A method for detecting a substantially non-volatile salt compound, the method comprising:
increasing the volatility of a substantially non-volatile salt compound, wherein increasing the volatility of the salt compound includes inserting a sample trap carrying the substantially non-volatile salt compound into an opening of a thermal desorber, wherein the opening of the thermal desorber is defined, at least in part, by two plates, applying a reagent to the salt compound and desorbing the salt compound within the thermal desorber, wherein the desorbing includes increasing the temperature within the desorber by resistively heating at least one of the two plates, and wherein said temperature is increased at a non-constant rate;
vaporizing the salt compound; and,
transferring the vaporized salt compound from the desorber into a detector, wherein the detector performs an analysis of the vaporized salt compound and detects the salt compound.

16. The method of claim 15 , wherein the reagent includes at least one of an organic acid, an inorganic acid or a reducing agent.

17. The method of claim 16 , wherein the reagent includes at least one of sulfuric acid, sulfonic acid, phosphonic acid, phosphoric acid or combinations thereof.

18. The method of claim 15 , wherein the substantially non-volatile salt compound includes at least one of sodium nitrate, potassium nitrate, strontium nitrate, barium nitrate, sodium chlorate, potassium chlorate, sodium perchlorate, potassium perchlorate, sodium permanganate, potassium permanganate, or combinations thereof.

19. The method of claim 15 , wherein the temperature is increased within the desorber from about 50° C. to about 400° C.

20. The method of claim 15 , wherein the temperature within the desorber is increased over a period of time from about 0 seconds to about 20 seconds.

Assignees

• Rapiscan Systems Inc

Inventors

• Vilkov Andrey N
• Widjaja Joseph A
• Syage Jack A

Classifications

• Y10T436/25875

  Gaseous sample or with change of physical state · CPC title

• Y10T436/173076

  Nitrite or nitrate · CPC title

• Y10T436/163333

  Organic [e.g., chemical warfare agents, insecticides, etc.] · CPC title

• G01N2001/028

  Sampling from a surface, swabbing, vaporising · CPC title

• G01N2001/022

  sampling for security purposes, e.g. contraband, warfare agents · CPC title