Structure or component for high temperature applications, as well as methods and apparatus for producing same

Patent metadata

Field	Value
Publication number	US-10344369-B2
Application number	US-201614993585-A
Country	US
Kind code	B2
Filing date	Jan 12, 2016
Priority date	Jan 13, 2015
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

A structure for high temperature applications comprises a base structure which includes a ceramic composite material, and a coating of a metal-semimetal compound, a metal boride, a metal carbide and/or a metal nitride. Furthermore, a production method and a coating device produces structures which resist high temperature applications with higher process temperatures and difficult chemical conditions.

First claim

The invention claimed is:

1. A method for producing a structure for high temperature applications comprising a base structure which includes a ceramic composite material and a coating, the method comprising:
providing the base structure of the ceramic composite material including a ceramic fiber composite material;
coating the base structure with an ultra high temperature ceramic coating of a coating material which contains at least a metal-semimetal compound, at least a metal boride, at least a metal carbide or at least a metal nitride, by
installing the base structure in a vacuum process chamber for plasma beam techniques,
providing a plasma torch with a cathode, an elongated plasma channel downstream of the cathode to guide the plasma beam, and an ultrasonic nozzle downstream of the elongated plasma channel,
introducing the coating material into the elongated plasma channel and forming a gas mixture in the elongated plasma channel,
expanding the gas with coating material via the ultrasonic nozzle, and
plasma coating the base structure with the coating material.

2. The method according to claim 1 , wherein
the providing the base structure comprises at least one of the following:
providing fibers of one or several fiber materials which are selected from a group of fiber materials which comprises C, ceramic materials, SiC, HfC, ZrC, TaC, TiC, ZrB 2 , HfB 2 , TiB 2 , TaB 2 and NbB 2 and nitride materials; and
embedding fibers in a matrix, wherein the matrix is formed from one or several matrix materials which are selected from a group of ceramic matrix materials which comprises SiC, HfC, ZrC, TaC, TiC, ZrB 2 , HfB 2 , TiB 2 , TaB 2 and NbB 2 and nitride materials.

3. The method according to claim 1 , wherein the coating further comprises at least one of the following:
pre-cleaning the base structure with at least one of the following: an organic solvent, an inorganic solvent and at least one acid;
pre-treating and preparing the base structure for the coating;
pre-heating the base structure;
treating the base structure by reactive plasma beams; and
coating the base structure with the coating material which is selected from coating materials of a group of coating materials which comprises SiC, HfC, ZrC, TaC, TiC, ZrB 2 , HfB 2 , TiB 2 , TaB 2 and NbB 2 and nitride materials.

4. The method according to claim 3 , wherein the coating the base structure further comprises at least one of the following:
using a powder or a powder mixture with an average grain size from 1 μm to 100 μm as a coating material, the powder or powder mixture including a metal-semimetal compound or a metal boride;
transferring the coating material into a plasma torch by a conveyor device;
fragmenting or partially evaporating the coating materials in a hot core beam of the plasma in combination with simple metal-semimetal molecules, metal atoms and semimetal atoms; and
performing an ultrasonic method for concentrating heavier components of the cluster gas or the gas mixture with coating material in the center of the gas beam.

5. A method according to claim 1 , further comprising
performing a superficial transformation of the metal-semimetal coating material by oxygen into at least one of the following: a glassy substance and mixtures of metal oxides with semimetal oxide.

6. The method according to claim 1 , further comprising
at least one flow body configured to guide the plasma beams more into the direction of a wall of the base structure to be coated.

7. The method according to claim 3 , wherein the preheating the base structure comprises at least one of the following
pre-heating by at least one of enthalpy and a temperature of a plasma beam;
varying plasma power dependent on at least one of a process duration, evaporation enthalpy and fragmentation enthalpy of the coating materials;
immediately electrically heating the base structure by introducing a heating current into the base structure;
at least one of heating and keeping warm the base structure at a process temperature in the range from 300° C. to 1400° C.; and
capturing the temperature of the base structure and controlling the heating processes.

8. A structure produced by a method according to claim 1 .

9. An apparatus comprising:
a vacuum process chamber for plasma beam techniques;
a plasma torch configured to produce a plasma beam and having a cathode, an anode, an elongated plasma channel downstream of the cathode for guiding a plasma beam, and an ultrasonic nozzle downstream of the elongated plasma channel; and
a device configured to introduce a coating material downstream of the cathode arranged such that the coating material is introduced into the elongated plasma channel,
the apparatus configured to coat a base structure disposed in the vacuum chamber with an ultra high temperature ceramic coating of the coating material which contains at least a metal-semimetal compound, at least a metal boride, at least a metal carbide or at least a metal nitride when the base structure is installed in the vacuum process chamber, by introducing the coating material into the elongated plasma channel and forming a gas mixture in the elongated plasma channel, expanding the gas with coating material via the ultrasonic nozzle, and plasma coating the base structure with the coating material.

Assignees

• Airbus Defence & Space Gmbh

Inventors

• Steinwandel Jürgen
• Wilhelmi Christian
• Uhlmann Franziska
• Laure Stefan

Classifications

• H05H1/42

  with provisions for introducing materials into the plasma, e.g. powder or liquid {(arc stabilising or constricting arrangements H05H1/3405; coaxial protecting fluids H05H1/341)} · CPC title

• C23C4/134

  Plasma spraying · CPC title

• C23C4/10 Primary

  Oxides, borides, carbides, nitrides or silicides; Mixtures thereof · CPC title

• C23C4/02

  Pretreatment of the material to be coated, e.g. for coating on selected surface areas · CPC title

• H05H1/34

  Details, e.g. electrodes, nozzles · CPC title