Member for hydrogen production and hydrogen production apparatus

Patent metadata

Field	Value
Publication number	US-10343904-B2
Application number	US-201616061685-A
Country	US
Kind code	B2
Filing date	Nov 15, 2016
Priority date	Dec 14, 2015
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

A member for hydrogen production includes a ceramic composite in which a plurality of ceramic particles having an average particle diameter ranging from 5 nm to 200 nm are dispersed in a porous insulator having a different component from the ceramic particles. The ceramic particles comprise at least one substance selected from the group consisting of AXO3±δ (where 0≤δ≤1, A: at least one of rare earth elements, alkaline earth elements, and alkali metal elements, X: at least one of transition metal elements and metalloid elements, and O: oxygen), cerium oxide, and zirconium oxide as a main component.

First claim

The invention claimed is:

1. A member for hydrogen production, the member comprising:
a ceramic composite comprising a plurality of ceramic particles having an average particle diameter ranging from 5 nm to 200 nm; wherein the plurality of ceramic particles are dispersed in a porous insulator having a different composition from the ceramic particles, wherein
the ceramic particles comprise at least one substance selected from the group consisting of AXO 3±δ (where 0≤δ≤1, wherein A represents at least one of rare earth elements, alkaline earth elements, alkali metal elements, and combinations thereof; wherein X represents at least one of transition metal elements, metalloid elements, and combinations thereof and wherein O represents oxygen), cerium oxide, and zirconium oxide.

2. The member for hydrogen production according to claim 1 , wherein the proportion of the ceramic particles in the ceramic composite ranges from 20% by volume to 80% by volume.

3. The member for hydrogen production according to claim 1 , wherein a number of ceramic particles of the plurality of ceramic particles existing in an isolated state is 90% or more.

4. The member for hydrogen production according to claim 1 , wherein a light absorbing member is provided on the ceramic composite.

5. The member for hydrogen production according to claim 4 , wherein the light absorbing member is a metal particle-containing composite in which metal particles are dispersed in a dielectric substance or a metal-based film laminated product in which a metal-based film and a dielectric substance are laminated.

6. The member for hydrogen production according to claim 4 , wherein a metal film is provided between the ceramic composite and the light absorbing member.

7. A hydrogen production apparatus according to claim 4 , further comprising:
a reaction unit configured to cause oxidation-reduction reactions by receiving solar energy,
a water supply unit configured to supply water to the reaction unit, and
a recovery unit configured to recover hydrogen gas generated from the reaction unit, wherein
the member for hydrogen production is provided in the reaction unit.

8. The hydrogen production apparatus according to claim 7 , further comprising a pressure-reducible container; wherein the reaction unit is contained in the pressure-reducible container.

9. The hydrogen production apparatus according to claim 8 , wherein the pressure-reducible container comprises two or more intake ports.

10. The hydrogen production apparatus according to claim 9 , wherein one of the two intake ports is used for reducing pressure inside the pressure-reducible container and the other is used for reducing pressure inside the reaction unit.

11. The hydrogen production apparatus according to claim 8 , wherein the pressure-reducible container is provided with a window for taking in sunlight.

12. The hydrogen production apparatus according to claim 7 , wherein the reaction unit is a flat plate type laminated structure in which the ceramic composite having a flat plate-like shape is sandwiched from an upper side and a lower side by the light absorbing members having a flat plate-like shape.

13. The hydrogen production apparatus according to claim 7 , wherein the reaction unit is a hollow cylindrical laminated structure in which the ceramic composite having a cylindrical shape is surrounded by the light absorbing member having a cylindrical shape.

14. The hydrogen production apparatus according to claim 13 , wherein the hollow cylindrical laminated structure is a non-coaxial structure in which a central axis of a section of the cylindrical ceramic composite does not overlap with a central axis of a section of the cylindrical light absorbing member.

15. The hydrogen production apparatus according to claim 7 , wherein a hydrogen absorbing member is provided adjacent to the reaction unit.

Assignees

• Kyocera Corp

Inventors

• Akiyama Masahide
• Ohkuma Takeshi

Classifications

• C04B2235/3229

  Cerium oxides or oxide-forming salts thereof · CPC title

• C01G49/00

  Compounds of iron · CPC title

• C01G25/02

  Oxides · CPC title

• C01B3/061 Primary

  by reaction of water with metal oxides · CPC title

• Y02P20/134

  Cross-Sectional Technologies · mapped topic