Flame retardant nanocoated substrate

Patent metadata

Field	Value
Publication number	US-10343185-B2
Application number	US-201515300176-A
Country	US
Kind code	B2
Filing date	Mar 27, 2015
Priority date	Mar 28, 2014
Publication date	Jul 9, 2019
Grant date	Jul 9, 2019

Abstract

A method includes coating a substrate to provide a flame resistant substrate. In an embodiment, the method includes exposing the substrate to a cationic solution to produce a cationic layer deposited on the substrate. The cationic solution comprises cationic materials. The cationic materials comprise a polymer, a colloidal particle, a nanoparticle, a nitrogen-rich molecule, a geopolymer, a carbon-based filler, or any combinations thereof. The method also includes agitating the substrate. The method further includes exposing the cationic layer to an anionic solution to produce an anionic layer deposited on the cationic layer to produce a layer comprising the anionic layer and the cationic layer. The anionic solution comprises a layerable material.

First claim

What is claimed is:

1. A method for coating a substrate to provide a flame resistant substrate, comprising:
exposing the substrate to a cationic solution to produce a cationic layer deposited on the substrate, wherein the cationic solution comprises cationic materials, and wherein the cationic materials comprise a polymer, a colloidal particle, a nanoparticle, a nitrogen-rich molecule, a geopolymer, a carbon-based filler, or any combinations thereof;
exposing the cationic layer to an anionic solution to produce an anionic layer deposited on the cationic layer to produce a layer comprising the anionic layer and the cationic layer, wherein the anionic solution comprises a layerable material; and
agitating the substrate during the steps of exposing, wherein the agitating comprises ultrasonication.

2. The method of claim 1 , wherein the ultrasonication comprises a frequency from about 20 kHz to about 300 kHz.

3. The method of claim 1 , wherein the agitating comprises agitating the substrate in the presence of the cationic solution, the anionic solution, or any combinations thereof.

4. The method of claim 1 , further comprising rinsing the cationic layer deposited on the substrate, and wherein the agitating is accomplished during the rinsing.

5. The method of claim 1 , further comprising rinsing the anionic layer deposited on the cationic layer, and wherein the agitating is accomplished during the rinsing.

6. The method of claim 1 , wherein the layerable material comprises an anionic polymer, a colloidal particle, a phosphated molecule, a sulfated molecule, a boron-containing polymer, a carbon-based filler, or any combinations thereof.

7. The method of claim 1 , wherein the substrate comprises a primer layer.

8. The method of claim 1 , wherein the substrate comprises a fabric.

9. The method of claim 1 , wherein the agitating is from about 0.1 seconds to about 10 minutes.

10. A method for coating a substrate to provide a flame resistant substrate, comprising:
exposing the substrate to an anionic solution to produce an anionic layer deposited on the substrate, wherein the anionic solution comprises a layerable material;
exposing the anionic layer to a cationic solution to produce a cationic layer deposited on the anionic layer to produce a layer comprising the anionic layer and the cationic layer, wherein the cationic solution comprises cationic materials, and wherein the cationic materials comprise a polymer, a colloidal particle, a nanoparticle, a nitrogen-rich molecule, a geopolymer, a carbon-based filler, or any combinations thereof; and
agitating the substrate during the steps of exposing, wherein the agitating comprises ultrasonication.

11. The method of claim 10 , wherein the ultrasonication comprises a frequency from about 20 kHz to about 300 kHz.

12. The method of claim 10 , wherein the agitating comprises agitating the substrate in the presence of the cationic solution, the anionic solution, or any combinations thereof.

13. The method of claim 10 , further comprising rinsing the anionic layer deposited on the substrate, and wherein the agitating is accomplished during the rinsing.

14. The method of claim 10 , further comprising rinsing the cationic layer deposited on the anionic layer, and wherein the agitating is accomplished during the rinsing.

15. The method of claim 10 , wherein the layerable material comprises an anionic polymer, a colloidal particle, a phosphated molecule, a sulfated molecule, a boron-containing polymer, a carbon-based filler, or any combinations thereof.

16. The method of claim 10 , wherein the substrate comprises a primer layer.

17. The method of claim 10 , wherein the substrate comprises a fabric.

18. The method of claim 10 , wherein the agitating is from about 0.1 seconds to about 10 minutes.

Assignees

• Texas A & M Univ Sys

Inventors

• Grunlan Jaime C
• Guin Tyler C

Classifications

• C08J2375/06

  from polyesters · CPC title

• C08J2205/06

  Flexible foams · CPC title

• D06M2200/30

  Flame or heat resistance, fire retardancy properties · CPC title

• C08J2205/05

  Open cells, i.e. more than 50% of the pores are open · CPC title

• B32B5/02

  characterised by structural features of a {fibrous or filamentary} layer {(layer formed of metallic wires B32B15/02; layer formed of natural mineral fibres B32B19/02; layer formed of wood fibres B32B21/02)} · CPC title