Hydride generation system

Patent metadata

Field	Value
Publication number	US-10340832-B2
Application number	US-201715688396-A
Country	US
Kind code	B2
Filing date	Aug 28, 2017
Priority date	Feb 28, 2014
Publication date	Jul 2, 2019
Grant date	Jul 2, 2019

Abstract

The present disclosure is directed to a system and a method for hydride generation. In some embodiments, the system includes an assembly for introducing hydride generation reagents into a mixing path or mixing container, where the assembly includes first chamber configured to contain a first hydride generation reagent and a second chamber configured to contain a second hydride generation reagent. A first plunger is configured to translate within the first chamber and cause a displacement of the first hydride generation reagent, and a second plunger is configured to translate within the second chamber and cause a displacement of the second hydride generation reagent. The assembly further includes base coupling the first plunger and the second plunger together.

First claim

What is claimed is:

1. A sampling system, comprising:
a sampling assembly configured to draw a sample into a mixing path; and
a hydride generation assembly configured to introduce selected amounts of a first hydride generation reagent and a second hydride generation reagent into the mixing path, the hydride generation assembly including: a source of the first hydride generation reagent; a source of the second hydride generation reagent; a first chamber configured to contain the first hydride generation reagent; a second chamber configured to contain the second hydride generation reagent; a first plunger configured to translate within the first chamber and cause a displacement of the first hydride generation reagent; a second plunger configured to translate within the second chamber and cause a displacement of the second hydride generation reagent; and a base coupling the first plunger and the second plunger together, the base movable relative to the first chamber in a direction of translation of the first plunger within the first chamber;
a nebulizer fluidically coupled with the mixing path, the nebulizer configured to introduce at least a portion of the sample received from the mixing path into a spray chamber; and
a sample analysis instrument configured to receive the at least a portion of the sample from the nebulizer, the spray chamber being fluidically coupled with or forming a portion of the sample analysis instrument, the sample analysis instrument comprising a spectrometer.

2. The sampling system of claim 1 , wherein the first chamber includes an input for receiving the first plunger and an output for connecting to a first tube, and the second chamber includes an input for receiving the second plunger and an output for connecting to a second tube, the first and second tubes being fluidically coupled to the mixing path.

3. The sampling system of claim 1 , wherein the hydride generation assembly further includes:
a third chamber fluidically coupled with the mixing path and configured to contain a carrier solution; and
a third plunger configured to translate within the third chamber and cause a displacement of the carrier solution, wherein the base further couples the third plunger with the first plunger and the second plunger together.

4. The sampling system of claim 3 , wherein a cross-sectional area of the first chamber is different from a cross-sectional area of the second chamber, or a cross-sectional area of the first chamber is different from a cross-sectional area of the third chamber, or a cross-sectional area of the second chamber is different from a cross-sectional area of the third chamber.

5. The sampling system of claim 1 , wherein the first chamber and the second chamber are rigidly connected with one another.

6. The sampling system of claim 1 , wherein the hydride generation assembly further comprises one or more mounting members rigidly connected to the first and second chambers, the one or more mounting members configured for affixing the first and second chambers to a rigid structure.

7. The sampling system of claim 6 , further comprising:
an actuator coupled to the rigid structure or the base; and
a controller configured to cause the actuator to actuate the rigid structure or the base to dispense a selected amount of the first hydride generation reagent and a selected amount of the second hydride generation reagent.

8. The sampling system of claim 1 , wherein the sample analysis instrument comprises an inductively coupled plasma spectrometer.

9. The sampling system of claim 1 , wherein the first plunger and the second plunger are configured respectively to displace fluid within the first chamber and the second chamber in a synchronized manner when the base, the first plunger, and the second plunger together are moved relative to the first chamber and the second chamber.

10. The sampling system of claim 1 , wherein the first plunger and the second plunger are rotationally coupled to the base via at least one pin.

11. A sampling system, comprising:
a sampling assembly configured to draw a sample into a mixing path; and
a hydride generation assembly configured to introduce selected amounts of a first hydride generation reagent and a second hydride generation reagent into the mixing path, the hydride generation assembly including: a source of the first hydride generation reagent; a source of the second hydride generation reagent; a first chamber configured to contain the first hydride generation reagent; a second chamber configured to contain the second hydride generation reagent; a first plunger configured to translate within the first chamber and cause a displacement of the first hydride generation reagent; a second plunger configured to translate within the second chamber and cause a displacement of the second hydride generation reagent; and a base coupling the first plunger and the second plunger together, the base movable relative to the first chamber in a direction of translation of the first plunger within the first chamber;
a nebulizer fluidically coupled with the mixing path; and
a spray chamber configured to receive from the nebulizer at least a portion of the sample received from the mixing path.

12. The sampling system of claim 11 , further comprising a sample analysis instrument configured to receive the at least a portion of the sample from the nebulizer, the spray chamber being fluidically coupled with or forming a portion of the sample analysis instrument, the sample analysis instrument comprising a spectrometer.

Assignees

• Elemental Scientific Inc

Inventors

• Wiederin Daniel R
• Schultz Austin

Classifications

• H02P25/188 Primary

  wherein the motor windings are switched from series to parallel or vice versa to control speed or torque · CPC title

• B63H23/10

  for transmitting drive from more than one propulsion power unit · CPC title

• H02K3/28

  Layout of windings or of connections between windings (windings for pole-changing H02K17/06, H02K17/14, H02K19/12, H02K19/32) · CPC title

• G01N21/73

  using plasma burners or torches · CPC title

• G01N21/714 Primary

  Sample nebulisers for flame burners or plasma burners (nebulizers per se B05B) · CPC title