Apparatus and associated methods for electrical storage

Patent metadata

Field	Value
Publication number	US-10340094-B2
Application number	US-201615572947-A
Country	US
Kind code	B2
Filing date	Apr 27, 2016
Priority date	May 18, 2015
Publication date	Jul 2, 2019
Grant date	Jul 2, 2019

Abstract

An apparatus including a first charge collector and an ionic layer, the ionic layer configured to absorb water from the surrounding environment to deliver said water to the apparatus, the apparatus including graphene oxide provided on the first charge collector, the graphene oxide configured to generate protons in the presence of water; a second conductive material spaced apart from the first charge collector, the second material having a lower work function than the first charge collector, the graphene oxide extending from the first charge collector to be in contact with the second material at an interface; wherein the ionic layer is in contact with the graphene oxide and the second material; and wherein the ionic layer includes a room temperature ionic fluid and a solidifying material which provides for the ionic layer to be a solid at room temperature.

First claim

The invention claimed is:

1. An apparatus comprising a first charge collector and an ionic layer, the ionic layer configured to absorb water from the surrounding environment to deliver said water to the apparatus, the apparatus comprising:
graphene oxide provided on the first charge collector, the graphene oxide configured to generate protons in the presence of water;
a second conductive material spaced apart from the first charge collector, the second material having a lower work function than the first charge collector, the graphene oxide extending from the first charge collector to be in contact with the second material at an interface;
wherein the ionic layer is in contact with the graphene oxide and the second material; and wherein the ionic layer comprises a room temperature ionic fluid and a solidifying material which provides for the ionic layer to be a solid at room temperature.

2. The apparatus of claim 1 , wherein the room temperature ionic fluid is a liquid at room temperature.

3. The apparatus of claim 2 , wherein the room temperature ionic fluid comprises one or more of:
triethylsulfonium bis(trifluoromethane)sulfonimide (TES-TFSI);
1-ethyl-3-methylimidazolium bis(trifluoromethane)sulfonimide (EMIM-TFSI);
trioctylmethylammonium bis(trifluoromethane)sulfonimide (OMA-TFSI); and
another bis(trifluoromethane)sulfonimide (TFSI) containing compound.

4. The apparatus of claim 1 , wherein the solidifying material comprises a covalent polymeric network.

5. The apparatus of claim 1 , wherein the ionic layer comprises a room temperature ionic fluid which is one or more of immobilised, embedded, contained or held in a covalent polymeric network.

6. The apparatus of claim 1 , wherein the second material is provided on a second charge collector, the second charge collector spaced apart from the first charge collector, the second material extending from the second charge collector to the junction.

7. The apparatus of claim 1 , wherein the second material comprises one or more of:
reduced graphene oxide;
potassium hydroxide;
poly(3,4-ethylenedioxythiophene) polystyrene sulfonate;
a base; and
a conducting polymer.

8. The apparatus of claim 1 , wherein the graphene oxide is provided as a mixture of graphene oxide and a proton conductor, wherein the proton conductor is hydrophobic.

9. The apparatus of claim 1 , wherein the ionic layer has one or more of the following properties:
a pencil gauge hardness above 2B at room temperature; and
a glass transition temperature above 50° C.

10. The apparatus of claim 1 , wherein the apparatus is one or more of a battery, a capacitor, a supercapacitor, a battery-capacitor hybrid, an electronic device, a portable electronic device, a portable telecommunications device, a personal digital assistant, a mobile phone, a smartphone, a phablet, a tablet, a laptop computer, a desktop computer, a smartwatch, smart eyewear, an electronic watch, a wireless sensor, an electrochemical sensor, a wearable device, an RFID tag, an electrochromic device, a humidity sensor and a module for one or more of the same.

11. An apparatus comprising two or more of the apparatus of claim 1 arranged in a stack.

12. A method of making an apparatus, comprising
providing graphene oxide on a first charge collector, the graphene oxide configured to generate protons in the presence of water,
providing a second conductive material spaced apart from the first charge collector, the second material having a lower work function than the first charge collector,
the graphene oxide provided so as to extend from the first charge collector to be in contact with the second material at an interface; and
providing an ionic layer in contact with the graphene oxide and the second material, the ionic layer configured to absorb water from the surrounding environment to deliver said water to the apparatus, wherein the ionic layer comprises a room temperature ionic fluid and a solidifying material which provides for the ionic layer to be a solid at room temperature.

13. The method of claim 12 , wherein providing the ionic layer comprises polymerising a cross-linkable oligomer in the presence of the room-temperature ionic fluid to form a covalent polymeric network containing the room-temperature ionic fluid.

14. The method of claim 13 , wherein polymerising the cross-linkable oligomer in the presence of a room-temperature ionic fluid comprises UV irradiation of the room temperature ionic fluid, the cross-linkable oligomer and a UV cross-linking initiator material.

15. The method of claim 14 , wherein the weight ratio between the room temperature ionic fluid, the cross-linkable oligomer and the UV cross-linking initiator is one of: 85:10:5, 80:15:5 or 75:20:5.

Assignees

• Nokia Technologies Oy

Inventors

• Wei Di
• Zarra Salvatore

Classifications

• H01M10/36

  Accumulators not provided for in groups H01M10/05-H01M10/34 · CPC title

• H01G11/54

  Electrolytes · CPC title

• H01M6/22

  Immobilising of electrolyte · CPC title

• H01G11/28 Primary

  arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives · CPC title

• H01M2220/30

  Batteries in portable systems, e.g. mobile phone, laptop · CPC title