Rare earth permanent magnetic material and method of preparing the same

Patent metadata

Field	Value
Publication number	US-10340064-B2
Application number	US-201615192246-A
Country	US
Kind code	B2
Filing date	Jun 24, 2016
Priority date	Dec 27, 2013
Publication date	Jul 2, 2019
Grant date	Jul 2, 2019

Abstract

A rare earth permanent magnetic material contains a main phase of R1 x1 R2 y1 Fe 1-x1-y1-z1-u1 Co z1 B u1 , and an auxiliary phase including a first auxiliary phase of R3 x2 R4 y2 Fe 1-x2-y2-z2-u2-v1 Co z2 B u2 M v1 and a second auxiliary of R5 x3 R6 y3 Fe 1-x3-y3-z3-u3-v2 Co z3 B u3 M v2 . Each of R1, R3 and R5 is Pr and/or Nd. Each of R2, R4 and R6 is at least one of Dy, Tb and Ho. M is at least one of Zr, Ga, Cu, Nb, Sn, Mo, Al, V, W, Si, Hf, Ti, Zn, Bi, Ta and In. 26 wt %≤x1+y1≤34 wt %, 0.01 wt %≤y1≤4 wt %, 0≤z1≤6 wt %, and 0.78 wt %≤u1≤1.25 wt %. 35 wt %≤x2+y2≤82 wt %, 5 wt %≤y2≤42 wt %, 0≤z2≤40 wt %, 0≤u2≤1.25 wt %, and 0≤v1≤10 wt %. 10 wt %≤x3+y3≤32 wt %, 0≤y3≤4.8 wt %, 0≤z3≤40 wt %, 0≤u3≤1.25 wt %, and 31 wt %≤v2≤50 wt %.

First claim

What is claimed is:

1. A rare earth permanent magnetic material comprising:
a main phase represented by R1 x1 R2 y1 Fe 1-x-y1-z1-u1 Co z1 B u1 , wherein R1 is at least one element selected from Pr and Nd; R2 is at least one element selected from Dy, Tb and Ho; x1, y1, z1 and u1 are weight percentages, 26%≤x1+y1≤34%, 0.01%≤y1≤4%, 0≤z1≤6%, and 0.78%≤u1≤1.25%; and
an auxiliary phase separated from or cladding the main phase, comprising a first auxiliary phase and a second auxiliary, wherein
the first auxiliary phase is represented by R3 x2 R4 y2 Fe 1-x2-y2-z2-u2-v1 CO z2 B u2 M v1 , where R3 is at least one element selected from Pr and Nd; R4 is at least one element selected from Dy, Tb and Ho; M is at least one element selected from Zr, Ga, Cu, Nb, Sn, Mo, Al, V, W, Si, Hf, Ti, Zn, Bi, Ta and In; x2, y2, z2, u2 and v1 are weight percentages, 35%≤x2+y2≤82%, 5%≤y2≤42%, 0≤z2≤40%, 0≤u2≤1.25%, and 0≤v1≤10%; and
the second auxiliary phase is represented by R5 x3 R6 y3 Fe 1-x3-y3-z3-u3-v2 Co z3 B u3 M v2 , where R5 is at least one element selected from Pr and Nd; R6 is at least one element selected from Dy, Tb and Ho; M is at least one element selected from Zr, Ga, Cu, Nb, Sn, Mo, Al, V, W, Si, Hf, Ti, Zn, Bi, Ta and In; x3, y3, z3, u3 and v2 are weight percentages, 10%≤x3+y3≤32%, 0≤y3≤4.8%, 0≤z3≤40%, 0.15≤u3≤1.25%, and 31%≤v2≤50%.

2. The rare earth permanent magnetic material of claim 1 , wherein based on the total weight of the main phase and the auxiliary phase, the content of the first auxiliary C1 satisfies: 0<C1≤25 wt %.

3. The rare earth permanent magnetic material of claim 2 , wherein based on the total weight of the main phase and the auxiliary phase, the content of the first auxiliary C1 satisfies: 0<C1≤15 wt %.

4. The rare earth permanent magnetic material of claim 1 , wherein based on the total weight of the main phase and the auxiliary phase, the content of the second auxiliary C2 satisfies: 0<C2≤20 wt %.

5. The rare earth permanent magnetic material of claim 4 , wherein based on the total weight of the main phase and the auxiliary phase, the content of the second auxiliary C2 satisfies: 0<C2≤10 wt %.

6. The rare earth permanent magnetic material of claim 1 , wherein 27%≤x1+y1≤33%, 1%≤y1≤4%, 1%≤z1≤3%, and 0.8%≤u1≤1.1%.

7. The rare earth permanent magnetic material of claim 1 , wherein 37%≤x2+y2≤68%, 9%≤y2≤26%, 0≤z2≤18%, 0≤u2≤1.1%, and 0≤v1≤8%.

8. The rare earth permanent magnetic material of claim 1 , wherein 10%≤x3+y3≤30%, 0≤y3≤4%, 5%≤z3≤18%, 0.1≤u3≤1.1%, and 31%≤v2≤48%.

Assignees

• Byd Co Ltd

Inventors

• Deng Xiaoxia
• Chen Bo
• ZHANG Failang

Classifications

• C22C38/005

  containing rare earths, i.e. Sc, Y, Lanthanides · CPC title

• H01F1/057

  and IIIa elements, e.g. Nd2Fe14B · CPC title

• C22C38/12

  containing tungsten, tantalum, molybdenum, vanadium, or niobium · CPC title

• C22C38/14

  containing titanium or zirconium · CPC title

• B22F2304/10

  Micron size particles, i.e. above 1 micrometer up to 500 micrometer · CPC title