Anti-fog coating

Patent metadata

Field	Value
Publication number	US-10338278-B2
Application number	US-201615295919-A
Country	US
Kind code	B2
Filing date	Oct 17, 2016
Priority date	May 15, 2012
Publication date	Jul 2, 2019
Grant date	Jul 2, 2019

Abstract

The present invention relates to an optical component having a crosslinked anti-fog coating obtainable by covalent attachment of a silane derivative of the formula (2) to the surface of the optical component and crosslinking of adjacent molecules:

R o X m SiB n   (2)

wherein

m=1 to 3, n=1 or 2 and o=0 or 1, with the proviso that m+n+o=4;

the radical X is selected from halogen or C 1-4 -alkoxy, and

for m=2 or 3 the individual radicals X may be identical or different,

the radical R is C 1-4 -alkyl,

the radical B has the structure -B1-B2, in which -B2 is a terminal hydrophilic group which is crosslinked to at least one hydrophilic group of an adjacent molecule of the anti-fog coat, and -B1- represents either a spacer group, which joins the hydrophilic group B2 to the Si atom, or a covalent bond,

where the terminal hydrophilic group -B2 is poly(meth)acrylate, and for n=2 the individual radicals B may be identical or different.

First claim

What is claimed is:

1. An optical component comprising a crosslinked anti-fog coating produced by covalent attachment of a silane derivative of the formula (2) to the surface of the optical component and crosslinking of adjacent molecules:
R o X m SiB n   (2)

wherein:
m=1 to 3,
n=1 or 2, and
o=0 or 1,
with the proviso that m+n+o=4;
the radical X is selected from a halogen or C 1-4 alkoxy, and for m=2 or 3 the individual radicals X are identical or different,
the radical R is C 1-4 -alkyl,
the radical B has the structure -B1-B2, in which -B2 is a terminal hydrophilic group which is crosslinked to at least one hydrophilic group of an adjacent molecule of the anti-fog coat, and -B1- represents either a spacer group, which joins the hydrophilic group B2 to the Si atom, or a covalent bond,
the terminal hydrophilic group -B2 is poly(meth)acrylate, and for n=2 the individual radicals B are identical or different, and
the anti-fog coating has a coat thickness of 100 nm or less.

2. The optical component according to claim 1 , where the covalent attachment of the compound of the formula (2) to the surface of the optical component takes place by reacting at least one of the reactive —Si—X— groups with a suitable reactive surface group to form —Si—O—.

3. The optical component according to claim 1 , where the optical component comprises an anti-reflection coat and the anti-fog coating is applied to the anti-reflection coat.

4. The optical component according to claim 1 , wherein the poly(meth)acrylate of the terminal hydrophilic group -B2 comprises monomer units which are selected from CH 2 ═C(CH 3 ) COOC 1-4 -alkyl, CH 2 ═C(H) COOC 1-4 -alkyl, hydroxyethylene methacrylate, 2-acrylamido-2-methylpropanesulphonic acid, trimethylolpropane triacrylate and pentaerythritol tetraacrylate or mixtures thereof.

5. A method for producing a crosslinked anti-fog coating on an optical component comprising:
covalently bonding a precursor compound to the surface of the optical component, the precursor compound having the formula (3):
R o X m SiC n   (3)

wherein:
m=1 to 3,
n=1 or 2, and
o=0 or 1,
with the proviso that m+n+o=4,

the radical X is selected from a halogen or C 1-4 alkoxy, and for m=2 or 3 the individual radicals X are identical or different,
the radical R is C 1-4 -alkyl,
the radical C has the structure -C1-C2, in which -C2 is a terminal group comprising a (meth)acrylate functionality and -C1- represents either a spacer group or a covalent bond;
reacting the terminal group -C2 with (meth)acrylate monomers to give a hydrophilic poly(meth)acrylate group; and,
crosslinking of the hydrophilic poly(meth)acrylate groups of adjacent molecules,
wherein the step of covalently bonding a precursor compound to the surface of the optical component does not include a surfactant in the step or in the precursor compound bonded to the surface of the optical component.

6. The method according to claim 5 , comprising:
providing the optical component and the covalent attachment of the silane derivative of the formula (3) by chemical reaction with reactive groups on the surface of the optical component, followed by the crosslinking of the hydrophilic groups C2 of adjacent molecules of the anti-fog coating.

7. The method according to claim 5 , wherein the (meth)acrylate monomers are selected from the group consisting of CH 2 ═C(CH 3 )COOC 1-4 -alkyl, CH 2 ═C(H)COOC 1-4 -alkyl, hydroxyethylene methacrylate, 2-acrylamido-2-methylpropanesulphonic acid, trimethylolpropane triacrylate and pentaerythritol tetraacrylate or mixtures thereof.

Assignees

• Zeiss Carl Vision Int Gmbh

Inventors

• Gloege Thomas
• Hugenberg Norbert
• von Blankenhagen Bernhard
• Kraus Stefan

Classifications

• C03C17/30

  with silicon-containing compounds · CPC title

• G02B27/0006

  with means to keep optical surfaces clean, e.g. by preventing or removing dirt, stains, contamination, condensation (G02B1/18 takes precedence; cleaning in general B08B) · CPC title

• C03C2217/75

  Hydrophilic and oleophilic coatings · CPC title

• C03C2218/111

  by dipping, immersion · CPC title

• C08G77/14

  containing silicon bound to oxygen-containing groups · CPC title