Hot-dip galvanized steel sheet and production method therefor

Patent metadata

Field	Value
Publication number	US-10337094-B2
Application number	US-201214131957-A
Country	US
Kind code	B2
Filing date	Aug 1, 2012
Priority date	Aug 5, 2011
Publication date	Jul 2, 2019
Grant date	Jul 2, 2019

Abstract

Provided are a high-strength hot-dip galvanized steel sheet having excellent formability and a tensile strength of 440 MPa or more and a method for manufacturing the same. A steel sheet has a microstructure containing a ferrite phase having an area fraction of 60% or more, a pearlite phase having an area fraction of 20% to 30%, and a bainite phase having an area fraction of 1% to 5%, the area fraction of a cementite phase present in a grain of the ferrite phase being 5% or less. Upon manufacture, a hot-rolled sheet or a cold-rolled sheet is heated to a temperature of 650° C. or higher at an average heating rate of 10° C./s or more, is held at a temperature of 700° C. to (Ac3-5)° C. for ten seconds or more, is cooled to a temperature of 300° C. to 500° C. at an average cooling rate of 10° C./s to 200° C./s, is held at a temperature of 300° C. to 500° C. for 30 seconds to 300 seconds, and is then hot-dip galvanized.

First claim

The invention claimed is:

1. A hot-dip galvanized steel sheet comprising a steel sheet having a composition containing 0.100% to 0.200% C, 0.50% or less Si, 0.60% or less Mn, 0.100% or less P, 0.0100% or less S, 0.010% to 0.100% Al, and 0.0100% or less N on a mass basis, the remainder comprising Fe and inevitable impurities, the steel sheet having a microstructure containing a ferrite phase having an area fraction of 60% to 79%, a pearlite phase having an area fraction of 20% to 30%, and a bainite phase having an area fraction of 1% to 5%, the area fraction of a cementite phase present in a grain of the ferrite phase being 1% or more and 5% or less, wherein the hot-dip galvanized steel sheet has an elongation of 35.6% or more, a tensile strength of 440 MPa to 490 MPa, and a stretch flangeability of 77% or more.

2. The hot-dip galvanized steel sheet according to claim 1 , wherein the composition of the steel sheet further contains at least one selected from the group consisting of 0.05% to 0.80% Cr, 0.005% to 0.100% V, 0.005% to 0.500% Mo, 0.01% to 0.10% Cu, 0.01% to 0.10% Ni, and 0.0003% to 0.2000% B on a mass basis.

3. The hot-dip galvanized steel sheet according to claim 1 , wherein the composition of the steel sheet further contains at least one selected from the group consisting of 0.001% to 0.005% Ca and 0.001% to 0.005% of an REM on a mass basis.

4. The hot-dip galvanized steel sheet according to claim 1 , wherein the composition of the steel sheet further contains at least one selected from the group consisting of 0.05% to 0.80% Cr, 0.005% to 0.100% V, 0.005% to 0.500% Mo, 0.01% to 0.10% Cu, 0.01% to 0.10% Ni, and 0.0003% to 0.2000% B and at least one selected from the group consisting of 0.001% to 0.005% Ca and 0.001% to 0.005% of an REM on a mass basis.

5. The hot-dip galvanized steel sheet according to claim 1 , being a hot-dip galvannealed steel sheet.

6. The hot-dip galvanized steel sheet according to claim 1 , comprising a galvanizing layer, wherein the galvanizing layer is a hot-dip galvannealing layer.

7. The hot-dip galvanized steel sheet according to claim 6 , wherein the galvannealing layer has an Fe content of 7% to 15%.

8. The hot-dip galvaniized steel sheet according to claim 1 , having an elongation of 36.1% or more.

9. The hot-dip galvanized steel sheet according to claim 1 , herein the content of Si is 0.01% to 0.50%.

10. The hot-dip galvanized steel sheet according to claim 1 , wherein the content of Mn is 0.10% to 0.60%.

11. The hot-dip galvanized steel sheet according to claim 1 , wherein the content of P is 0.003% to 0.100%.

12. A method for manufacturing the hot-dip galvanized steel sheet of claim 1 , comprising:
preparing a steel material having a composition containing 0.100% to 0.200% C, 0.50% or less Si, 0.60% or less Mn, 0.100% or less P, 0.0100% or less S, 0.010% to 0.100% Al, and 0.0100% or less N on a mass basis, the remainder comprising Fe and inevitable impurities;
heating the steel material;
hot-rolling the steel material at a finishing delivery temperature not lower than the Ar 3 temperature;
coiling a hot-rolled sheet at a temperature of 600° C. or lower;
pickling the hot-rolled sheet;
cold-rolling the pickled hot-rolled sheet with a reduction of 40% to 85%;
performing heating to a temperature of 650° C. or higher at an average heating rate of 10° C./s or more;
performing holding at a temperature of 700° C. to (Ac 3 −5)° C. for ten seconds or more;
performing cooling to a temperature of 300° C. to 500° C. at an average cooling rate of 10° C./s to 200° C./s;
performing holding at a temperature of 300° C. to 500° C. for 30 seconds to 300 seconds; and
performing hot-dip galvanizing.

13. The hot-dip galvanized steel sheet-manufacturing method according to claim 12 , further comprising performing alloying after hot-dip galvanizing.

14. The hot-dip galvanized steel sheet-manufacturing method according to claim 13 , wherein alloying is performed by heating a steel sheet to a temperature of 450° C. to 600° C.

15. The hot-dip galvanized steel sheet according to claim 1 , wherein the composition of the steel sheet contains 0.49% or less Mn on a mass basis.

Assignees

• Kariya Nobusuke
• Kaneko Shinjiro
• Nagataki Yasunobu
• Jfe Steel Corp

Inventors

• Kariya Nobusuke
• Kaneko Shinjiro
• Nagataki Yasunobu

Classifications

• C23C2/40

  Plates; Strips · CPC title

• B32B15/013

  one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium · CPC title

• C22C38/005

  containing rare earths, i.e. Sc, Y, Lanthanides · CPC title

• Y10T428/12799

  Next to Fe-base component [e.g., galvanized] · CPC title

• C22C38/14

  containing titanium or zirconium · CPC title