Cathode electrode material and lithium sulfur battery using the same

Patent metadata

Field	Value
Publication number	US-10333147-B2
Application number	US-201815871094-A
Country	US
Kind code	B2
Filing date	Jan 15, 2018
Priority date	Jul 20, 2015
Publication date	Jun 25, 2019
Grant date	Jun 25, 2019

Abstract

A cathode electrode material and a lithium sulfur battery are disclosed. The cathode electrode material includes the cathode binder. The cathode binder includes a polymer obtained by polymerizing a dianhydride monomer with a diamine monomer. At least one of the dianhydride monomer and the diamine monomer includes a silicon-containing monomer. The lithium sulfur battery includes an anode electrode, an electrolyte, and the cathode electrode, the cathode electrode includes a sulfur containing cathode active material, a conducting agent, and the cathode binder.

First claim

What is claimed is:

1. A cathode electrode material comprising a sulfur containing cathode active material, a conducting agent, and a cathode binder, wherein the cathode binder comprises a polymer obtained by polymerizing a dianhydride monomer with a diamine monomer, wherein at least one of the dianhydride monomer and the diamine monomer comprises a silicon-containing monomer.

2. The cathode electrode material of claim 1 , wherein the dianhydride monomer comprises a first monomer represented by a formula I,

wherein R 1 is a first silicon-containing bivalent organic substituent.

3. The cathode electrode material of claim 2 , wherein R 1 is selected from the group consisting of

wherein n is in a range from 1 to 6; R 5 , R 6 , R 7 , and R 8 are independently selected from the group consisting of an alkyl group with 1 to 6 carbon atoms, an alkoxy group with 1 to 6 carbon atoms, a monovalent alicyclic group, a monovalent substituted alicyclic group, a monovalent aromatic group, a monovalent substituted aromatic group, —C(O)R, —RS(O)R, and —RNH 2 R, wherein R is an alkyl group with 1 to 6 carbon atoms.

4. The cathode electrode material of claim 2 , wherein R 1 is selected from the group consisting of

5. The cathode electrode material of claim 1 , wherein the diamine monomer comprises a second monomer represented by a formula II,

wherein R 2 is a second silicon-containing bivalent organic substituent.

6. The cathode electrode material of claim 5 , wherein R 2 is selected from the group consisting of

wherein n is in a range from 1 to 6; R 5 , R 6 , R 7 , and R 8 are independently selected from the group consisting of an alkyl group with 1 to 6 carbon atoms, an alkoxy group with 1 to 6 carbon atoms, a monovalent alicyclic group, a monovalent substituted alicyclic group, a monovalent aromatic group, a monovalent substituted aromatic group, —C(O)R, —RS(O)R, and —RNH 2 R, wherein R is an alkyl group with 1 to 6 carbon atoms.

7. The cathode electrode material of claim 5 , wherein R 2 is selected from the group consisting of

8. The cathode electrode material of claim 5 , wherein the dianhydride monomer comprises a third monomer represented by formulas III, IV, or V,

wherein R 3 is a third bivalent organic substituent containing no silicon atom.

9. The cathode electrode material of claim 8 , wherein the diamine monomer comprises a fourth monomer represented by a formula VI,

wherein R 4 is a fourth bivalent organic substituent containing no silicon atom.

10. The cathode electrode material of claim 1 , wherein at least one of the dianhydride monomer and the diamine monomer comprises a silicon-free monomer, a molar ratio of a total amount of the silicon-containing monomer to a total amount of the silicon-free monomer is in a range from 1:100 to 10:1.

11. The cathode electrode material of claim 1 , wherein at least one of the dianhydride monomer and the diamine monomer comprises a silicon-free monomer, a molar ratio of all of the silicon-containing monomer to all of the silicon-free monomer is in a range from 1:20 to 1:1.

12. The cathode electrode material of claim 1 , wherein a molar ratio of all of the dianhydride monomer to all of the diamine monomer is in a range from 1:2 to 4:1.

13. The cathode electrode material of claim 1 , wherein a molecular weight of the polymer obtained by polymerizing the dianhydride monomer with the diamine monomer is in a range from about 10000 to about 600000.

14. The cathode electrode material of claim 1 , wherein the sulfur containing cathode active material is at least one of elemental sulfur and sulfur based polymer, and the sulfur based polymer is selected from the group consisting of sulfurized poly(pyridinopyridine), sulfurized polystyrene, sulfurized polyoxyethylene, sulfurized polyvinyl alcohol, sulfurized poly(vinylidene chloride), sulfurized poly(vinylidene difluoride), sulfurized polyvinylchloride, sulfurized polyvinyl fluoride, sulfurized poly(1,2-dichloroethylene), sulfurized poly(1,2-difluoroethylene), sulfurized polymethyl methacrylate, sulfurized phenolic resin, and combinations thereof.

15. A lithium sulfur battery comprising:
a cathode electrode;
an electrolyte; and
an anode electrode,
wherein the cathode electrode comprises a sulfur containing cathode active material, a conducting agent, and a cathode binder, wherein the cathode binder comprises a polymer obtained by polymerizing a dianhydride monomer with a diamine monomer, and at least one of the dianhydride monomer and the diamine monomer comprises a silicon-containing monomer.

16. A cathode electrode material comprising a sulfur containing cathode active material, a conducting agent, and a cathode binder, wherein the cathode binder comprises a polymer obtained by polymerizing a dianhydride monomer with a diamine monomer, wherein the dianhydride monomer comprises a silicon-containing monomer.

17. The cathode electrode material of claim 16 , wherein the dianhydride monomer comprises a first monomer represented by a formula I,

wherein R 1 is a first silicon-containing bivalent organic substituent.

18. The cathode electrode material of claim 17 , wherein R 1 is selected from the group consisting of

wherein n is in a range from 1 to 6; R 5 , R 6 , R 7 , and R 8 are independently selected from the group consisting of an alkyl group with 1 to 6 carbon atoms, an alkoxy group with 1 to 6 carbon atoms, a monovalent alicyclic group, a monovalent substituted alicyclic group, a monovalent aromatic group, a monovalent substituted aromatic group, —C(O)R, —RS(O)R, and —RNH 2 R, wherein R is an alkyl group with 1 to 6 carbon atoms.

19. The cathode electrode material of claim 17 , wherein R 1 is selected from the group consisting of

20. The cathode electrode material of claim 16 , wherein the diamine monomer containing no silicon atom, a molar ratio of all of the silicon-containing monomer to all of silicon-free monomer is in a range from 1:20 to 1:1.

Assignees

• Univ Tsinghua

Inventors

• He xiang-ming
• Qian guan-nan
• Wang Li

Classifications

• H01M4/1399

  of electrodes based on electro-active polymers · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/602

  Polymers · CPC title

• H01M10/052

  Li-accumulators · CPC title