Curable prepregs with surface openings

Patent metadata

Field	Value
Publication number	US-10329696-B2
Application number	US-201715712481-A
Country	US
Kind code	B2
Filing date	Sep 22, 2017
Priority date	Dec 21, 2012
Publication date	Jun 25, 2019
Grant date	Jun 25, 2019

Abstract

Curable prepregs possessing enhanced ability for the removal of gases from within prepregs and between prepreg plies in a prepreg layup prior to and/or during consolidation and curing. Each curable prepreg is a resin-impregnated, woven fabric that has been subjected to a treatment to create an array of openings in at least one major surface. Furthermore, the location of the openings is specific to the weave pattern of the fabric.

First claim

What is claimed is:

1. A curable prepreg produced by a method comprising:
providing a woven fabric having two opposing faces and a plain weave pattern in which a tow in a first weaving direction passes over another tow in a second weaving direction, then pass under an adjacent tow in the second weaving direction, and interstices are defined between adjacent tows, wherein the woven fabric has an areal weight of 100-600 gsm;
partially impregnating the woven fabric with a curable, hot-melt resin such that a continuous resin film covers each face of the fabric and penetrates partially through the thickness of the fabric leaving an inner section of the fabric, in the thickness direction, substantially free of said resin, wherein each resin film has a film weight of 10-200 gsm:
heating the partially impregnated fabric so that the resin film on each face of the fabric becomes flowable, and subsequently, portions of the resin film over the air pockets at the interstices break open, creating openings in the resin film that correspond to locations of the interstices, wherein the locations of the openings are dependent on the plain weave pattern, and
each opening exposes a single interstice in the fabric and is configured to create a fluid flow path from the inner section of the fabric to at least one outer surface of the prepreg, from at least one outer surface of the prepreg to the inner section, from one outer surface of the prepreg to an opposite outer surface, or combination thereof.

2. The curable prepreg of claim 1 , wherein the hot-melt resin film is substantially solid at a temperature within the range of 20° C.-25° C. and becomes flowable at an elevated temperature below an onset curing temperature of the resin film.

3. The curable prepreg of claim 1 , wherein the hot-melt resin film comprises one or more thermoset resins as a major component, and is substantially free of any organic solvent.

4. The curable prepreg of claim 1 , wherein the hot-melt resin film comprises one or more epoxy resins, a curing agent, and at least one thermoplastic or elastomeric compound.

5. The curable prepreg of claim 1 , wherein each tow comprises a plurality of fiber filaments, which are formed of a material selected from: glass, carbon, aramid, polyethylene (PE), boron, quartz, basalt, ceramic, polyester, poly-p-phenylene-benzobisoxazole (PBO), and combinations thereof.

Assignees

• Cytec Ind Inc

Inventors

• Roman Mark
• Howard Stephen J
• Boyd Jack D

Classifications

• B32B2262/0276

  Polyester fibres · CPC title

• Y10T442/20

  Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer · CPC title

• Y10T442/2861

  Coated or impregnated synthetic organic fiber fabric · CPC title

• B32B2363/00

  Epoxy resins · CPC title

• B32B27/38

  comprising epoxy resins · CPC title