Epoxy resin composition

Patent metadata

Field	Value
Publication number	US-10329465-B2
Application number	US-201715626266-A
Country	US
Kind code	B2
Filing date	Jun 19, 2017
Priority date	Dec 22, 2014
Publication date	Jun 25, 2019
Grant date	Jun 25, 2019

Abstract

The present invention relates to adhesive compositions containing a prepolymer which can be obtained by reacting a reaction mixture containing: at least one epoxy resin; at least one polyetherdiamine or polyethertriamine; at least one carboxyl-terminated butadiene-acrylonitrile copolymer (CTBN); and rubber particles having a core/shell structure. The invention also relates to methods for curing said compositions, to the cured adhesive compositions thus obtained, to the use thereof for bonding components and to the components thus obtained.

First claim

What is claimed is:

1. An adhesive composition, comprising: a curable epoxy prepolymer, a curing agent, and rubber particles having a core/shell structure;
wherein the curable epoxy prepolymer is obtained by reacting (a), (b), and (c) in a reaction mixture containing (a), (b), (c), and (d):
(a) at least one epoxy resin having at least two 1,2-epoxy groups per molecule;
(b) at least one polyetherdiamine or polyethertriamine;
(c) at least one carboxyl-terminated butadiene-acrylonitrile copolymer (CTBN) or epoxy resin adduct thereof; and
(d) said rubber particles having a core/shell structure;

wherein a total of epoxy groups in the reaction mixture is in excess relative to a total of epoxy-reactive groups in the reaction mixture;
wherein the reaction mixture does not contain a diglycidyl ether epoxy resin which is solid at room temperature; and
wherein a cured product of the adhesive composition has: a modulus of elasticity of <800 MPa and/or a glass transition temperature T g of >100° C.

2. The adhesive composition according to claim 1 , characterized in that:
(a) the at least one epoxy resin having at least two 1,2-epoxy groups per molecule is a diglycidyl ether epoxy resin, which is liquid at room temperature; and/or
(b) the at least one polyetherdiamine or polyethertriamine is an amino-terminated polypropylene oxide.

3. The adhesive composition according to claim 1 , characterized in that:
(c) the at least one carboxyl-terminated butadiene-acrylonitrile copolymer (CTBN) or epoxy resin adduct thereof is an epoxy resin adduct thereof.

4. The adhesive composition according to claim 1 , characterized in that the curing agent is a latent curing agent.

5. The adhesive composition according to claim 1 , which further comprises a curing accelerator.

6. The adhesive composition according to claim 1 , which further comprises at least one filler.

7. A method for producing a cured adhesive composition, which comprises:
(a) providing an adhesive composition according to claim 1 ; and
(b) partially or fully curing the adhesive composition through exposure to conditions suitable for curing the adhesive composition.

8. A method for bonding at least two components, which comprises:
(a) applying an adhesive composition according to claim 1 to one or both of the components to be bonded;
(b) bringing the components into contact such that the adhesive composition is located between the two components; and
(c) partially or fully curing the adhesive composition through exposure to conditions suitable for curing the adhesive composition.

9. A component obtained by the method according to claim 8 .

Assignees

• Holtgrewe Christian
• Kuester Harald
• Bachon Thomas
• Schoenfeld Rainer
• Henkel Ag & Co Kgaa

Inventors

• Holtgrewe Christian
• Kuester Harald
• Bachon Thomas
• Schoenfeld Rainer

Classifications

• C08G59/504

  containing an atom other than nitrogen belonging to the amine group, carbon and hydrogen · CPC title

• C09J163/00 Primary

  Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins · CPC title

• C08G59/4261

  Macromolecular compounds obtained by reactions involving only unsaturated carbon-to-carbon bindings (C08G59/4253 takes precedence) · CPC title

• C08G2650/50

  containing nitrogen, e.g. polyetheramines or Jeffamines(r) · CPC title

• C08G59/186

  with acids · CPC title