Minimizing water content in ethanolamine product streams

Patent metadata

Field	Value
Publication number	US-10329239-B2
Application number	US-201515301576-A
Country	US
Kind code	B2
Filing date	Apr 2, 2015
Priority date	Apr 4, 2014
Publication date	Jun 25, 2019
Grant date	Jun 25, 2019

Abstract

Systems and method are provided for reducing the water content from approximately 0.15%-0.19% by weight to approximately 0.01-0.03% by weight in an ethanolamine product stream in a non-reactive distillation column. The reduced water content can be achieved by increasing the processing conditions at the drying column by approximately 5% to approximately 20%, more preferably to approximately 10%. The increased processing conditions at the drying column can result in an increased bottom stream flow rate and an increased reboiler duty. The reboiler duty of the drying column can be increased by up to 2% to achieve said level of water content. The bottom stream flow rate can be increased by up to approximately 12% to achieve said level of water content.

First claim

The invention claimed is:

1. A method for producing an ethanolamine product stream in a non-reactive distillation column, comprising:
mixing an ammonia solution comprising 30% to 40% by weight ammonia with ethylene oxide in a reactor to create a resultant product stream, wherein said resultant product stream comprises ethanolamines, unreacted ammonia and water;
removing 30% to 50% by weight of the unreacted ammonia and 50% to 70% by weight of water from the resultant product stream to create a stripped product stream, wherein the stripped product stream comprises ethanolamines and 30% to 50% by weight of water;
operating a vacuum drying column at adjusted processing conditions, wherein said processing conditions are selected from: the stripped product stream flow rate, reflux rate at the vacuum drying column, condenser heat duty at the vacuum drying column, reboiler heat duty at the vacuum drying column, bottom rate at the vacuum drying column and a combination comprising at least one of the foregoing, and where said adjusted processing conditions are 5% to 20% above a base case value of the selected processing conditions, wherein the base case value comprises the stripped product stream at a flow rate of 14,798 kg/hr, a reflux rate of 1,600 kg/hr, a condenser heat duty of 8,860 kiloWatts, a reboiler heat duty of 7,483 kiloWatts, and a bottom rate of 14,798 kg/hr;
transferring the stripped product stream to a stage of the vacuum drying column to create a dehydrated product stream; and
removing a portion of residual water from the stripped product stream at the vacuum drying column to create a dehydrated product stream, wherein said dehydrated product stream comprises ethanolamines and 0.01% to 0.03% by weight of water.

2. The method of claim 1 , wherein the dehydrated product stream is transferred to one or more columns for the recovery of monoethanolamine, diethanolamine and triethanolamine.

3. The method of claim 1 , wherein the ammonia solution comprises 50% to 70% by weight of water, 1% to 5% by weight of monoethanolamine, and 1% to 5% by weight of diethanolamine.

4. The method of claim 3 , wherein the ammonia solution comprises 33% by weight ammonia, 62% by weight of water, 2.7% of monoethanolamine, and 2.2% of diethanolamine.

5. The method of claim 1 , wherein the ethanolamines are selected from monoethanolamine, diethanolamine, triethanolamine and combinations comprising at least one of the foregoing.

6. The method of claim 1 , wherein the unreacted ammonia is recycled and added to the ammonia solution.

7. The method of claim 1 , wherein the vacuum drying column is operated at a pressure from 260 mbar to 280 mbar and a temperature at top stages of the vacuum drying column from 55° C. to 75° C., and a temperature at bottom stages of the vacuum drying column from 140° C. to 160° C.

8. The method of claim 1 , wherein the reactor is operated at a temperature of 37° C. to 70° C. and a pressure of 15 barg to 30 barg.

9. The method of claim 1 , wherein the vacuum drying column comprises a heat exchanger selected from thermosiphon, a reboiler, and combinations comprising at least one of the foregoing.

10. The method of claim 9 , wherein the heat exchange is a reboiler.

11. The method of claim 1 , wherein the adjusted processing conditions are increased by 10% above the base case value.

12. The method of claim 1 , wherein the adjusted processing conditions increase the reboiler duty from 7,000 kiloWatts to 10,000 kiloWatts.

13. The method of claim 12 , wherein the reboiler duty is increased from 7,483 kiloWatts to 9,099 kiloWatts.

14. The method of claim 1 , wherein the reboiler duty is at least 9,099 kiloWatts.

15. The method of claim 1 , wherein the adjusted processing conditions increase bottom flow rate from 14,000 kg/hr to 17,000 kg/hr.

16. The method of claim 15 , wherein the bottom flow rate increases from 14,798 kg/hr to 16,816 kg/hr.

17. The method of claim 16 , wherein the bottom flow rate is at least 16,816.41 Kg/hr.

18. The method of claim 1 , wherein the reactor comprises a multi-stage reactor.

19. The method of claim 18 , wherein the multi-stage reactor comprises six stages.

Assignees

• Sabic Global Technologies Bv

Inventors

• Al-Hazmi Naeem

Classifications

• Y02P20/127

  Cross-Sectional Technologies · mapped topic

• C07C215/08

  with only one hydroxy group and one amino group bound to the carbon skeleton · CPC title

• C07C213/10 Primary

  Separation; Purification; Stabilisation; Use of additives · CPC title

• C07C213/04 Primary

  by reaction of ammonia or amines with olefin oxides or halohydrins · CPC title

• Y02P20/10

  Process efficiency · CPC title