Method and apparatus for producing hydrocarbons

Patent metadata

Field	Value
Publication number	US-10329214-B2
Application number	US-201515533002-A
Country	US
Kind code	B2
Filing date	Dec 2, 2015
Priority date	Dec 5, 2014
Publication date	Jun 25, 2019
Grant date	Jun 25, 2019

Abstract

A method for producing hydrocarbons is proposed, in which a product stream containing hydrocarbons is produced from a methane-rich feed stream and from an oxygen-rich feed stream in a reaction unit which is configured for implementing a method for oxidative coupling of methane, the product stream or at least a stream formed therefrom being treated cryogenically in at least one separation unit using at least one liquid, methane-rich stream. It is provided that in the at least one separation unit (10) a recycle stream is formed from methane contained in product stream (c) and from methane contained in the at least one liquid, methane-rich stream (e, v), the recycle stream being fed to the reaction unit (1) as the methane-rich feed stream (a), and in that the liquid, methane-rich stream (e, v) is provided as makeup.

First claim

The invention claimed is:

1. A method for producing hydrocarbons by oxidative coupling of methane comprising:
contacting a methane-rich feed stream and an oxygen-rich feed stream in a reaction unit configured for oxidative coupling of methane to produce a product stream comprising hydrocarbons and unreacted methane;
cryogenically separating the product stream in at least one separation unit using at least one liquid, methane-rich stream to form a recycle stream comprising unreacted methane and at least a portion of methane contained in the at least one liquid, methane-rich stream; and
feeding the recycle stream to the reaction unit, wherein the methane-rich feed stream consists of the recycle stream and the methane-rich feed stream is the only methane feed to the reaction unit;
wherein the at least one liquid, methane-rich stream is produced using a pressurised, methane-containing gas mixture that is provided separately from the product stream and wherein the liquid, methane-rich stream is used in an amount that is greater than or equal to the amount of methane which is converted in the reaction unit and which is lost by separation losses.

2. The method according to claim 1 , wherein the cryogenic separation comprises a cooling procedure in at least one heat exchanger which is operated with the at least one liquid, methane-rich stream as refrigerant.

3. The method according to claim 1 , wherein the cryogenic separation comprises a separation procedure in a cryogenic separation device in which the at least one liquid, methane-rich stream is charged as reflux.

4. The method according to claim 3 , wherein an absorption column and/or a distillation column is used as the cryogenic separation device.

5. The method according to claim 1 , wherein natural gas is used as the pressurised, methane-containing gas mixture.

6. The method according to claim 1 , wherein the liquid, methane-rich stream is produced at least in part from a liquid stream which is formed from the pressurised, methane-containing gas mixture using a distillation process.

7. The method according to claim 6 , wherein the pressurised, methane-containing gas mixture is at least partly rid of impurities before the distillation process is carried out.

8. The method according to claim 7 , wherein sulphur compounds, carbon dioxide and/or mercury are at least partly removed from the pressurised, methane-containing gas mixture.

9. The method according to claim 6 , wherein the pressurised, methane-containing gas mixture is depleted in nitrogen, hydrogen and/or helium in the distillation process.

10. The method according to claim 9 , wherein a dividing wall column is used to deplete the pressurised, methane-containing gas mixture in nitrogen, hydrogen and/or helium in the distillation process.

Assignees

• Linde Ag

Inventors

• Fritz Helmut

Classifications

• F25J3/0209

  Natural gas or substitute natural gas · CPC title

• F25J3/0252

  separation of hydrogen (production of hydrogen containing gas in general C01B3/00, e.g. separation of hydrogen or hydrogen containing gases form gaseous mixtures at low temperatures C01B3/506) · CPC title

• F25J2200/74

  Refluxing the column with at least a part of the partially condensed overhead gas · CPC title

• F25J3/0238

  separation of CnHm with 2 carbon atoms or more · CPC title

• F25J2290/50

  Arrangement of multiple equipments fulfilling the same process step in parallel · CPC title