Positive electrode including discrete aluminum oxide nanomaterials and method for forming aluminum oxide nanomaterials

Patent metadata

Field	Value
Publication number	US-10326142-B2
Application number	US-201514855142-A
Country	US
Kind code	B2
Filing date	Sep 15, 2015
Priority date	Sep 15, 2015
Publication date	Jun 18, 2019
Grant date	Jun 18, 2019

Abstract

A positive electrode includes a lithium-based active material, a binder, a conductive filler, and discrete aluminum oxide nanomaterials. The aluminum oxide nanomaterials are mixed, as an additive, throughout the positive electrode with the lithium-based active material, the binder, and the conductive filler. The positive electrode with the discrete aluminum oxide nanomaterials may be incorporated into a lithium ion battery. The aluminum oxide nanomaterials may be formed by the following method. A solution is formed by mixing an aluminum oxide precursor and an acid. A carbon material is added to the solution, thereby forming an aqueous mixture having the carbon material therein. Hydrothermal synthesis is performed using the aqueous mixture, and precursor nanostructures are grown on the carbon material. The precursor nanostructures on the carbon material are annealed so that the carbon material is removed and aluminum oxide nanomaterials are formed.

First claim

What is claimed is:

1. A positive electrode, comprising:
a lithium-based active material;
a binder;
a conductive filler; and
additives for scavenging hydrofluoric acid (HF) within the positive electrode, the additives comprising:
discrete aluminum oxide nanomaterials comprising nanostructures extending radially and outward from a center and having a surface area of at least 150 m 2 /g; and
discrete aluminum oxide nanostructures, wherein the discrete aluminum oxide nanomaterials and discrete aluminum oxide nanostructures each comprise a plurality of absorbing sites that absorb the hydrofluoric acid (HF) and are substantially uniformly mixed throughout the positive electrode, with the lithium-based active material, the binder, and the conductive filler.

2. The positive electrode as defined in claim 1 wherein the aluminum oxide nanomaterials are present in amount ranging from greater than 0 wt % to about 10 wt % based on a total wt % of the positive electrode.

3. The positive electrode as defined in claim 1 wherein:
the lithium-based active material is present in an amount ranging from about 50 wt % to about 95 wt % based on a total wt % of the positive electrode;
the binder is present in an amount ranging from about 5 wt % to about 20 wt % based on the total wt % of the positive electrode;
the conductive filler is present in an amount ranging from about 5 wt % to about 20 wt % based on the total wt % of the positive electrode; and
the aluminum oxide nanomaterials are present in an amount ranging from greater than 0 wt % up to about 10 wt % based on the total wt % of the positive electrode.

4. The positive electrode as defined in claim 1 wherein the nanostructures are connected to one another at or near the center.

5. The positive electrode as defined in claim 1 wherein at least a portion of the discrete aluminum oxide nanostructures are laterally disposed throughout the positive electrode.

6. A lithium-based battery, comprising:
a positive electrode, including:
a lithium-based active material;
a binder;
a conductive filler;
discrete aluminum oxide nanomaterials; and
discrete aluminum oxide nanostructures, wherein the discrete aluminum oxide nanomaterials and discrete aluminum oxide nanostructures are substantially uniformly mixed throughout the positive electrode as an additive for scavenging hydrofluoric acid (HF) within the positive electrode with the lithium-based active material, the binder, and the conductive filler, wherein the discrete aluminum oxide nanomaterials include nanostructures extending radially and outward from a center and having a surface area of at least 150 m 2 /g, and wherein the discrete aluminum oxide nanomaterials and the discrete aluminum oxide nanostructures each comprise a plurality of absorbing sites that absorb the hydrofluoric acid (HF),

a negative electrode,
a solid-electrolyte interphase (SEI) on a surface of the negative electrode that mitigates transition metal dissolution within the lithium-based battery; and
a microporous polymer separator soaked in an electrolyte solution, the microporous polymer separator being disposed between the positive electrode and the negative electrode.

7. The lithium-based battery as defined in claim 6 wherein the aluminum oxide nanomaterials are present in amount ranging from greater than 0 wt % to about 10 wt % based on a total wt % of the positive electrode.

8. The lithium-based battery as defined in claim 6 wherein the nanostructures are connected to one another at or near the center.

9. A method, comprising:
forming a solution by mixing an aluminum oxide precursor and an acid;
adding a carbon material to the solution, thereby forming an aqueous mixture having the carbon material therein;
performing hydrothermal synthesis using the aqueous mixture, thereby growing precursor nanostructures on the carbon material; and
annealing the precursor nanostructures on the carbon material, thereby removing the carbon material to form aluminum oxide nanomaterials and discrete aluminum oxide nanostructures, wherein the aluminum oxide nanomaterials and discrete aluminum oxide nanostructures are substantially uniformly mixed throughout a positive electrode, as additives for scavenging hydrofluoric acid (HF) within the positive electrode, wherein the discrete aluminum oxide nanomaterials and discrete aluminum oxide nanostructures each comprise a plurality of absorbing sites that absorb the hydrofluoric acid (HF), wherein the aluminum oxide nanomaterials include nanostructures extending radially and outward from a center and have a surface area of at least 150 m 2 /g.

10. The method as defined in claim 9 wherein the aluminum oxide precursor is AlCl 3 or Al(O-i-Pr) 3 .

11. The method as defined in claim 9 wherein the solution has a potential hydrogen (pH) value ranging from about 1 to about 3.

12. The method as defined in claim 9 wherein the hydrothermal synthesis includes subjecting the aqueous mixture to heat and vapor pressure in a closed system, thereby causing growth of the precursor nanostructures radially and outward from the carbon material.

13. The method as defined in claim 9 , further comprising:
removing the precursor nanostructures and any liquid present after the hydrothermal synthesis from a closed system prior to the annealing of the precursor nanostructures;
wherein the annealing of the precursor nanostructures occurs by applying a heat treatment in an oxygen-containing environment at a temperature ranging from about 400° C. to about 800° C. for a time ranging from about 3 hours to about 8 hours, thereby forming the aluminum oxide nanomaterials.

14. The method as defined in claim 9 wherein the carbon material is hollow carbon or graphite.

15. The method as defined in claim 9 wherein the method further comprises breaking off at least some nanostructures extending radially and outward from the center.

16. The method as defined in claim 9 , further comprising:
dry mixing the aluminum oxide nanomaterials into a mixture, the mixture including a lithium-based active material and a conductive filler;
adding a binder and a solvent to the mixture;
mixing the mixture to form a slurry;
depositing the slurry onto a support; and
drying the slurry to form the positive electrode.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Wu Yan
• Liu Zhongyi
• Huang Xiaosong
• Yang Xingyi

Classifications

• C01P2006/12

  Surface area · CPC title

• H01M4/621

  Binders · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• C01F7/34

  Preparation of aluminium hydroxide by precipitation from solutions containing aluminium salts · CPC title

• H01M4/625

  Carbon or graphite · CPC title