Nonaqueous electrolyte battery, battery pack, and vehicle

Patent metadata

Field	Value
Publication number	US-10326140-B2
Application number	US-201715445726-A
Country	US
Kind code	B2
Filing date	Feb 28, 2017
Priority date	Sep 21, 2016
Publication date	Jun 18, 2019
Grant date	Jun 18, 2019

Abstract

According to one embodiment, a nonaqueous electrolyte battery including a negative electrode that includes a negative electrode current collector and a negative electrode mixed-materials layer is provided. The negative electrode mixed-materials layer includes a titanium-including metal oxide particle that includes a phase including a carbon material on a surface and a binder that includes an acrylic resin. The negative electrode satisfies Equation (I):

α/β>6  (I)
α is a peel strength (kN/m) between the negative electrode current collector and the negative electrode mixed-materials layer, and β is a cutting strength (kN/m) in the negative electrode mixed-materials layer.

First claim

What is claimed is:

1. A nonaqueous electrolyte battery comprising:
a positive electrode;
a negative electrode comprising a negative electrode current collector, and a negative electrode mixed-materials layer disposed on the negative electrode current collector, the negative electrode mixed-materials layer having a thickness of 10 μm to 75 μm and comprising a titanium-comprising metal oxide particle capable of having lithium ions inserted into and extracted from, and a binder that comprises an acrylic resin, the titanium-comprising metal oxide particle comprising a phase that comprises a carbon material on at least a portion of a surface thereof, and the negative electrode satisfying Equation (I); and
a nonaqueous electrolyte:
α/β>6  (I)

wherein, in Equation (I), α is a peel strength (kN/m) between the negative electrode current collector and the negative electrode mixed-materials layer according to a surface/interface cutting method, and β is a cutting strength (kN/m) in the negative electrode mixed-materials layer according to the surface/interface cutting method.

2. The nonaqueous electrolyte battery according to claim 1 , wherein the peel strength α is from 1.1 kN/m to 20 kN/m.

3. The nonaqueous electrolyte battery according to claim 1 , wherein the titanium-comprising metal oxide particle is a particle comprising at least one selected from the group consisting of spinel type lithium titanate, monoclinic titanium dioxide, monoclinic titanium composite oxide, niobium-titanium composite oxide represented by a formula Ti 1−x M x+y Nb 2−y O 7−δ , wherein 0≤x<1, 0≤y<1, M is at least one selected from the group consisting of Mg, Fe, Ni, Co, W, Ta, and Mo, and orthorhombic Na-comprising niobium-titanium composite oxide represented by a formula Li 2+v Na 2−w M1 x Ti 6−y−z Nb y M2 z O 14+δ , wherein 0≤v≤4, 0<w<2, 0≤x<2, 0<y<6, 0≤z<3, y+z<6, −0.5≤δ≤0.5, M1 is at least one selected from the group consisting of Cs, K, Sr, Ba, and Ca, and M2 is at least one selected from the group consisting of Zr, Sn, V, Ta, Mo, W, Fe, Co, Mn, and Al.

4. The nonaqueous electrolyte battery according to claim 1 , wherein the acrylic resin is an acrylic resin comprising a nitrile group, or a copolymer of the acrylic resin comprising the nitrile group.

5. The nonaqueous electrolyte battery according to claim 1 , wherein the acrylic resin is an acrylic resin that comprises a methacrylate copolymer comprising a phosphate group.

6. The nonaqueous electrolyte battery according to claim 1 , wherein the binder comprises a mixture of the acrylic resin and a methacrylate-based resin, and a mixing ratio of the acrylic resin is from 50 wt % to 90 wt %.

7. The nonaqueous electrolyte battery according to claim 1 , wherein the binder has a weight average molecular weight of 10,000 to 50,000,000.

8. The nonaqueous electrolyte battery according to claim 1 , wherein the carbon material satisfies a ratio I G /I D of a peak intensity I G of a G band to a peak intensity I D of a D band of from 0.8 to 1.2, the G band being observed at 1530 cm −1 to 1630 cm −1 in a Raman chart obtained by Raman spectroscopy measurement using a measurement light source of 532 nm of the carbon material, and the D band being observed at 1280 cm −1 to 1380 cm −1 in the Raman chart.

9. A battery pack comprising the nonaqueous electrolyte battery according to claim 1 .

10. The battery pack according to claim 9 further comprising:
an external power distribution terminal; and
a protective circuit.

11. The battery pack according to claim 9 , comprising a plurality of the nonaqueous electrolyte batteries, the nonaqueous electrolyte batteries being electrically connected in series, in parallel, or in a combination of series and parallel.

12. A vehicle comprising the battery pack according to claim 9 .

13. The vehicle according to claim 12 , wherein the battery pack is configured to recover a regenerative energy of a power of the vehicle.

14. An electrode comprising:
a current collector; and
a mixed-materials layer disposed on the current collector, the mixed-materials layer having a thickness of 10 μm to 75 μm and comprising a titanium-comprising metal oxide particle capable of having lithium ions inserted into and extracted from, and a binder that comprises an acrylic resin, the titanium-comprising metal oxide particle comprising a phase that comprises a carbon material on at least a portion of a surface thereof,
the electrode satisfying Equation (I):
α/β>6  (I)

wherein, in Equation (I), α is a peel strength (kN/m) between the current collector and the mixed-materials layer according to a surface/interface cutting method, and β is a cutting strength (kN/m) in the mixed-materials layer according to the surface/interface cutting method.

15. The electrode according to claim 14 , wherein the peel strength α is from 1.1 kN/m to 20 kN/m.

16. The electrode according to claim 14 , wherein the titanium-comprising metal oxide particle is a particle comprising at least one selected from the group consisting of spinet type lithium titanate, monoclinic titanium dioxide, monoclinic titanium composite oxide, niobium-titanium composite oxide represented by a formula Ti 1−x M x+y Nb 2−y O 7−δ , wherein 0≤x<1, 0≤y<1, M is at least one selected from the group consisting of Mg, Fe, Ni, Co. W, Ta, and Mo, and orthorhombic Na-comprising niobium-titanium composite oxide represented by a formula Li 2+v Na 2−w M1 x Ti 6−y−z Nb y M2 z O 14+δ , wherein 0≤v≤4, 0<w<2, 0≤x<2, 0<y<6, 0≤z<3, y+z<6, −0.5≤δ≤0.5, M1 is at least one selected from the group consisting of Cs, K, Sr, Ba, and Ca, and M2 is at least one selected from the group consisting of Zr, Sn, V, Ta, Mo,W, Fe. Co, Mn, and Al.

17. The electrode according to claim 14 , wherein the acrylic resin is an acrylic resin comprising a nitrile group, or a copolymer of the acrylic resin comprising the nitrile group.

18. The electrode according to claim 14 , wherein the cutting strength β is 0.18 kN/m to 3.33 kN/m.

19. The electrode according to claim 14 , wherein the peel strength α and the cutting strength β satisfy α/β<7.

Assignees

• Toshiba Kk

Inventors

• Yamashita Yasunobu
• Isozaki Yoshiyuki
• Ishibashi Mitsuru
• Ise Kazuki
• Takami Norio

Classifications

• H01M10/0525 Primary

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/622 Primary

  being polymers · CPC title

• H01M4/131 Primary

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/0404

  by coating on electrode collectors · CPC title