Energy storage system using rare earth and hydroxyl co-doped ceramic in humid-environment

Patent metadata

Field	Value
Publication number	US-10325724-B2
Application number	US-201715473364-A
Country	US
Kind code	B2
Filing date	Mar 29, 2017
Priority date	Mar 29, 2017
Publication date	Jun 18, 2019
Grant date	Jun 18, 2019

Abstract

An energy storage system includes a hermetically-sealed casing defining a volume whose relative humidity is a range of 30-90%. At least one energy storage capacitor disposed in the volume has a solid dielectric sandwiched between two electrodes with the solid dielectric being a lanthanum-doped barium titanate-based ceramic material.

First claim

What is claimed as new and desired to be secured by Letters Patent of the United States is:

1. An energy storage system, comprising:
a hermetically-sealed casing having a volume defined within the casing wherein a relative humidity in said volume is a range of 30-90%; and
at least one energy storage capacitor disposed in said volume, each said energy storage capacitor having a solid dielectric sandwiched between two electrodes, wherein said solid dielectric is a lanthanum-doped barium titanate-based ceramic material, wherein a dopant of said lanthanum-doped barium titanate-based ceramic material is selected from the group consisting of lanthanum hydroxide and lanthanum oxide, and wherein said lanthanum-doped barium titanate-based ceramic material includes an alkali hydroxide co-dopant selected from the group consisting of potassium hydroxide, sodium hydroxide, rubidium hydroxide, and lithium hydroxide.

2. An energy storage system as in claim 1 , wherein said casing is made from a material selected from the group consisting of plastics, ceramics, and metals.

3. An energy storage system as in claim 1 , wherein said at least one energy storage capacitor comprises a plurality of energy storage capacitors in a stacked arrangement.

4. An energy storage system as in claim 1 , wherein each said solid dielectric has a thickness in a range of 1-50 micrometers.

5. An energy storage system as in claim 1 , wherein said relative humidity in said volume is a range of 50-90%.

6. An energy storage system, comprising:
a hermetically-sealed casing having a volume defined within the casing wherein a relative humidity in said volume is a range of 30-90%; and
a stacked arrangement of a plurality energy storage capacitors disposed in said volume, each of said energy storage capacitors having a solid dielectric sandwiched between two electrodes, wherein said solid dielectric is a lanthanum-doped barium titanate-based ceramic material having a thickness in a range of 1-50 micrometers, wherein a dopant of said lanthanum-doped barium titanate-based ceramic material is selected from the group consisting of lanthanum hydroxide and lanthanum oxide, and wherein said lanthanum-doped barium titanate-based ceramic material includes an alkali hydroxide co-dopant selected from the group consisting of potassium hydroxide, sodium hydroxide, rubidium hydroxide, and lithium hydroxide.

7. An energy storage system as in claim 6 , wherein said casing is made from a material selected from the group consisting of plastics, ceramics, and metals.

8. An energy storage system as in claim 6 , wherein said relative humidity in said volume is a range of 50-90%.

9. An energy storage system, comprising:
a hermetically-sealed casing having a volume defined within the casing wherein a relative humidity in said volume is a range of 30-90%; and
at least one energy storage capacitor disposed in said volume, each said energy storage capacitor having a solid dielectric sandwiched between two electrodes, wherein said solid dielectric is a lanthanum-doped barium titanate-based ceramic material, wherein a dopant of said lanthanum-doped barium titanate-based ceramic material comprises lanthanum hydroxide, and wherein said lanthanum-doped barium titanate-based ceramic material includes an alkali hydroxide co-dopant selected from the group consisting of potassium hydroxide, sodium hydroxide, rubidium hydroxide, and lithium hydroxide, each said energy storage capacitor prepared by a process comprising the steps of
providing particles of lanthanum hydroxide having an average grain diameter of 50-700 nanometers, particles of barium oxide having an average grain diameter of 50-700 nanometers, and particles of titanium dioxide having an average grain diameter of 50-700 nanometers,
mixing 0.7-5.0 weight percent of said particles of lanthanum hydroxide, 60-65 weight percent of said particles of barium oxide, and a remaining weight percent of said particles of titanium dioxide, wherein a mixture of particles is generated,
heating said mixture of particles to a temperature in a range of 1000−1300° C. wherein a sintered mixture is generated,
milling said sintered mixture to generate milled particles having diameters of 50-700 nanometers,
mixing 50-70 weight percent of said milled particles with
5-15 weight percent of glass particles having a particle size of 0.5-10 micrometers,
0.1-5.0 weight percent of an organic surfactant,
5-25 weight percent of a solvent,
5-25 weight percent of an organic vehicle, and
1-5 weight percent of said alkali hydroxide, wherein a liquid mixture is generated,
providing a first electrode of said two electrodes,
depositing a layer of said liquid mixture onto said first electrode,
processing said first electrode with said layer thereon to remove liquid portions of said liquid mixture, wherein said step of processing includes a cycle of heating said layer to a temperature in a range of 850-900° C. followed by a cycle of cooling said layer in a nitrogen atmosphere containing less than 25 parts per million of oxygen, and
affixing a second electrode of said two electrodes onto said layer after said liquid portions of said liquid mixture have been removed.

10. An energy storage system as in claim 9 , wherein said step of heating said mixture of particles occurs in air.

11. An energy storage system as in claim 9 , wherein said step of heating said mixture of particles occurs in a vacuum.

12. An energy storage system as in claim 9 , wherein said layer is 1-50 micrometers in thickness.

13. An energy storage system as in claim 9 , wherein said organic surfactant is selected from the group consisting of phosphate esters.

14. An energy storage system as in claim 9 , wherein said solvent is selected from the group consisting of ester alcohol, terpineol, and butyl carbitol.

15. An energy storage system as in claim 9 , wherein said organic vehicle comprises ethyl cellulose.

16. An energy storage system as in claim 9 , wherein said glass particles are selected from the group consisting of lead germinate glass particles and zinc borate glass particles.

17. An energy storage system as in claim 9 , wherein said relative humidity in said volume is a range of 50-90%.

Assignees

• The United States of America as Represented by NASA
• Nasa

Inventors

• Rolin Terry D
• Small Ian K
• Hill Curtis W

Classifications

• H01M8/0217

  Complex oxides, optionally doped, of the type AMO3, A being an alkaline earth metal or rare earth metal and M being a metal, e.g. perovskites · CPC title

• H01M6/185

  with oxides, hydroxides or oxysalts as solid electrolytes · CPC title

• H01G4/005

  Electrodes · CPC title

• C04B2235/656

  characterised by specific heating conditions during heat treatment · CPC title

• C04B2235/5454

  nanometer sized, i.e. below 100 nm · CPC title