Crystal oriented ceramicscrystal oriented ceramics, the production process, and heat radiation material

Patent metadata

Field	Value
Publication number	US-10323168-B2
Application number	US-201615555532-A
Country	US
Kind code	B2
Filing date	Mar 4, 2016
Priority date	Mar 5, 2015
Publication date	Jun 18, 2019
Grant date	Jun 18, 2019

Abstract

A production process for a crystal oriented ceramics includes: a first step of preparing composite particles formed of particles having magnetic anisotropy having magnetic susceptibility anisotropy and seed particles having magnetic susceptibility anisotropy less than or equal to 1/10 of the magnetic susceptibility anisotropy of the particles having magnetic anisotropy and are formed of an inorganic compound having an anisotropic shape in which a crystal axis intended to be corresponds to a minor axis or a major axis; a second step of adding raw material powder including the composite particles to a solvent to prepare a slurry a third step of preparing a green compact by disposing the slurry in a static magnetic field of ≥0.1 tesla and drying the slurry in a state in which crystal axes of the seed particles in a major axis direction are in one direction; and a fourth step of sintering the green compact.

First claim

The invention claimed is:

1. A production process for a crystal oriented ceramic comprising:
a first step of preparing composite particles (C) formed of particles having magnetic anisotropy (A) which have a magnetic susceptibility anisotropy and seed particles (B) which have a magnetic susceptibility anisotropy less than or equal to 1/10 of the magnetic susceptibility anisotropy of the particles having magnetic anisotropy (A) and are formed of an inorganic compound having an anisotropic shape in which a crystal axis intended to be oriented corresponds to a minor axis or a major axis;
a second step of adding raw material powder (D) which includes the composite particles (C) to a solvent to prepare a slurry including the raw material powder (D) and the solvent;
a third step of preparing a green compact by disposing the slurry in a static magnetic field of 0.1 tesla (T) or greater and drying the slurry in a state in which crystal axes of the seed particles (B) in a major axis direction are in one direction; and
a fourth step of sintering the green compact.

2. The production process for a crystal oriented ceramic according to claim 1 ,
wherein the raw material powder (D) contains particles whose chemical composition is the same as the chemical composition of the seed particles (B).

3. The production process for a crystal oriented ceramic according to claim 1 ,
wherein an average particle diameter of the seed particles (B) is 0.5 μm or greater, and
a ratio of a major axis diameter to a minor axis diameter (major axis diameter/minor axis diameter) is 1.6 or greater.

4. The production process for a crystal oriented ceramic according to claim 1 ,
wherein the average particle diameter of the particles having magnetic anisotropy (A) is less than or equal to 1/10 of the average particle diameter of the seed particles (B).

5. The production process for a crystal oriented ceramic according to claim 1 ,
wherein a compounding ratio of the particles having magnetic anisotropy (A) to the seed particles (B) in the first step is 0.1% by volume or greater of the total amount of the seed particles (B).

6. The production process for a crystal oriented ceramic according to claim 1 ,
wherein grains in the ceramic are in the same direction as the crystal axes of the seed particles (B) in the major axis direction by sintering the green compact to obtain a crystal oriented ceramics in which an orientation degree of crystal axes of the grains in the ceramic in a direction which is the same as the major axis direction of the seed particles (B) is 0.2 or greater.

7. A crystal oriented ceramic which is obtained by the production process for a crystal oriented ceramic according to claim 1 .

Assignees

• Kanagawa Institute Of Industrial Science And Tech
• Nat Univ Corp Yokohama Nat Univ

Inventors

• Takahashi Takuma
• Tatami Junichi
• SUGIMOTO Nanako

Classifications

• C04B2235/3878

  Alpha silicon nitrides · CPC title

• C04B2235/605

  Making or treating the green body or pre-form in a magnetic field · CPC title

• C04B2235/5445

  submicron sized, i.e. from 0,1 to 1 micron · CPC title

• C04B2235/522

  Oxidic · CPC title

• C04B35/62881

  with metal salts, e.g. phosphates · CPC title