Method for fabricating a ceramic material

Patent metadata

Field	Value
Publication number	US-10323167-B2
Application number	US-201615267198-A
Country	US
Kind code	B2
Filing date	Sep 16, 2016
Priority date	Oct 12, 2011
Publication date	Jun 18, 2019
Grant date	Jun 18, 2019

Abstract

A method for fabricating a ceramic material includes impregnating a porous structure with a mixture that includes a preceramic polymer and a filler. The filler includes at least one free metal. The preceramic polymer material is then rigidized to form a green body. The green body is then thermally treated to convert the rigidized preceramic polymer material into a ceramic matrix located within pores of the porous structure. The same thermal treatment or a second, further thermal treatment is used to cause the at least one free metal to move to internal porosity defined by the ceramic matrix or pores of the porous structure.

First claim

What is claimed is:

1. A method for fabricating a ceramic material, the method comprising:
infiltrating a porous structure with a mixture that includes a preceramic material and a filler, the filler including ceramic particles coated with the at least one free metal;
rigidizing the preceramic material to form a green body; and
thermally treating the green body to convert the rigidized preceramic material into a ceramic matrix within pores of the porous structure, wherein the thermal treatment or a second, further thermal treatment is used to cause the at least one free metal to move to internal porosity defined by the ceramic matrix or residual open pores of the porous structure.

2. The method as recited in claim 1 , wherein the porous structure comprises a fibrous structure.

3. The method as recited in claim 1 , wherein the at least one free metal comprises silicon.

4. The method as recited in claim 1 , wherein the at least one free metal is selected from a group consisting of boron, titanium, vanadium, chromium, zirconium, niobium, molybdenum, ruthenium, rhodium, hafnium, tantalum, tungsten, rhenium, osmium, iridium and combinations thereof.

5. The method as recited in claim 1 , wherein the ceramic particles have a higher thermal conductivity than the ceramic matrix.

6. The method as recited in claim 1 , including thermally treating the green body in an environment that is substantially free of oxygen, to convert the rigidized preceramic material into the ceramic matrix.

7. The method as recited in claim 1 , including thermally treating the green body at a temperature that is below the melting temperature of the at least one free metal, to convert the rigidized preceramic material into the ceramic matrix.

8. The method as recited in claim 1 , including thermally treating the green body at a first temperature to convert the rigidized preceramic material into the ceramic matrix, and wherein the second thermal treatment is used at a second temperature that is greater than the first temperature to cause the at least one free metal to move to the internal porosity defined by the ceramic matrix or the residual open pores of the porous structure.

9. The method as recited in claim 1 , including using at least two free metals and reacting the at least two free metals together to form a compound.

10. The method as recited in claim 1 , wherein the at least one metal forms a continuous phase within the ceramic matrix.

Assignees

• United Technologies Corp

Inventors

• Schmidt Wayde R
• Kashyap Tania Bhatia
• Sheedy Paul

Classifications

• C22C29/065

  based on SiC · CPC title

• C04B35/62844

  Coating fibres · CPC title

• C04B2235/5252

  having a specific pre-form · CPC title

• C04B35/571

  obtained from {Si-containing} polymer precursors {or organosilicon monomers} · CPC title

• C04B2235/5248

  Carbon, e.g. graphite · CPC title