Coating to cool a surface by passive radiative cooling

Patent metadata

Field	Value
Publication number	US-10323151-B2
Application number	US-201715444029-A
Country	US
Kind code	B2
Filing date	Feb 27, 2017
Priority date	Feb 27, 2017
Publication date	Jun 18, 2019
Grant date	Jun 18, 2019

Abstract

Disclosed herein are implementations of a radiative cooling formulation, an apparatus including a substrate coated with the radiative cooling formulation, and a method of applying a coating of the radiative cooling formulation to an object. In one implementation, a radiative cooling formulation includes a binder which includes a first polymer and a second polymer that are practically water insoluble and are substantially non-absorbing to light having wavelengths in a solar spectrum. The radiative cooling formulation further includes a solar reflector material embedded in the binder.

First claim

What is claimed is:

1. A radiative cooling formulation comprising:
a binder comprising a plurality of polymers comprising a first polymer and a second polymer that are practically water insoluble and are substantially non-absorbing to light having wavelengths in a solar spectrum, wherein the first polymer has a first emissivity peak value greater than 0.85 at a first wavelength between 4 and 35 micrometers (μm) and the second polymer has a second emissivity peak value greater than 0.85 at a second wavelength between 4 and 35 μm, the first emissivity peak value and the second emissivity peak value are substantially non-overlapping, and a net emissivity of the first polymer and the second polymer is greater than at least one of first emissivity of the first polymer or second emissivity of the second polymer; and
a solar reflector material embedded in the binder.

2. The radiative cooling formulation of claim 1 further comprising a solvent selected from the group consisting of water, ethyl alcohol, butyl carbitol, carbitol, dimethylformamide, xylene, toluene, mineral spirits, a mixture of aliphatic carbons, methylethyl ketone, methyl isobutyl ketone, butyl acetate, and 1-methoxy-2-propylacetate.

3. The radiative cooling formulation of claim 1 , wherein each of the plurality of polymers has a corresponding emissivity peak value greater than 0.85 at wavelengths between 4 and 35 μm and each of the corresponding emissivity peak values are substantially non-overlapping.

4. The radiative cooling formulation of claim 1 , wherein the first wavelength and second wavelength are between 8 and 13 μm.

5. The radiative cooling formulation of claim 1 , wherein the solar reflector material reflects solar radiation at wavelengths from 0.3 to 2.5 μm and has an average solar reflectance greater than 0.95.

6. A radiative cooling formulation comprising:
a binder comprising a plurality of polymers comprising a first polymer and a second polymer that are practically water insoluble and are substantially non-absorbing to light having wavelengths in a solar spectrum, wherein the first polymer has a first emissivity peak value greater than 0.85 at a first wavelength between 4 and 35 micrometers (μm) and the second polymer has a second emissivity peak value greater than 0.85 at a second wavelength between 4 and 35 μm, the first emissivity peak value and the second emissivity peak value are substantially non-overlapping, and a net emissivity of the first polymer and the second polymer is greater than at least one of first emissivity of the first polymer or second emissivity of the second polymer; and
a solar reflector material embedded in the binder, wherein the solar reflector material comprises particles of barium sulfate (BaSO 4 ) and at least half of the particles of BaSO 4 are smaller than 2 μm.

7. The radiative cooling formulation of claim 6 further comprising titanium dioxide (TiO 2 ) embedded in the binder.

8. A radiative cooling formulation comprising:
a binder comprising a plurality of polymers comprising a first polymer and a second polymer that are practically water insoluble and are substantially non-absorbing to light having wavelengths in a solar spectrum, wherein the first polymer has a first emissivity peak value greater than 0.85 at a first wavelength between 4 and 35 micrometers (μm) and the second polymer has a second emissivity peak value greater than 0.85 at a second wavelength between 4 and 35 μm, the first emissivity peak value and the second emissivity peak value are substantially non-overlapping, and a net emissivity of the first polymer and the second polymer is greater than at least one of first emissivity of the first polymer or second emissivity of the second polymer; and
a solar reflector material embedded in the binder, wherein each of the plurality of polymers is selected from the group consisting of ethyl cellulose, poly ethyl methacrylate (PEMA), poly methyl methacrylate (PMMA), polyvinyl butyral (PVB), cellulose acetate, polyethylene, polypropylene, polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyesters, and polycarbonates, wherein the first polymer is different from the second polymer.

9. The radiative cooling formulation of claim 1 , wherein the binder is a polymer emulsion comprising at least one of a first set of particles comprising the first polymer or a second set of particles comprising the second polymer.

10. A method comprising:
applying a coating of a radiative cooling formulation to an object, wherein the radiative cooling formulation comprises:
a binder comprising a plurality of polymers comprising a first polymer and a second polymer that are practically water insoluble and are substantially non-absorbing to light having wavelengths in a solar spectrum, wherein the first polymer has a first emissivity peak value greater than 0.85 at a first wavelength between 4 and 35 micrometers (μm) and the second polymer has a second emissivity peak value greater than 0.85 at a second wavelength between 4 and 35 μm, the first emissivity peak value and the second emissivity peak value are substantially non-overlapping, and a net emissivity of the first polymer and the second polymer is greater than at least one of first emissivity of the first polymer or second emissivity of the second polymer; and
a solar reflector material embedded in the binder.

11. The method of claim 10 , wherein the first wavelength and second wavelength are between 8 and 13 μm.

12. The method of claim 10 further comprising applying a layer on the coating, the layer comprising one or more of polytetrafluoroethylene (PTFE), perfluoroalkoxy (PFA), fluorinated ethylene-propylene (FEP), ethylene tetrafluoroethylene (ETFE), or tetrafluoroethylene/hexafluoropropylene/vinylidene fluoride copolymer (THV).

13. The method of claim 10 further comprising applying a layer on the coating, the layer comprising a hydrophobic material, wherein the hydrophobic material is substantially non-absorbing of wavelengths from 0.3 to 2.5 μm and the hydrophobic material comprises at least one of fluorinated silica nanospheres, or nano-etched silica.

14. The method of claim 10 further comprising applying a layer on the coating, the layer comprising titanium dioxide (TiO 2 ).

15. The method of claim 10 , wherein the object comprises at least one of aluminum, steel, galvanized steel, carbon fiber resin, a tent, a flexible tarp, a roof structure, or a surface of an automobile.

Assignees

• Palo Alto Res Ct Inc

Inventors

• Van Overmeere Quentin
• Elrod Scott Alan
• Solberg Scott E
• Iftime Gabriel
• Neelakantan Ravi
• Casse Bernard D

Classifications

• C09D133/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C08K2003/3045

  Sulfates · CPC title

• C09D5/004 Primary

  Reflecting paints; Signal paints · CPC title

• C08K2003/2241

  Titanium dioxide · CPC title

• C09D129/14

  Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols · CPC title